The formulas of the given complex compounds are to be stated. Concept introduction: Rules followed in the naming of coordination compound: Greek prefix is used to express the number of ligands. Roman numeral is used to denote the oxidation state of metal ion. In case of more than one type of ligand present in a compound, they are named alphabetically. The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals. If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt. To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Question

2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Answer 1

Question

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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2. Name the following hydrocarbons. (9 marks) a) HHHHHHHH H-C-C- H-O-S b) HCEC-CH3 H H H H H d) c) H C=C- H H H e) CH3 CH3 CH2CH=CH-CH=CHCH3 HHHH H-C-C-C-C-H H HH H f) large CH2CH3 pola H3C section lovels tower, able ocart firs g) Tower H3C-CH2 then in H3C-CH-CH-CH3 enblbano bne noitsidab Copyright © 2008. Durham Continuing Education CH3

Name the molecules & Identify any chiral center CH3CH2CH2CHCH₂CH₂CH₂CH₂ OH CH₂CHCH2CH3 Br CH3 CH3CHCH2CHCH2CH3 CH3

Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electrons-pushing arrows for the following reaction or mechanistic step(s).

Answer 2

Question

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 3

Question

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 4

Question

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

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Answer 5

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 6

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Answer 7

Chapter 20, Problem 37E

(a)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound potassium tetrachlorocobaltate(II).

Answer 8

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

Answer 9

(b)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound aquatricarbonylplatinum(II) bromide.

Answer 10

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

Answer 11

(c)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound sodium dicyanobis(oxalato)ferrate(III).

Answer 12

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 13

(d)

Interpretation Introduction

Interpretation: The formulas of the given complex compounds are to be stated.

Concept introduction: Rules followed in the naming of coordination compound:

Greek prefix is used to express the number of ligands.

Roman numeral is used to denote the oxidation state of metal ion.

In case of more than one type of ligand present in a compound, they are named alphabetically.

The suffix ‘-ate’ is added to metal ion if complex ion contains negative charge. Latin names are also used to identify the name of metals.

If counter ions are present in complex compound, then cation is named first which is the name of element, whereas anion is named last which is the name of salt.

To determine: The formula of the complex compound triamminechloroethylenediaminechromium(III) iodide

Answer 14

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Ch. 20 - What two first-row transition metals have...Ch. 20 - Prob. 2RQ Ch. 20 - Prob. 3RQ Ch. 20 - Prob. 4RQ Ch. 20 - Prob. 5RQ Ch. 20 - Prob. 6RQ Ch. 20 - Prob. 7RQ Ch. 20 - Prob. 8RQ Ch. 20 - Prob. 9RQ Ch. 20 - Prob. 10RQ

Solution Summary: The author explains the formulas of the complex compound potassium tetrachlorocobaltate(II). Greek prefix is used to express the number of ligands and Roman numeral to denote the

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