Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 20, Problem 63P
Interpretation Introduction
Interpretation: The role of progesterone and similar compounds in contraceptive pills needs to be explained.
Concept Introduction: The characterization of steroids is done by the presence of four ring structures arranged in a specific configuration in the compound. They are found in the cell membrane and influence the fluidity of the membrane. They work by decreasing inflammation and reducing the activity of the immune system.
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(c) The following data have been obtained for the hydrolysis of sucrose, C12H22O11, to
glucose, C6H12O6, and fructose C6H12O6, in acidic solution:
C12H22O11 + H2O → C6H12O6 + C6H12O6
[sucrose]/mol dm³
t/min
0
0.316
14
0.300
39
0.274
60
0.256
80
0.238
110
0.211
(i) Graphically prove the order of the reaction and determine the rate constant of the
reaction.
(ii) Determine the half-life, t½ for the hydrolysis of sucrose.
(III) adsorbent
(b) Adsorption of the hexacyanoferrate (III) ion, [Fe(CN)6] ³, on y-Al2O3 from aqueous
solution was examined. The adsorption was modelled using a modified Langmuir
isotherm, yielding the following values of Kat pH = 6.5:
(ii)
T/K
10-10 K
280
2.505
295
1.819
310
1.364
325
1.050
Determine the enthalpy of adsorption, AadsHⓇ.
If the reported value of entropy of adsorption, Aads Se = 146 J K-1 mol-1 under the above
conditions, determine Aads Gº.
with full details solution please
Chapter 20 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 20.2 - Prob. 20.1QCCh. 20.4 - Prob. 20.2QCCh. 20.5 - Prob. 20.3QCCh. 20.7 - Prob. 20.4QCCh. 20.8 - Prob. 20.5QCCh. 20.9 - Prob. 20.6QCCh. 20.10 - Prob. 20.7QCCh. 20.13 - Prob. 20.8QCCh. 20 - Prob. 1PCh. 20 - 21-2 Why are fats a good source of energy for...
Ch. 20 - 21-3 Proteins, nucleic acids, and carbohydrates...Ch. 20 - Prob. 4PCh. 20 - Prob. 5PCh. 20 - Draw the line-angle structure for the following:...Ch. 20 - Prob. 7PCh. 20 - What is the difference between the -system and...Ch. 20 - Prob. 9PCh. 20 - Prob. 10PCh. 20 - Prob. 11PCh. 20 - Prob. 12PCh. 20 - For the diglycerides in Problem 12 , predict which...Ch. 20 - 21-8 Predict which acid in each pair has the...Ch. 20 - Prob. 15PCh. 20 - Prob. 16PCh. 20 - Prob. 17PCh. 20 - Prob. 18PCh. 20 - 21-13 Rank the following in order of increasing...Ch. 20 - Prob. 20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - 21-29 Name all the groups of complex lipids that...Ch. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - 21-39 How does VLDL become LDL?Ch. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - 21-44 Describe the difference in structure between...Ch. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - Prob. 47PCh. 20 - 21-48 List all of the functional groups that make...Ch. 20 - 21-49 Explain how the constant elimination of bile...Ch. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - 21-52 What are the chemical and physiological...Ch. 20 - 21-53 How does aspirin, an anti-inflammatory drug,...Ch. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - For each of the processes below, tell whether it...Ch. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - 21-68 What is the role of taurine in lipid...Ch. 20 - Prob. 71PCh. 20 - 21-70 How many different triglycerides can you...Ch. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - 21-76 Which part of LDL interacts with the LDL...Ch. 20 - Prob. 79PCh. 20 - Prob. 80PCh. 20 - Prob. 81PCh. 20 - Prob. 82PCh. 20 - Prob. 83PCh. 20 - 21-82 Suggest a reason why the same protein system...Ch. 20 - Prob. 85PCh. 20 - Prob. 86PCh. 20 - 21-85 Which of the following statements is (are)...Ch. 20 - Prob. 88PCh. 20 - 21-87 Which statements are consistent with the...Ch. 20 - Prob. 90PCh. 20 - Prob. 91PCh. 20 - 21-90 To what extent do lipids and carbohydrates...Ch. 20 - Prob. 93PCh. 20 - Prob. 94PCh. 20 - Prob. 95PCh. 20 - Prob. 96PCh. 20 - Prob. 97PCh. 20 - Prob. 98PCh. 20 - Prob. 99PCh. 20 - Prob. 100PCh. 20 - Prob. 101PCh. 20 - 21-100 What are the functions of a cell membrane?...Ch. 20 - 21-101 Glycerophospholipids tend to have both a...Ch. 20 - Prob. 104P
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