INTRODUCTORY CHEMISTRY
9th Edition
ISBN: 9780357858998
Author: ZUMDAHL
Publisher: CENGAGE C
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Textbook Question
Chapter 20, Problem 82QAP
. Draw a structural formula for each of the following:
a. methyl butanoate
b. ethyl acetate
c. o-chlorobenzoic acid
d. 2,2-dimethyl-3-chloro-buianoic acid
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With this, please answer the following questions:
1.) draw the structure of the electrophilic intermediate in this reaction.
2.) what is the role of the AlCl3 in the reaction
3.) write the complete stepwise mechanism for this reaction. Show all electron flow with arrows and include all intermediate structures
Consider the data below to answer the following questions.
Cyanohydrins are important intermediates in the synthesis of a-hydroxycarboxylic acids from ketones
and aldehydes. The nitrile functional group can be hydrolyzed by aqueous acid to yield a carboxylic
acid. Nitriles can also be hydrolyzed to carboxylic acids using aqueous base. Unfortunately, when a
cyanohydrin is treated with aqueous base the original carbonyl compound is isolated.
HO
H
HCEN
H-3-
HO'
NaOH
HO
cyanohychin
a.
a nucleophilic substitution
b.
an electrophilic addition
C10
OH
CH-COOH
A. The reaction of an aldehyde with hydrogen cyanide is an example of
+ NaCN + H₂O
reaction.
H-
C.
an electrophilic substitution
d. a nucleophilic addition
B. Identify the electrophile in the reaction of benzaldehyde with hydrogen cyanide.
Refer to the data below to answer the following questions:
The octapeptide saralasin is a specific antagonist of angiotensin II. A derivative of saralasin is used
therapeutically as an antihypertensive. Amino acid analysis of saralasin show the presence of the following
amino acids:
Ala, Arg, His, Pro, Sar, Tyr, Val, Val
A. Sar is the abbreviation for sarcosine, N-methyl aminoethanoic acid. Draw the structure of sarcosine.
B. N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N-terminus.
Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments:
Tyr-Val-His
Sar-Arg-Val
His-Pro-Ala
Val-Tyr-Val
Arg-Val-Tyr
What is the structure of saralasin?
Chapter 20 Solutions
INTRODUCTORY CHEMISTRY
Ch. 20.2 - Exercise 20.1 Give the molecular formulas for the...Ch. 20.4 - Exercise 20.2 Name the following molecules. a. b.Ch. 20.4 - Exercise 20.3 Write the structural formula for...Ch. 20.5 - Petroleum is a very valuable raw material for the...Ch. 20.7 - Exercise 20.4 Name the following molecules. a. b.Ch. 20.9 - Prob. 20.5SCCh. 20.11 - Prob. 20.6SCCh. 20.14 - Prob. 20.7SCCh. 20 - What is meant by the term “unsaturated...Ch. 20 - Prob. 2ALQ
Ch. 20 - Prob. 3ALQCh. 20 - How many different possible “tetramethylbenzenes”...Ch. 20 - For the general formula C6H14O, draw the...Ch. 20 - Prob. 6ALQCh. 20 - Prob. 1QAPCh. 20 - Your roommate, a chemistry major, claims to have...Ch. 20 - Prob. 3QAPCh. 20 - How many electron pairs are shared when a triple...Ch. 20 - Prob. 5QAPCh. 20 - Prob. 6QAPCh. 20 - Prob. 7QAPCh. 20 - Prob. 8QAPCh. 20 - Prob. 9QAPCh. 20 - . The chains in normal alkanes are not really...Ch. 20 - Prob. 11QAPCh. 20 - Prob. 12QAPCh. 20 - . Give the name of each of the following...Ch. 20 - Prob. 14QAPCh. 20 - . What are structural isomers? Which is the...Ch. 20 - Prob. 16QAPCh. 20 - Prob. 17QAPCh. 20 - Prob. 18QAPCh. 20 - Prob. 19QAPCh. 20 - Prob. 20QAPCh. 