The ions that are expected to form colored octahedral complex ions are to be determined. Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels. To determine: If Zn +2 will form colored octahedral aqueous complex or not.

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Answer 1

Question

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

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Answer 3

Question

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

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Answer 4

Question

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

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Answer 5

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

Answer 6

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

Answer 7

Chapter 20, Problem 85CWP

(a)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Zn+2 will form colored octahedral aqueous complex or not.

Answer 8

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

Answer 9

(b)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Cu+2 will form colored octahedral aqueous complex or not.

Answer 10

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

Answer 11

(c)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

To determine: If Mn+3 ion will form colored octahedral aqueous complex or not.

Answer 12

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

Answer 13

(d)

Interpretation Introduction

Interpretation: The ions that are expected to form colored octahedral complex ions are to be determined.

Concept introduction: There is degeneracy in the d orbitals of a transition metal atom or ion. It means they have same energy levels. But when they interact with ligands, the d orbitals become non degenerate, i.e. they do not have same energy. Color of the complex ions depends upon how the 3d electrons occupy the split energy levels.

Answer 14

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Answer 17

Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQ Ch. 20 - Prob. 3RQ Ch. 20 - Prob. 4RQ Ch. 20 - Prob. 5RQ Ch. 20 - Prob. 6RQ Ch. 20 - Prob. 7RQ Ch. 20 - Prob. 8RQ Ch. 20 - Prob. 9RQ Ch. 20 - Prob. 10RQ

Solution Summary: The author explains the degeneracy in the d orbitals of a transition metal atom or ion.

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