Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 20, Problem 24E
Explain, in terms of Figure 20.2, how unstable heavy nuclides (atomic number > 83) may decompose to form nuclides of greater stability (a) if they are below the band of stability and (b) if they are above the band of stability.
Figure 20.2 This plot shows the nuclides that are known to exist and those are stable. The stable nuclides are indicated in blue, and the unstable nuclides are indicated in green. Note that all
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For each reaction below, decide if the first stable organic product that forms in solution will create a new CC bond, and check
the appropriate box.
Next, for each reaction to which you answered "Yes" to in the table, draw this product in the drawing area below.
Note for advanced students: for this problem, don't worry if you think this product will continue to react under the current conditions
- just focus on the first stable product you expect to form in solution.
?
NH2
MgBr
Will the first product that forms in this reaction
create a new CC bond?
○ Yes
○ No
MgBr
?
Will the first product that forms in this reaction
create a new CC bond?
O Yes
O No
Click and drag to start drawing a
structure.
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G
x
c
olo
Ar
HE
Predicting
As the lead product manager at OrganometALEKS Industries, you are trying to decide if the following reaction will make a molecule
with a new C - C bond as its major product:
H₂N
O
H
1.
?
2. H3O+
If this reaction will work, draw the major organic product or products you would expect in the drawing area below. If there's more
than one major product, you can draw them in any arrangement you like. Be sure you use wedge and dash bonds if necessary, for
example to distinguish between major products with different stereochemistry.
0
If the major products of this reaction won't have a new CC bond, just check the box under the drawing area and leave it blank.
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Explanation
Check
Click and drag to start drawing a
structure.
Highlight the chirality (or stereogenic) center(s) in the given compound. A compound may have one or more stereogenic centers.
OH
OH
OH
OH
OH
OH
Chapter 20 Solutions
Chemistry Atoms First2e
Ch. 20 - Write the following isotopes in hyphenated form...Ch. 20 - Write the following isotopes in nuclide notation...Ch. 20 - For the following isotopes that have missing...Ch. 20 - For each of the isotopes in Exercise 20.1,...Ch. 20 - Write the nuclide notation, including charge if...Ch. 20 - Calculate the density of the M1224g nucleus in...Ch. 20 - What are the two principal differences between...Ch. 20 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 20 - Which of the following nuclei lie within the band...Ch. 20 - Which of the following nuclei lie within the band...
Ch. 20 - Write a brief description or definition of each of...Ch. 20 - Which of the various particles ( particles, ...Ch. 20 - Complete each of the following equations by adding...Ch. 20 - Complete each 0f the following equations: (a)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 20 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 20 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 20 - What are the types of radiation emitted by the...Ch. 20 - That changes occur to the atomic number and mass...Ch. 20 - What is the change in the nucleus that results...Ch. 20 - Many nuclides with atomic numbers greater than 83...Ch. 20 - Why is electron capture accompanied by the...Ch. 20 - Explain, in terms of Figure 20.2, how unstable...Ch. 20 - Which of the following nuclei is most likely to...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - Predict by what mode(s) of spontaneous radioactive...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Define the term half-life and illustrate it with...Ch. 20 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 20 - 239Pu is a nuclear waste byproduct with a...Ch. 20 - The isotope 208Tl undergoes decay with a...Ch. 20 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 20 - The isotope S3890r one of the extremely hazardous...Ch. 20 - Technetium-99 is often used for assessing heart,...Ch. 20 - What is the age of mummified primate skin that...Ch. 20 - A sample of rock was found to contain 8.23 mg of...Ch. 20 - A laboratory investigation shows that a sample of...Ch. 20 - Plutonium was detected in trace amounts in natural...Ch. 20 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 20 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 20 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write the balanced nuclear equation for the...Ch. 20 - How does nuclear fission differ from nuclear...Ch. 20 - Both fusion and fission are nuclear reactions. Why...Ch. 20 - Cite the conditions necessary for a nuclear chain...Ch. 20 - Describe the components of a nuclear reactor.Ch. 20 - In usual practice, both a moderator and control...Ch. 20 - Describe how the potential energy of uranium is...Ch. 20 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 20 - How can a radioactive nuclide be used to show that...Ch. 20 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 20 - Iodine that enters the body is stored in the...Ch. 20 - If a hospital were storing radioisotopes, what is...Ch. 20 - Based on what is known about Radon-222’s primary...Ch. 20 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 20 - A scientist is studying a 2.234 g sample of...Ch. 20 - Given specimens neon-24 (t1/2=3.38min) and...
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- Using wedge-and-dash bonds, modify the bonds on the chiral carbon in the molecule below so the molecule has R stereochemical configuration. NH H Br X टेarrow_forwardProvide photos of models of the following molecules. (Include a key for identification of the atoms) 1,2-dichloropropane 2,3,3-trimethylhexane 2-bromo-3-methybutanearrow_forwardPlease draw the structure in the box that is consistent with all the spectral data and alphabetically label all of the equivalent protons in the structure (Ha, Hb, Hc....) in order to assign all the proton NMR peaks. The integrations are computer generated and approximate the number of equivalent protons. Molecular formula: C13H1802 14 13 12 11 10 11 (ppm) Structure with assigned H peaks 2.08 3.13arrow_forward
- A 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forwardFirefly luciferin exhibits three rings. Identify which of the rings are aromatic. Identify which lone pairs are involved in establishing aromaticity. The lone pairs are labeled A-D below.arrow_forwardA 0.10 M solution of acetic acid (CH3COOH, Ka = 1.8 x 10^-5) is titrated with a 0.0250 M solution of magnesium hydroxide (Mg(OH)2). If 10.0 mL of the acid solution is titrated with 10.0 mL of the base solution, what is the pH of the resulting solution?arrow_forward
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