EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
7th Edition
ISBN: 9781119360889
Author: HYSLOP
Publisher: VST
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Chapter 20, Problem 88RQ
Interpretation Introduction
Interpretation:
The radioactivity of the given sample in
Concept Introduction:
For radioactive elements, the number of disintegrations per second occurring in them is defined as their activity. Becquerel is the SI unit of activity, which is equal to one disintegration per second.
Naturally occurring radioactive element, uranium is known to have an activity of approximately
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 20 Solutions
EBK STUDY GUIDE TO ACCOMPANY CHEMISTRY:
Ch. 20 - Prob. 1PECh. 20 - Prob. 2PECh. 20 - Prob. 3PECh. 20 - Prob. 4PECh. 20 - Prob. 5PECh. 20 - Prob. 6PECh. 20 - Prob. 7PECh. 20 - Prob. 8PECh. 20 - Prob. 9PECh. 20 - Prob. 10PE
Ch. 20 - Prob. 11PECh. 20 - Prob. 12PECh. 20 - Prob. 13PECh. 20 - Prob. 14PECh. 20 - Prob. 15PECh. 20 - Prob. 1RQCh. 20 - Conservation of Mass and Energy
20.2 How can we...Ch. 20 - Conservation of Mass and Energy
20.3 State the...Ch. 20 - Conservation of Mass and Energy What is the...Ch. 20 - Prob. 5RQCh. 20 - Prob. 6RQCh. 20 - Prob. 7RQCh. 20 - Prob. 8RQCh. 20 - Prob. 9RQCh. 20 - Prob. 10RQCh. 20 - Prob. 11RQCh. 20 - Prob. 12RQCh. 20 - Prob. 13RQCh. 20 - Prob. 14RQCh. 20 - Prob. 15RQCh. 20 - Prob. 16RQCh. 20 - Prob. 17RQCh. 20 - Prob. 18RQCh. 20 - Prob. 19RQCh. 20 - Band of Stability
20.20 Although lead-164 has two...Ch. 20 - Prob. 21RQCh. 20 - Prob. 22RQCh. 20 - Prob. 23RQCh. 20 - Prob. 24RQCh. 20 - Prob. 25RQCh. 20 - Prob. 26RQCh. 20 - Prob. 27RQCh. 20 - Prob. 28RQCh. 20 - Prob. 29RQCh. 20 - Prob. 30RQCh. 20 - Prob. 31RQCh. 20 - Prob. 32RQCh. 20 - Prob. 33RQCh. 20 - Prob. 34RQCh. 20 - Prob. 35RQCh. 20 - Prob. 37RQCh. 20 - Prob. 38RQCh. 20 - Prob. 39RQCh. 20 - Prob. 40RQCh. 20 - Prob. 41RQCh. 20 - Prob. 42RQCh. 20 - Prob. 43RQCh. 20 - Prob. 44RQCh. 20 - Prob. 45RQCh. 20 - Prob. 46RQCh. 20 - Prob. 47RQCh. 20 - Prob. 48RQCh. 20 - Prob. 49RQCh. 20 - Prob. 50RQCh. 20 - Prob. 51RQCh. 20 - Conservation of Mass and Energy Calculate the...Ch. 20 - Prob. 53RQCh. 20 - Prob. 54RQCh. 20 - Prob. 55RQCh. 20 - Prob. 56RQCh. 20 - Prob. 57RQCh. 20 - Prob. 58RQCh. 20 - Prob. 59RQCh. 20 - Prob. 60RQCh. 20 - Prob. 61RQCh. 20 - Prob. 62RQCh. 20 - Prob. 63RQCh. 20 - Prob. 64RQCh. 20 - Prob. 65RQCh. 20 - Prob. 66RQCh. 20 - Prob. 67RQCh. 20 - Prob. 68RQCh. 20 - Prob. 69RQCh. 20 - Prob. 70RQCh. 20 - Prob. 71RQCh. 20 - Prob. 72RQCh. 20 - Prob. 73RQCh. 20 - Prob. 74RQCh. 20 - Prob. 75RQCh. 20 - Prob. 76RQCh. 20 - Prob. 77RQCh. 20 - Prob. 78RQCh. 20 - Prob. 79RQCh. 20 - Prob. 80RQCh. 20 - Prob. 81RQCh. 20 - Prob. 82RQCh. 20 - Prob. 83RQCh. 20 - Prob. 84RQCh. 20 - Prob. 85RQCh. 20 - Prob. 86RQCh. 20 - Prob. 87RQCh. 20 - Prob. 88RQCh. 20 - Prob. 89RQCh. 20 - Prob. 90RQCh. 20 - Prob. 91RQCh. 20 - Prob. 92RQCh. 20 - Prob. 93RQCh. 20 - Prob. 94RQCh. 20 - Prob. 95RQCh. 20 - Prob. 96RQCh. 20 - Prob. 97RQCh. 20 - Prob. 98RQCh. 20 - Prob. 99RQCh. 20 - Prob. 100RQCh. 20 - Prob. 101RQCh. 20 - Prob. 102RQCh. 20 - Prob. 103RQCh. 20 - Prob. 104RQCh. 20 - Prob. 105RQCh. 20 - Prob. 106RQCh. 20 - Prob. 107RQCh. 20 - Prob. 108RQCh. 20 - Prob. 109RQCh. 20 - Prob. 110RQCh. 20 - Prob. 111RQCh. 20 - Prob. 112RQCh. 20 - Prob. 113RQCh. 20 - Prob. 114RQCh. 20 - Prob. 115RQCh. 20 - Prob. 116RQCh. 20 - Prob. 117RQCh. 20 - Prob. 118RQCh. 20 - Prob. 119RQCh. 20 - Prob. 120RQCh. 20 - Prob. 121RQCh. 20 - Prob. 122RQCh. 20 - Prob. 123RQCh. 20 - Prob. 124RQCh. 20 - Prob. 125RQCh. 20 - A complex ion of chromium(III) with oxalate ion...Ch. 20 - Prob. 127RQCh. 20 - Prob. 128RQCh. 20 - Prob. 129RQCh. 20 - Prob. 132RQ
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