CHEMISTRY: MOLECULAR...(LL) W/ALEKS
9th Edition
ISBN: 9781265141875
Author: SILBERBERG
Publisher: MCG CUSTOM
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 20.4, Problem 20.9BFP
Interpretation Introduction
Interpretation: The change in standard Gibbs free energy of the reaction needs to be calculated at 298 K using the given equilibrium constant value.
Concept Introduction:
The relation between change in standard Gibbs free energy of reaction and equilibrium constant is as follows:
Here, R is the universal gas constant and T is temperature.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
:☐
G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
فا
Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 20 Solutions
CHEMISTRY: MOLECULAR...(LL) W/ALEKS
Ch. 20.1 - Prob. 20.1AFPCh. 20.1 - Prob. 20.1BFPCh. 20.2 - Prob. 20.2AFPCh. 20.2 - Prob. 20.2BFPCh. 20.2 - Prob. 20.3AFPCh. 20.2 - Prob. 20.3BFPCh. 20.3 - Prob. 20.4AFPCh. 20.3 - Prob. 20.4BFPCh. 20.3 - Prob. 20.5AFPCh. 20.3 - Prob. 20.5BFP
Ch. 20.3 - Prob. 20.6AFPCh. 20.3 - Prob. 20.6BFPCh. 20.3 - Prob. 20.7AFPCh. 20.3 - Prob. 20.7BFPCh. 20.3 - Prob. 20.8AFPCh. 20.3 - Prob. 20.8BFPCh. 20.4 - Prob. 20.9AFPCh. 20.4 - Prob. 20.9BFPCh. 20.4 - Prob. 20.10AFPCh. 20.4 - Prob. 20.10BFPCh. 20.4 - Prob. 20.11AFPCh. 20.4 - Prob. 20.11BFPCh. 20 - Prob. 20.1PCh. 20 - Distinguish between the terms spontaneous and...Ch. 20 - State the first law of thermodynamics in terms of...Ch. 20 - State qualitatively the relationship between...Ch. 20 - Why is ΔSvap of a substance always larger than...Ch. 20 - Prob. 20.6PCh. 20 - Prob. 20.7PCh. 20 - Which of these processes are spontaneous? (a)...Ch. 20 - Prob. 20.9PCh. 20 - Which of these processes are spontaneous? (a)...Ch. 20 - Prob. 20.11PCh. 20 - Prob. 20.12PCh. 20 - Prob. 20.13PCh. 20 - Prob. 20.14PCh. 20 - Prob. 20.15PCh. 20 - Prob. 20.16PCh. 20 - Prob. 20.17PCh. 20 - Prob. 20.18PCh. 20 - Prob. 20.19PCh. 20 - Prob. 20.20PCh. 20 - Prob. 20.21PCh. 20 - Prob. 20.22PCh. 20 - Prob. 20.23PCh. 20 - Prob. 20.24PCh. 20 - Predict which substance has greater molar entropy....Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - Without consulting Appendix B, arrange each group...Ch. 20 - In the reaction depicted in the molecular scenes,...Ch. 20 - Describe the equilibrium condition in terms of the...Ch. 20 - Prob. 20.32PCh. 20 - For each reaction, predict the sign and find the...Ch. 20 - For each reaction, predict the sign and find the...Ch. 20 - Find for the combustion of ethane (C2H6) to...Ch. 20 - Find for the combustion of methane to carbon...Ch. 20 - Find for the reaction of nitrogen monoxide with...Ch. 20 - Find for the combustion of ammonia to nitrogen...Ch. 20 - Find for the formation of Cu2O(s) from its...Ch. 20 - Find for the formation of HI(g) from its...Ch. 20 - Find for the formation of CH3OH(l) from its...Ch. 20 - Find for the formation of N2O(g) from its...Ch. 20 - Sulfur dioxide is released in the combustion of...Ch. 20 - Oxyacetylene welding is used to repair metal...Ch. 20 - What is the advantage of calculating free energy...Ch. 20 - Given that ΔGsys = −TΔSuniv, explain how the sign...Ch. 20 -
Is an endothermic reaction more likely to be...Ch. 20 - Explain your answers to each of the following for...Ch. 20 - With its components in their standard states, a...Ch. 20 - How can ΔS° for a reaction be relatively...Ch. 20 - Calculate ΔG° for each reaction using ...Ch. 20 - Calculate ΔG° for each reaction using ...Ch. 20 - Prob. 20.53PCh. 20 - Prob. 20.54PCh. 20 - Consider the oxidation of carbon...Ch. 20 - Consider the combustion of butane gas:
Predict...Ch. 20 - For the gaseous reaction of xenon and fluorine to...Ch. 20 - For the gaseous reaction of carbon monoxide and...Ch. 20 - One reaction used to produce small quantities of...Ch. 20 - A reaction that occurs in the internal combustion...Ch. 20 - As a fuel, H2(g) produces only nonpolluting H2O(g)...Ch. 20 - The U.S. government requires automobile fuels to...Ch. 20 -
If K << 1 for a reaction, what do you know about...Ch. 20 - How is the free energy change of a process related...Ch. 20 - The scenes and the graph relate to the reaction of...Ch. 20 - What is the difference between ΔG° and ΔG? Under...Ch. 20 - Calculate K at 298 K for each reaction:
MgCO3(s) ⇌...Ch. 20 - Calculate ΔG° at 298 K for each reaction:
2H2S(g)...Ch. 20 - Calculate K at 298 K for each reaction:
HCN(aq) +...Ch. 20 - Calculate ΔG° at 298 K for each reaction:
2NO(g) +...Ch. 20 - Use ΔH° and ΔS° values for the following process...Ch. 20 - Use ΔH° and ΔS° values to find the temperature at...Ch. 20 - Prob. 20.73PCh. 20 - Use Appendix B to determine the Ksp of CaF2.
