The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated. Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds. To determine: The correct name of the complex [ Cu ( NH 3 ) 4 ] Cl 2 .

Question

The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

Answer 1

Question

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

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The table includes macrostates characterized by 4 energy levels (&) that are equally spaced but with different degrees of occupation. a) Calculate the energy of all the macrostates (in joules). See if they all have the same energy and number of particles. b) Calculate the macrostate that is most likely to exist. For this macrostate, show that the population of the levels is consistent with the Boltzmann distribution. macrostate 1 macrostate 2 macrostate 3 ε/k (K) Populations Populations Populations 300 5 3 4 200 7 9 8 100 15 17 16 0 33 31 32 DATO: k = 1,38×10-23 J K-1

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In an experiment, the viscosity of water was measured at different temperatures and the table was constructed from the data obtained. a) Calculate the activation energy of viscous flow (kJ/mol). b) Calculate the viscosity at 30°C. T/°C 0 20 40 60 80 η/cpoise 1,972 1,005 0,656 0,469 0,356

Answer 2

Question

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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Answer 3

Question

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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Answer 4

Question

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Expert Solution & Answer

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Answer 5

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 6

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

Answer 7

Chapter 20, Problem 4RQ

(a)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Cu(NH3)4]Cl2 .

Answer 8

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

Answer 9

(b)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex [Ni(en)2]SO4 .

Answer 10

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

Answer 11

(c)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex K[Cr(H2O)2]Cl4 .

Answer 12

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 13

(d)

Interpretation Introduction

Interpretation: The incorrect names of some coordination compounds are given. The correct names and the reason behind the wrong naming is to be stated.

Concept introduction: The naming of coordination compounds is done to present an easy way to represent the formulas and their names in a systematic manner. When the isomers are to be studied, there the nomenclature plays an important role. Certain rules are assigned for the nomenclature of the coordination compounds.

To determine: The correct name of the complex Na4[Co(CN)4C2O4] .

Answer 14

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Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQ Ch. 20 - Prob. 3RQ Ch. 20 - Prob. 4RQ Ch. 20 - Prob. 5RQ Ch. 20 - Prob. 6RQ Ch. 20 - Prob. 7RQ Ch. 20 - Prob. 8RQ Ch. 20 - Prob. 9RQ Ch. 20 - Prob. 10RQ

Solution Summary: The author explains that the nomenclature of coordination compounds is used to represent the formulas and their names in a systematic manner.

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