Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 20, Problem 27E
The following nuclei do not lie in the band of stability. How would they be expected to decay?.
(a)
(b)
(c)
(d)
(e)
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10.
Stereochemistry. Assign R/S stereochemistry for the chiral center indicated on the
following compound. In order to recieve full credit, you MUST SHOW YOUR WORK!
H₂N
CI
OH
CI
カー
11. () Stereochemistry. Draw all possible stereoisomers of the following compound. Assign
R/S configurations for all stereoisomers and indicate the relationship between each as
enantiomer, diastereomer, or meso.
NH2
H
HNH,
-18
b)
8.
Indicate whether the following carbocation rearrangements are likely to occur
Please explain your rational using 10 words or less
not likely to occur
• The double bond is still in the
Same position
+
Likely
to oc
occur
WHY?
-3
H3C
Brave
Chair Conformers. Draw the chair conformer of the following substituted
cyclohexane. Peform a RING FLIP and indicate the most stable
conformation and briefly explain why using 20 words or less.
CI
2
-cobs ??
MUST INDICATE H -2
-2
Br
EQ
Cl
OR
AT
Br
H&
most stable
WHY?
- 4
CH
12
Conformational Analysis. Draw all 6 conformers (one above each letter) of the
compound below looking down the indicated bond. Write the letter of the
conformer with the HIGHEST and LOWEST in energies on the lines provided.
NOTE: Conformer A MUST be the specific conformer of the structure as drawn below
-4 NOT
HOH
OH
3
Conformer A:
Br
OH
A
Samo
Br H
04
Br
H
H3
CH₂
H
anti
stagere
Br CH
clipsed
H
Brott
H
IV
H
MISSING 2
-2
B
C
D
E
F
X
6
Conformer with HIGHEST ENERGY:
13. (1
structure
LOWEST ENERGY:
Nomenclature. a) Give the systematic (IUPAC) name structure. b) Draw the
corresponding to this name. HINT: Do not forget to indicate stereochemistry
when applicable.
a)
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2
"Br
{t༐B,gt)-bemn€-nehpརི་ཚ༐lnoa
Parent name (noname)
4 Bromo
Sub = 2-methylethyl-4 Bromo nonane
b) (3R,4S)-3-chloro-4-ethyl-2,7-dimethyloctane
# -2
-2
Chapter 20 Solutions
Chemistry Atoms First2e
Ch. 20 - Write the following isotopes in hyphenated form...Ch. 20 - Write the following isotopes in nuclide notation...Ch. 20 - For the following isotopes that have missing...Ch. 20 - For each of the isotopes in Exercise 20.1,...Ch. 20 - Write the nuclide notation, including charge if...Ch. 20 - Calculate the density of the M1224g nucleus in...Ch. 20 - What are the two principal differences between...Ch. 20 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 20 - Which of the following nuclei lie within the band...Ch. 20 - Which of the following nuclei lie within the band...
Ch. 20 - Write a brief description or definition of each of...Ch. 20 - Which of the various particles ( particles, ...Ch. 20 - Complete each of the following equations by adding...Ch. 20 - Complete each 0f the following equations: (a)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 20 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 20 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 20 - What are the types of radiation emitted by the...Ch. 20 - That changes occur to the atomic number and mass...Ch. 20 - What is the change in the nucleus that results...Ch. 20 - Many nuclides with atomic numbers greater than 83...Ch. 20 - Why is electron capture accompanied by the...Ch. 20 - Explain, in terms of Figure 20.2, how unstable...Ch. 20 - Which of the following nuclei is most likely to...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - Predict by what mode(s) of spontaneous radioactive...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Define the term half-life and illustrate it with...Ch. 20 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 20 - 239Pu is a nuclear waste byproduct with a...Ch. 20 - The isotope 208Tl undergoes decay with a...Ch. 20 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 20 - The isotope S3890r one of the extremely hazardous...Ch. 20 - Technetium-99 is often used for assessing heart,...Ch. 20 - What is the age of mummified primate skin that...Ch. 20 - A sample of rock was found to contain 8.23 mg of...Ch. 20 - A laboratory investigation shows that a sample of...Ch. 20 - Plutonium was detected in trace amounts in natural...Ch. 20 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 20 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 20 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write the balanced nuclear equation for the...Ch. 20 - How does nuclear fission differ from nuclear...Ch. 20 - Both fusion and fission are nuclear reactions. Why...Ch. 20 - Cite the conditions necessary for a nuclear chain...Ch. 20 - Describe the components of a nuclear reactor.Ch. 20 - In usual practice, both a moderator and control...Ch. 20 - Describe how the potential energy of uranium is...Ch. 20 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 20 - How can a radioactive nuclide be used to show that...Ch. 20 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 20 - Iodine that enters the body is stored in the...Ch. 20 - If a hospital were storing radioisotopes, what is...Ch. 20 - Based on what is known about Radon-222’s primary...Ch. 20 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 20 - A scientist is studying a 2.234 g sample of...Ch. 20 - Given specimens neon-24 (t1/2=3.38min) and...
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- Indicate the variation in conductivity with concentration in solutions of strong electrolytes and weak electrolytes.arrow_forwardThe molar conductivity of a very dilute solution of NaCl has been determined. If it is diluted to one-fourth of the initial concentration, qualitatively explain how the molar conductivity of the new solution will compare with the first.arrow_forwardWhat does the phrase mean, if instead of 1 Faraday of electricity, Q coulombs (Q/F Faradays) pass through?arrow_forward
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