Ch. 20 - For the reaction I2(g) + Cl2(g) ⇌ 2ICl(g),...Ch. 20 - For the reaction CaCO3(s) ⇌ CaO(s) + CO2(g),...Ch. 20 - The Ksp of PbCl2 is 1.7×10−5 at 25°C. What is ΔG°?...Ch. 20 - Prob. 20.78PCh. 20 - The equilibrium constant for the...Ch. 20 - The formation constant for the reaction
Ni2+(aq) +...Ch. 20 - Prob. 20.81PCh. 20 - Prob. 20.82PCh. 20 - High levels of ozone (O3) cause rubber to...Ch. 20 - A BaSO4 slurry is ingested before the...Ch. 20 - According to advertisements, “a diamond is...Ch. 20 - Prob. 20.86PCh. 20 - Prob. 20.87PCh. 20 - Prob. 20.88PCh. 20 - Is each statement true or false? If false, correct...Ch. 20 - Prob. 20.90PCh. 20 - Prob. 20.91PCh. 20 - Prob. 20.92PCh. 20 - Prob. 20.93PCh. 20 -
Write a balanced equation for the gaseous...Ch. 20 - Prob. 20.95PCh. 20 - Hydrogenation is the addition of H2 to double (or...Ch. 20 - Prob. 20.97PCh. 20 - Prob. 20.98PCh. 20 - Prob. 20.99PCh. 20 - Prob. 20.100PCh. 20 - From the following reaction and data, find (a) S°...Ch. 20 - Prob. 20.102PCh. 20 - Prob. 20.103PCh. 20 - Prob. 20.104PCh. 20 - Prob. 20.105PCh. 20 - Prob. 20.106PCh. 20 - Prob. 20.107PCh. 20 - Consider the formation of ammonia:
N2(g) + 3H2(g)...Ch. 20 -
Kyanite, sillimanite, and andalusite all have the...Ch. 20 - Prob. 20.110PCh. 20 - Prob. 20.111P
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
- Given a complex reaction with rate equation v = k1[A] + k2[A]2, what is the overall reaction order?arrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forwardCHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the steady-state approximation method. Explain what it consists of.arrow_forward
- CHEMICAL KINETICS. One of the approximation methods for solving the rate equation is the limiting or determining step approximation method. Explain what it consists of.arrow_forwardCHEMICAL KINETICS. Indicate the approximation methods for solving the rate equation.arrow_forwardTRANSMITTANCE เบบ Please identify the one structure below that is consistent with the 'H NMR and IR spectra shown and draw its complete structure in the box below with the protons alphabetically labeled as shown in the NMR spectrum and label the IR bands, including sp³C-H and sp2C-H stretch, indicated by the arrows. D 4000 OH LOH H₂C CH3 OH H₂C OCH3 CH3 OH 3000 2000 1500 HAVENUMBERI-11 1000 LOCH3 Draw your structure below and label its equivalent protons according to the peak labeling that is used in the NMR spectrum in order to assign the peaks. Integrals indicate number of equivalent protons. Splitting patterns are: s=singlet, d=doublet, m-multiplet 8 3Hb s m 1Hd s 3Hf m 2Hcd 2Had 1He 鄙视 m 7 7 6 5 4 3 22 500 T 1 0arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
General Chemistry - Standalone book (MindTap Cour...
Chemistry
ISBN:9781305580343
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
The Laws of Thermodynamics, Entropy, and Gibbs Free Energy; Author: Professor Dave Explains;https://www.youtube.com/watch?v=8N1BxHgsoOw;License: Standard YouTube License, CC-BY