INTRODUCTORY CHEMISTRY
9th Edition
ISBN: 9780357858998
Author: ZUMDAHL
Publisher: CENGAGE C
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Textbook Question
Chapter 20, Problem 2QAP
Your roommate, a chemistry major, claims to have synthesized the compound CH5 in the lab. Why is that not possible?
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
८८
2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 20 Solutions
INTRODUCTORY CHEMISTRY
Ch. 20.2 - Exercise 20.1 Give the molecular formulas for the...Ch. 20.4 - Exercise 20.2 Name the following molecules. a. b.Ch. 20.4 - Exercise 20.3 Write the structural formula for...Ch. 20.5 - Petroleum is a very valuable raw material for the...Ch. 20.7 - Exercise 20.4 Name the following molecules. a. b.Ch. 20.9 - Prob. 20.5SCCh. 20.11 - Prob. 20.6SCCh. 20.14 - Prob. 20.7SCCh. 20 - What is meant by the term “unsaturated...Ch. 20 - Prob. 2ALQ
Ch. 20 - Prob. 3ALQCh. 20 - How many different possible “tetramethylbenzenes”...Ch. 20 - For the general formula C6H14O, draw the...Ch. 20 - Prob. 6ALQCh. 20 - Prob. 1QAPCh. 20 - Your roommate, a chemistry major, claims to have...Ch. 20 - Prob. 3QAPCh. 20 - How many electron pairs are shared when a triple...Ch. 20 - Prob. 5QAPCh. 20 - Prob. 6QAPCh. 20 - Prob. 7QAPCh. 20 - Prob. 8QAPCh. 20 - Prob. 9QAPCh. 20 - . The chains in normal alkanes are not really...Ch. 20 - Prob. 11QAPCh. 20 - Prob. 12QAPCh. 20 - . Give the name of each of the following...Ch. 20 - Prob. 14QAPCh. 20 - . What are structural isomers? Which is the...Ch. 20 - Prob. 16QAPCh. 20 - Prob. 17QAPCh. 20 - Prob. 18QAPCh. 20 - Prob. 19QAPCh. 20 - Prob. 20QAPCh. 20 - . What is an alkyl group? How is a given alkyl...Ch. 20 - . When naming alkanes, find the longest continuous...Ch. 20 - Prob. 23QAPCh. 20 - . When naming alkanes, the alkyl groups are listed...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 27QAPCh. 20 - Prob. 28QAPCh. 20 - Prob. 29QAPCh. 20 - Prob. 30QAPCh. 20 - . What is pyrolytic cracking, and why is the...Ch. 20 - Prob. 32QAPCh. 20 - . Explain why alkanes are relatively unreactive.Ch. 20 - Prob. 34QAPCh. 20 - . Indicate the missing molecule in each of the...Ch. 20 - Prob. 36QAPCh. 20 - Prob. 37QAPCh. 20 - Prob. 38QAPCh. 20 - Prob. 39QAPCh. 20 - Prob. 40QAPCh. 20 - Prob. 41QAPCh. 20 - Prob. 42QAPCh. 20 - Prob. 43QAPCh. 20 - Prob. 44QAPCh. 20 - Prob. 45QAPCh. 20 - Prob. 46QAPCh. 20 - Prob. 47QAPCh. 20 - Prob. 48QAPCh. 20 - Prob. 49QAPCh. 20 - . Benzene exhibits resonance Explain this...Ch. 20 - . How is a monosubstituted benzene named? Give the...Ch. 20 - Prob. 52QAPCh. 20 - Prob. 53QAPCh. 20 - . What do the prefixes ortho-, meta-, and para-...Ch. 20 - Prob. 55QAPCh. 20 - Prob. 56QAPCh. 20 - Prob. 57QAPCh. 20 - Prob. 58QAPCh. 20 - . What functional group characterizes an alcohol?...Ch. 20 - Prob. 60QAPCh. 20 - . Give the systematic name for each of the...Ch. 20 - . Is 1-pentanol a primary, secondary, or tertiary...Ch. 20 - . Why is methanol sometimes called wood alcohol?...Ch. 20 - Prob. 64QAPCh. 20 - . Write the equation for the synthesis of ethanol...Ch. 20 - . What is the simplest aromatic alcohol commonly...Ch. 20 - Prob. 67QAPCh. 20 - Prob. 68QAPCh. 20 - Prob. 69QAPCh. 20 - Prob. 70QAPCh. 20 - Prob. 71QAPCh. 20 - Prob. 72QAPCh. 20 - Prob. 73QAPCh. 20 - Prob. 74QAPCh. 20 - Prob. 75QAPCh. 20 - Prob. 76QAPCh. 20 - Prob. 77QAPCh. 20 - Prob. 78QAPCh. 20 - Prob. 79QAPCh. 20 - Prob. 80QAPCh. 20 - Prob. 81QAPCh. 20 - . Draw a structural formula for each of the...Ch. 20 - Prob. 83QAPCh. 20 - Prob. 84QAPCh. 20 - Prob. 85QAPCh. 20 - Prob. 86QAPCh. 20 - Prob. 87QAPCh. 20 - Prob. 88QAPCh. 20 - Prob. 89APCh. 20 - Prob. 90APCh. 20 - Prob. 91APCh. 20 - Prob. 92APCh. 20 - Prob. 93APCh. 20 - . The systematic names of all saturated...Ch. 20 - Prob. 95APCh. 20 - Prob. 96APCh. 20 - Prob. 97APCh. 20 - Prob. 98APCh. 20 - Prob. 99APCh. 20 - . With very reactive agents, such as the halogen...Ch. 20 - . Alkenes and alkynes are characterized by their...Ch. 20 - Prob. 102APCh. 20 - Prob. 103APCh. 20 - Prob. 104APCh. 20 - Prob. 105APCh. 20 - Prob. 106APCh. 20 - Prob. 107APCh. 20 - Prob. 108APCh. 20 - Prob. 109APCh. 20 - Prob. 110APCh. 20 - Prob. 111APCh. 20 - Prob. 112APCh. 20 - Prob. 113APCh. 20 - Prob. 114APCh. 20 - Prob. 115APCh. 20 - . Give the systematic name for each of the...Ch. 20 - Prob. 117APCh. 20 - Prob. 118APCh. 20 - Prob. 119APCh. 20 - Prob. 120APCh. 20 - Prob. 121APCh. 20 - Prob. 122APCh. 20 - Prob. 123APCh. 20 - Prob. 124APCh. 20 - Prob. 125APCh. 20 - Prob. 126APCh. 20 - Prob. 127APCh. 20 - Prob. 128APCh. 20 - Prob. 129APCh. 20 - Prob. 130APCh. 20 - Prob. 131APCh. 20 - . Write the formula for the missing reactant or...Ch. 20 - Prob. 133APCh. 20 - Prob. 134APCh. 20 - . Name each of the following aromatic or...Ch. 20 - Prob. 136APCh. 20 - Prob. 137APCh. 20 - Prob. 138APCh. 20 - Prob. 139APCh. 20 - Prob. 140APCh. 20 - Prob. 141APCh. 20 - . Name each of the following alkanes....Ch. 20 - Prob. 143CPCh. 20 - Prob. 144CPCh. 20 - Prob. 145CPCh. 20 - Prob. 146CPCh. 20 - Prob. 147CP
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