Physics for Scientists and Engineers with Modern Physics
4th Edition
ISBN: 9780131495081
Author: Douglas C. Giancoli
Publisher: Addison-Wesley
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Textbook Question
Chapter 20, Problem 54P
(I) Use Eq. 20–14 to determine the entropy of each of the five macrostates listed in the Table on page 546.
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(a) Calculate the change in entropy when a 0.125-kg chunk of ice melts at 0 °C. Assume the melting occurs reversibly.
(2) [
Describe briefly why the following statements are wrong.
(i) "Hot cup of coffee becoming cold spontaneously is an entropy-decreasing process. So the
law of entropy increase is violated in this situation."
(ii) "Air conditioners require bulky external unit, exhausting heat to outside. With the
technology constantly advancing, external unit will be eliminated in the future."
(a) Calculate the change in entropy when a 0.125-kg chunk of ice melts at 0◦C.
Assume the melting occurs reversibly.
(b) Suppose heat is now drawn reversibly from the 0◦ meltwater, causing a
decrease in entropy of 112 J/K. How much ice freezes in the process?
Chapter 20 Solutions
Physics for Scientists and Engineers with Modern Physics
Ch. 20.2 - An adiabatic process is defined as one in which no...Ch. 20.3 - A motor is running with an intake temperature TH =...Ch. 20.6 - A 1.00.kg piece of ice at 0C melts very slowly to...Ch. 20.9 - Prob. 1EECh. 20 - Prob. 1QCh. 20 - Can you warm a kitchen in winter by leaving the...Ch. 20 - Would a definition of heat engine efficiency as e...Ch. 20 - What plays the role of high-temperature and...Ch. 20 - Which will give the greater improvement in the...Ch. 20 - The oceans contain a tremendous amount of thermal...
Ch. 20 - Discuss the factors that keep real engines from...Ch. 20 - Prob. 8QCh. 20 - Describe a process in nature that is nearly...Ch. 20 - (a) Describe how heat could be added to a system...Ch. 20 - Suppose a gas expands to twice its original volume...Ch. 20 - Give three examples, other than those mentioned in...Ch. 20 - Which do you think has the greater entropy, 1 kg...Ch. 20 - (a) What happens if you remove the lid of a bottle...Ch. 20 - Prob. 15QCh. 20 - Prob. 16QCh. 20 - Prob. 17QCh. 20 - The first law of thermodynamics is sometimes...Ch. 20 - Powdered milk is very slowly (quasistatically)...Ch. 20 - Two identical systems are taken from state a to...Ch. 20 - It can he said that the total change in entropy...Ch. 20 - Use arguments, other than the principle of entropy...Ch. 20 - (I) A heat engine exhausts 7800 J of heat while...Ch. 20 - (I) A certain power plant puts out 580 MW of...Ch. 20 - (II) A typical compact car experiences a total...Ch. 20 - (II) A four-cylinder gasoline engine has an...Ch. 20 - (II) The burning of gasoline in a car releases...Ch. 20 - (II) Figure 2017 is a PV diagram for a reversible...Ch. 20 - (III) The operation of a diesel engine can be...Ch. 20 - (I) What is the maximum efficiency of a heat...Ch. 20 - (I) It is not necessary that a heat engines hot...Ch. 20 - (II) A heal engine exhausts its heat at 340C and...Ch. 20 - (II) (a) Show that the work done by a Carnot...Ch. 20 - (II) A Carnot engines operating temperatures are...Ch. 20 - (II) A nuclear power plant operates at 65% of its...Ch. 20 - (II) A Carnot engine performs work at the rate of...Ch. 20 - (II) Assume that a 65 kg hiker needs 4.0 103 kcal...Ch. 20 - (II) A particular car does work at the rate of...Ch. 20 - (II) A heat engine utilizes a heat source at 580C...Ch. 20 - (II) The working substance of a certain Carnot...Ch. 20 - (III) A Carnot cycle, shown in Fig. 20-7, has the...Ch. 20 - (III) One mole of monatomic gas undergoes a Carnot...Ch. 20 - (III) In an engine that approximates the Otto...Ch. 20 - (I) If an ideal refrigerator keeps its contents at...Ch. 20 - (I) The low temperature of a freezer cooling coil...Ch. 20 - (II) An ideal (Carnot) engine has an efficiency of...Ch. 20 - (II) An ideal heal pump is used to maintain the...Ch. 20 - (II) A restaurant refrigerator has a coefficient...Ch. 20 - (II) A heat pump is used to keep a house warm at...Ch. 20 - (II) (a) Given that the coefficient of performance...Ch. 20 - (II) A Carnot refrigerator (reverse of a Carnot...Ch. 20 - (II) A central heat pump updating as an air...Ch. 20 - (II) What volume of water at 0C can a freezer make...Ch. 20 - (I) What is the change in entropy of 250g of steam...Ch. 20 - (I) A 7.5-kg box having an initial speed of 4.0m/s...Ch. 20 - (I) What is the change in entropy of 1.00 m3 of...Ch. 20 - (II) If 1.00m3 of water at 0C is frozen and cooled...Ch. 20 - (II) If 0.45kg f water at 100C is changed by a...Ch. 20 - (II) An aluminum rod conducts 9.50 cal/s from a...Ch. 20 - (II) A 2.8-kg piece of aluminum at 43.0C is placed...Ch. 20 - (II) An ideal gas expands isothermally (T = 410 K)...Ch. 20 - (II) When 2.0 kg of water at 12.0C is mixed with...Ch. 20 - (II) (a) An ice cube of mass m at 0C is placed in...Ch. 20 - (II) The temperature of 2.0mol of an ideal...Ch. 20 - (II) Calculate the change in entropy of 1.00kg of...Ch. 20 - (II) An