Chemistry: Atoms First
Chemistry: Atoms First
3rd Edition
ISBN: 9781259638138
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 20.3, Problem 20.3.1SR
Interpretation Introduction

Interpretation: From the given details of the rock, age of the rock should be determined.

Concept Introduction:

  • Unstable nuclei emit radiation spontaneously to become stable nuclei by losing energy. This process of emission of radiation by unstable nuclei is known as radioactive decay.
  • These emitted radiations may be alpha radiations( α ), beta radiations( β ) or gamma radiations( γ )
  • These unstable nuclei are the nuclei with more than 83 protons and which do not lie within the belt of stability.
  • Radioactive decay are in the first order kinetics. Rate of radioactive decay at a time t is,

    Rate of decay at a time 't' = k Nk-Firstorderrateconstant and its unit is t1N-numberofradioactivenucleipresentattime't

    Suppose the number of radioactive nuclei at time zero is N0 and at a time t is Nt ,

    lnNtN0=-kt

  • Half-life of radioactive decay is the time required for a radioactive sample to decay to one half of the atomic nucleus.

    Half-life of the radiation,  t1/2=0.693k

    Half-life and rate constant for radioactive isotopes vary greatly from nucleus to nucleus.

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Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ar
Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1
Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?

Chapter 20 Solutions

Chemistry: Atoms First

Ch. 20.2 - Prob. 20.2.2SRCh. 20.2 - What is the change in mass (in ka) for the...Ch. 20.3 - Prob. 20.3WECh. 20.3 - Prob. 3PPACh. 20.3 - Prob. 3PPBCh. 20.3 - Prob. 20.4WECh. 20.3 - Prob. 4PPACh. 20.3 - Prob. 20.3.1SRCh. 20.3 - Prob. 20.3.2SRCh. 20.4 - Prob. 20.5WECh. 20.4 - Prob. 5PPACh. 20.4 - Prob. 5PPBCh. 20.4 - Prob. 5PPCCh. 20.4 - Prob. 20.4.1SRCh. 20.4 - Prob. 20.4.2SRCh. 20 - Prob. 20.1QPCh. 20 - Prob. 20.2QPCh. 20 - Prob. 20.3QPCh. 20 - Prob. 20.4QPCh. 20 - Prob. 20.5QPCh. 20 - Prob. 20.6QPCh. 20 - Prob. 20.7QPCh. 20 - Prob. 20.8QPCh. 20 - Prob. 20.9QPCh. 20 - Prob. 20.10QPCh. 20 - Prob. 20.11QPCh. 20 - Prob. 20.12QPCh. 20 - Prob. 20.13QPCh. 20 - Prob. 20.14QPCh. 20 - Prob. 20.15QPCh. 20 - Prob. 20.16QPCh. 20 - Prob. 20.17QPCh. 20 - Prob. 20.18QPCh. 20 - Prob. 20.19QPCh. 20 - Prob. 20.20QPCh. 20 - Prob. 20.21QPCh. 20 - Prob. 20.22QPCh. 20 - Prob. 20.23QPCh. 20 - Prob. 20.24QPCh. 20 - Prob. 20.25QPCh. 20 - Prob. 20.26QPCh. 20 - Prob. 20.27QPCh. 20 - Prob. 20.28QPCh. 20 - Prob. 20.29QPCh. 20 - Prob. 20.30QPCh. 20 - Prob. 20.31QPCh. 20 - Prob. 20.32QPCh. 20 - Prob. 20.33QPCh. 20 - Prob. 20.34QPCh. 20 - Prob. 20.35QPCh. 20 - Prob. 20.36QPCh. 20 - Prob. 20.37QPCh. 20 - Prob. 20.38QPCh. 20 - Prob. 20.39QPCh. 20 - Prob. 20.1VCCh. 20 - Prob. 20.3VCCh. 20 - Prob. 20.4VCCh. 20 - Prob. 20.40QPCh. 20 - Prob. 20.41QPCh. 20 - Prob. 20.42QPCh. 20 - Prob. 20.43QPCh. 20 - Prob. 20.44QPCh. 20 - Prob. 20.45QPCh. 20 - Prob. 20.46QPCh. 20 - Prob. 20.47QPCh. 20 - Prob. 20.48QPCh. 20 - Prob. 20.49QPCh. 20 - Prob. 20.50QPCh. 20 - Prob. 20.51QPCh. 20 - Prob. 20.52QPCh. 20 - Prob. 20.53QPCh. 20 - Prob. 20.54QPCh. 20 - Prob. 20.55QPCh. 20 - Prob. 20.56QPCh. 20 - Prob. 20.57QPCh. 20 - Prob. 20.58QPCh. 20 - Prob. 20.59QPCh. 20 - Prob. 20.60QPCh. 20 - Prob. 20.61QPCh. 20 - Prob. 20.62QPCh. 20 - Prob. 20.63QPCh. 20 - Prob. 20.64QPCh. 20 - Prob. 20.65QPCh. 20 - Prob. 20.66QPCh. 20 - Prob. 20.67QPCh. 20 - Prob. 20.68QPCh. 20 - Prob. 20.69QPCh. 20 - Prob. 20.70QPCh. 20 - Prob. 20.71QPCh. 20 - Prob. 20.72QPCh. 20 - Prob. 20.73QPCh. 20 - Prob. 20.74QPCh. 20 - Prob. 20.75QPCh. 20 - Prob. 20.76QPCh. 20 - Prob. 20.77QPCh. 20 - Prob. 20.78QPCh. 20 - Prob. 20.79QPCh. 20 - Prob. 20.80QPCh. 20 - Prob. 20.81QPCh. 20 - Prob. 20.82QPCh. 20 - Prob. 20.83QPCh. 20 - Prob. 20.84QPCh. 20 - Prob. 20.85QPCh. 20 - Prob. 20.86QPCh. 20 - Prob. 20.87QPCh. 20 - Prob. 20.88QPCh. 20 - Prob. 20.89QPCh. 20 - Prob. 20.90QPCh. 20 - Prob. 20.91QPCh. 20 - Prob. 20.92QPCh. 20 - Prob. 20.93QPCh. 20 - Prob. 20.94QPCh. 20 - Prob. 20.95QPCh. 20 - Prob. 20.96QPCh. 20 - Prob. 20.97QPCh. 20 - Prob. 20.98QPCh. 20 - Prob. 20.99QPCh. 20 - Prob. 20.100QPCh. 20 - Prob. 20.101QP
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