Chemistry and Chemical Reactivity - AP Edition
10th Edition
ISBN: 9781337399203
Author: Kotz
Publisher: CENGAGE L
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Chapter 20, Problem 44GQ
Interpretation Introduction
Interpretation: The equilibrium constant for the reaction
Concept introduction:
Equilibrium constant in terms of concentration
Equilibrium constant and Gibbs free energy:
Relation between Gibbs free energy , Enthalpy and Entropy:
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Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
Chapter 20 Solutions
Chemistry and Chemical Reactivity - AP Edition
Ch. 20.7 - Prob. 1.1ACPCh. 20.7 - Prob. 1.2ACPCh. 20.7 - Prob. 1.3ACPCh. 20.7 - Prob. 1.4ACPCh. 20.7 - Prob. 1.5ACPCh. 20.7 - Assume that a sample of hard water contains 50....Ch. 20.7 - One way to remove the calcium carbonate residue in...Ch. 20 - Prob. 1PSCh. 20 - Prob. 2PSCh. 20 - In the discussion on the composition of air,...
Ch. 20 - Prob. 4PSCh. 20 - Prob. 5PSCh. 20 - Prob. 6PSCh. 20 - Prob. 7PSCh. 20 - Prob. 8PSCh. 20 - Prob. 11PSCh. 20 - Although there are a number of...Ch. 20 - Prob. 14PSCh. 20 - Prob. 15PSCh. 20 - Prob. 16PSCh. 20 - Which of the following is a renewable energy...Ch. 20 - Prob. 18PSCh. 20 - Prob. 19PSCh. 20 - Prob. 21PSCh. 20 - The enthalpy of combustion of isooctane (C8H18),...Ch. 20 - Energy consumption in the United States amounts to...Ch. 20 - Prob. 24PSCh. 20 - Prob. 25PSCh. 20 - Prob. 27PSCh. 20 - Prob. 30PSCh. 20 - In methane hydrate the methane molecule is trapped...Ch. 20 - Prob. 32PSCh. 20 - Prob. 33PSCh. 20 - Prob. 34PSCh. 20 - Prob. 35PSCh. 20 - Prob. 36PSCh. 20 - Prob. 37PSCh. 20 - Prob. 38PSCh. 20 - Dinitrogen monoxide, N2O (commonly called nitrous...Ch. 20 - Prob. 40PSCh. 20 - Prob. 41PSCh. 20 - Prob. 42PSCh. 20 - Prob. 43GQCh. 20 - Prob. 44GQCh. 20 - Prob. 45GQCh. 20 - Prob. 46GQCh. 20 - Prob. 47GQCh. 20 - Prob. 48GQCh. 20 - Prob. 49ILCh. 20 - Prob. 50ILCh. 20 - Define the terms renewable and nonrenewable as...Ch. 20 - Prob. 52SCQCh. 20 - Prob. 53SCQCh. 20 - Prob. 54SCQCh. 20 - Prob. 55SCQCh. 20 - What is the likelihood that hydrogen (H2) will...Ch. 20 - Prob. 57SCQCh. 20 - Which sulfur compounds are atmospheric pollutants?...
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