20 - . What is an alkyl group? How is a given alkyl...Ch. 20 - . When naming alkanes, find the longest continuous...Ch. 20 - Prob. 23QAPCh. 20 - . When naming alkanes, the alkyl groups are listed...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 27QAPCh. 20 - Prob. 28QAPCh. 20 - Prob. 29QAPCh. 20 - Prob. 30QAPCh. 20 - . What is pyrolytic cracking, and why is the...Ch. 20 - Prob. 32QAPCh. 20 - . Explain why alkanes are relatively unreactive.Ch. 20 - Prob. 34QAPCh. 20 - . Indicate the missing molecule in each of the...Ch. 20 - Prob. 36QAPCh. 20 - Prob. 37QAPCh. 20 - Prob. 38QAPCh. 20 - Prob. 39QAPCh. 20 - Prob. 40QAPCh. 20 - Prob. 41QAPCh. 20 - Prob. 42QAPCh. 20 - Prob. 43QAPCh. 20 - Prob. 44QAPCh. 20 - Prob. 45QAPCh. 20 - Prob. 46QAPCh. 20 - Prob. 47QAPCh. 20 - Prob. 48QAPCh. 20 - Prob. 49QAPCh. 20 - . Benzene exhibits resonance Explain this...Ch. 20 - . How is a monosubstituted benzene named? Give the...Ch. 20 - Prob. 52QAPCh. 20 - Prob. 53QAPCh. 20 - . What do the prefixes ortho-, meta-, and para-...Ch. 20 - Prob. 55QAPCh. 20 - Prob. 56QAPCh. 20 - Prob. 57QAPCh. 20 - Prob. 58QAPCh. 20 - . What functional group characterizes an alcohol?...Ch. 20 - Prob. 60QAPCh. 20 - . Give the systematic name for each of the...Ch. 20 - . Is 1-pentanol a primary, secondary, or tertiary...Ch. 20 - . Why is methanol sometimes called wood alcohol?...Ch. 20 - Prob. 64QAPCh. 20 - . Write the equation for the synthesis of ethanol...Ch. 20 - . What is the simplest aromatic alcohol commonly...Ch. 20 - Prob. 67QAPCh. 20 - Prob. 68QAPCh. 20 - Prob. 69QAPCh. 20 - Prob. 70QAPCh. 20 - Prob. 71QAPCh. 20 - Prob. 72QAPCh. 20 - Prob. 73QAPCh. 20 - Prob. 74QAPCh. 20 - Prob. 75QAPCh. 20 - Prob. 76QAPCh. 20 - Prob. 77QAPCh. 20 - Prob. 78QAPCh. 20 - Prob. 79QAPCh. 20 - Prob. 80QAPCh. 20 - Prob. 81QAPCh. 20 - . Draw a structural formula for each of the...Ch. 20 - Prob. 83QAPCh. 20 - Prob. 84QAPCh. 20 - Prob. 85QAPCh. 20 - Prob. 86QAPCh. 20 - Prob. 87QAPCh. 20 - Prob. 88QAPCh. 20 - Prob. 89APCh. 20 - Prob. 90APCh. 20 - Prob. 91APCh. 20 - Prob. 92APCh. 20 - Prob. 93APCh. 20 - . The systematic names of all saturated...Ch. 20 - Prob. 95APCh. 20 - Prob. 96APCh. 20 - Prob. 97APCh. 20 - Prob. 98APCh. 20 - Prob. 99APCh. 20 - . With very reactive agents, such as the halogen...Ch. 20 - . Alkenes and alkynes are characterized by their...Ch. 20 - Prob. 102APCh. 20 - Prob. 103APCh. 20 - Prob. 104APCh. 20 - Prob. 105APCh. 20 - Prob. 106APCh. 20 - Prob. 107APCh. 20 - Prob. 108APCh. 20 - Prob. 109APCh. 20 - Prob. 110APCh. 20 - Prob. 111APCh. 20 - Prob. 112APCh. 20 - Prob. 113APCh. 20 - Prob. 114APCh. 20 - Prob. 115APCh. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 117APCh. 20 - Prob. 118APCh. 20 - Prob. 119APCh. 20 - Prob. 120APCh. 20 - Prob. 121APCh. 20 - Prob. 122APCh. 20 - Prob. 123APCh. 20 - Prob. 124APCh. 20 - Prob. 125APCh. 20 - Prob. 126APCh. 20 - Prob. 127APCh. 20 - Prob. 128APCh. 20 - Prob. 129APCh. 20 - Prob. 130APCh. 20 - Prob. 131APCh. 20 - . Write the formula for the missing reactant or...Ch. 20 - Prob. 133APCh. 20 - Prob. 134APCh. 20 - . Name each of the following aromatic or...Ch. 20 - Prob. 136APCh. 20 - Prob. 137APCh. 20 - Prob. 138APCh. 20 - Prob. 139APCh. 20 - Prob. 140APCh. 20 - Prob. 141APCh. 20 - . Name each of the following alkanes....Ch. 20 - Prob. 143CPCh. 20 - Prob. 144CPCh. 20 - Prob. 145CPCh. 20 - Prob. 146CPCh. 20 - Prob. 147CP
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