ideal gas of n moles undergoes the...Ch. 20 - (II) Two samples of an ideal gas are initially at...Ch. 20 - (II) A 150-g insulated aluminum cup at 15C is...Ch. 20 - (II) (a) Why would you expect the total entropy...Ch. 20 - (II) 1.00 mole of nitrogen (N2) gas and 1.00 mole...Ch. 20 - (II) Thermodynamic processes are sometimes...Ch. 20 - (III) The specific heat per mole of potassium at...Ch. 20 - (III) Consider an ideal gas of n moles with molar...Ch. 20 - (III) A general theorem states that the amount of...Ch. 20 - (III) Determine the work available in a 3.5-kg...Ch. 20 - (I) Use Eq. 2014 to determine the entropy of each...Ch. 20 - (II) Suppose that you repeatedly shake six coins...Ch. 20 - (II) Calculate the relative probabilities, when...Ch. 20 - (II) (a) Suppose you have four coins, all with...Ch. 20 - Prob. 58PCh. 20 - (II) Energy may be stored for use during peak...Ch. 20 - (II) Solar cells (Fig. 20-22) can produce about...Ch. 20 - Prob. 61PCh. 20 - It has been suggested that a heat engine could be...Ch. 20 - A heat engine takes a diatomic gas around the...Ch. 20 - A 126.5-g insulated aluminum cup at 18.00C is...Ch. 20 - (a) At a steam power plant, steam engines work in...Ch. 20 - (II) Refrigeration units can be rated in tons. A...Ch. 20 - Prob. 67GPCh. 20 - (a) What is the coefficient of performance of an...Ch. 20 - The operation of a certain heat engine takes an...Ch. 20 - A car engine whose output power is 155 hp operates...Ch. 20 - Suppose a power plant delivers energy at 850 MW...Ch. 20 - 1.00 mole of an ideal monatomic gas at STP first...Ch. 20 - Two 1100-kg cars are traveling 75 km/h in opposite...Ch. 20 - Metabolizing 1.0 kg of fat results in about 3.7 ...Ch. 20 - A cooling unit for a new freezer has an inner...Ch. 20 - Prob. 76GPCh. 20 - The Stirling cycle shown in Fig 20-27, is useful...Ch. 20 - A gas turbine operates under the Brayton cycle,...Ch. 20 - Thermodynamic processes can be represented not...Ch. 20 - An aluminum can, with negligible heat capacity, is...Ch. 20 - Prob. 81GPCh. 20 - A bowl contains a large number of red, orange, and...
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- Is it possible for a system to have an entropy change if it neither absorbs nor emits heat during a reversible? transition? What happens it the process is irreversible?arrow_forwardIn an isochoric process, heat is added to 10 mol of monoatomic ideal gas whose temperature increases from 273 to 373 K. What is the entropy change of the gas?arrow_forwardA cylinder contains 500 g of helium at 120 atm and 20 . The valve is leaky, and all the gas slowly escapes isothermally into the atmosphere. Use the results of the preceding problem to determine the resulting change in entropy of the universe.arrow_forward
- Suppose 20 g of ice at 0 is added to 300 g of water at 60 . What is the total change in entropy of the mixture after it reaches thermal equilibrium?arrow_forwardA Carnot engine operates between 550 and 20 baths and produces 300 kJ of energy in each cycle. Find the change in entropy of the (a) hot bath and (b) cold bath, in each Carnot cycle?arrow_forwardA copper rod of cross-sectional area 5.0 cm2 and length 5.0 m conducts heat from a heat reservoir at 373 K to one at 273 K. What is the time rate of change of the universe's entropy for this process?arrow_forward
- A 0.50-kg piece of aluminum at 250 is dropped into 1.0 kg of water at 20 . After equilibrium is reached, what is the net entropy change of the system?arrow_forwardFor the Carnot cycle of Figure 4.12, what is the entropy change of the hot reservoir, the cold reservoir, and the universe? Figure 4.11 The four processes of the Carnot cycle. The working substance is assumed to be an ideal gas whose thermodynamic path MNOP is represented in Figure 4.12. Figure 4.12 The total work done by the gas in the Carnot cycle is shown and given by the area enclosed by the loop MNOPM.arrow_forwardCheck Your Understanding In Example 4.7, the spontaneous flow of heat from a hot object to a cold object results in a net increase in entropy of the universe. Discuss how this result can be related to an increase in disorder of the system.arrow_forward
- (a) infinitesimal amount of heat is added reversibly to a system. By combining the first and second laws, show that dU=TdSdW. (b) When heat is added to an ideal gas, its temperature and volume change from T1 and V1 to T2 and V2 . Show that the entropy change of n moles of the gas is given by S=CnvlnT2T1nRlnV2V1 .arrow_forwardTwo hundred joules of heat are removed from a heat at a temperature of 200 K. What is the entropy change of the reservoir?arrow_forwardCheck Your Understanding A Carnot engine operates between reservoirs at 400 and 30 . (a) What is the efficiency of the engine? (b) If the engine does 5.0 J of work per cycle, how much heat per cycle does it absorb from the high-temperature reservoir? (c) How much heat per cycle does it exhaust to the cold-temperature reservoir? (d) What temperatures at the cold reservoir would give the minimum and maximum efficiency?arrow_forward
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