The reason for the for the tetrahedral complex ion having different crystal field diagram then octahedral complex ion; tetrahedral crystal field splitting diagram; the reason for tetrahedral complex ions being high spin; and the explanation for the crystal field diagram of square planar complex ion and linear complex ions is to be stated. Concept introduction: The ratio of crystal field splitting energy of tetrahedral complex and octahedral complex is 4 9 . The crystal field diagram of square planar complex is obtained by the removal of the two point charges along the z − axis . The crystal field diagram of linear complex is obtained by the removal of the two point charges along the z − axis and two along d x y . To determine: The reason for the for the tetrahedral complex ion having different crystal field diagram then octahedral complex ion; tetrahedral crystal field splitting diagram; the reason for tetrahedral complex ions being high spin; and the explanation for the crystal field diagram of square planar complex ion and linear complex ions.

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Chapter 20, Problem 8RQ

Interpretation Introduction

Interpretation: The reason for the for the tetrahedral complex ion having different crystal field diagram then octahedral complex ion; tetrahedral crystal field splitting diagram; the reason for tetrahedral complex ions being high spin; and the explanation for the crystal field diagram of square planar complex ion and linear complex ions is to be stated.

Concept introduction: The ratio of crystal field splitting energy of tetrahedral complex and octahedral complex is 49 .

The crystal field diagram of square planar complex is obtained by the removal of the two point charges along the z−axis .

The crystal field diagram of linear complex is obtained by the removal of the two point charges along the z−axis and two along dxy .

To determine: The reason for the for the tetrahedral complex ion having different crystal field diagram then octahedral complex ion; tetrahedral crystal field splitting diagram; the reason for tetrahedral complex ions being high spin; and the explanation for the crystal field diagram of square planar complex ion and linear complex ions.

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