The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated. Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin. To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Question

Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Answer 1

Question

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

Q: Arrange BCC and Fec metals, in sequence from the Fable (Dr. R's slides) and Calculate Volume and Density. Aa BCC V 52 5 SFCC

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Answer 2

Question

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

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Answer 3

Question

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

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Answer 4

Question

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

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Answer 5

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 6

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 7

Chapter 20, Problem 12Q

(a)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 8

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 9

(b)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 10

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

Answer 11

(c)

Interpretation Introduction

Interpretation: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for each of the given coordination compounds is to be stated.

Concept introduction: The electrons in the d orbital of a transition metal split into high and low energy orbitals when ligands are attached to it. The energy difference between these two levels depends upon the properties of both metal and the ligands. If the ligand is strong, then splitting will be high and the complex will be low spin. If the ligand is weak, then splitting will be less and the complex will be high spin.

To determine: The complex ion, the counter ions, the electronic configuration of the transition metal and geometry of complex ion for the given coordination compound.

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Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQ Ch. 20 - Prob. 3RQ Ch. 20 - Prob. 4RQ Ch. 20 - Prob. 5RQ Ch. 20 - Prob. 6RQ Ch. 20 - Prob. 7RQ Ch. 20 - Prob. 8RQ Ch. 20 - Prob. 9RQ Ch. 20 - Prob. 10RQ

Solution Summary: The author explains how the complex ion, counter ions, electronic configuration of the transition metal, and geometry of a coordination compound are to be stated.

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Chapter 20 Solutions