Chemistry Atoms First2e
2nd Edition
ISBN: 9781947172647
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 20, Problem 27E
The following nuclei do not lie in the band of stability. How would they be expected to decay?.
(a)
(b)
(c)
(d)
(e)
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
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fall
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Is it possible to reverse this tendency by adding H₂?
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be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
ப
acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
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Chapter 20 Solutions
Chemistry Atoms First2e
Ch. 20 - Write the following isotopes in hyphenated form...Ch. 20 - Write the following isotopes in nuclide notation...Ch. 20 - For the following isotopes that have missing...Ch. 20 - For each of the isotopes in Exercise 20.1,...Ch. 20 - Write the nuclide notation, including charge if...Ch. 20 - Calculate the density of the M1224g nucleus in...Ch. 20 - What are the two principal differences between...Ch. 20 - The mass of the atom N1123a is 22.9893 arm.. (a)...Ch. 20 - Which of the following nuclei lie within the band...Ch. 20 - Which of the following nuclei lie within the band...
Ch. 20 - Write a brief description or definition of each of...Ch. 20 - Which of the various particles ( particles, ...Ch. 20 - Complete each of the following equations by adding...Ch. 20 - Complete each 0f the following equations: (a)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Technetium-99 is prepared from 98Mo. Molybdenum-SS...Ch. 20 - The mass of the atom F919 is 18.99840 amu.. (a)...Ch. 20 - For the reaction C614N714+?, if 100.0 g of carbon...Ch. 20 - What are the types of radiation emitted by the...Ch. 20 - That changes occur to the atomic number and mass...Ch. 20 - What is the change in the nucleus that results...Ch. 20 - Many nuclides with atomic numbers greater than 83...Ch. 20 - Why is electron capture accompanied by the...Ch. 20 - Explain, in terms of Figure 20.2, how unstable...Ch. 20 - Which of the following nuclei is most likely to...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - The following nuclei do not lie in the band of...Ch. 20 - Predict by what mode(s) of spontaneous radioactive...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Write a nuclear reaction for each step in the...Ch. 20 - Define the term half-life and illustrate it with...Ch. 20 - A 1.00106 -g sample of nobelium, N102254o, has a...Ch. 20 - 239Pu is a nuclear waste byproduct with a...Ch. 20 - The isotope 208Tl undergoes decay with a...Ch. 20 - If 1.000 g of R88226a produces 0.0001 mL of the...Ch. 20 - The isotope S3890r one of the extremely hazardous...Ch. 20 - Technetium-99 is often used for assessing heart,...Ch. 20 - What is the age of mummified primate skin that...Ch. 20 - A sample of rock was found to contain 8.23 mg of...Ch. 20 - A laboratory investigation shows that a sample of...Ch. 20 - Plutonium was detected in trace amounts in natural...Ch. 20 - A B47e atom (mass = 7.0169 amu) decays into a L37i...Ch. 20 - A B58 atom (mass = 8.0246 amu) decays into B48...Ch. 20 - Isotopes such as 26Al (half-life: 7.2105 years)...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write a balanced equation for each of the...Ch. 20 - Write the balanced nuclear equation for the...Ch. 20 - How does nuclear fission differ from nuclear...Ch. 20 - Both fusion and fission are nuclear reactions. Why...Ch. 20 - Cite the conditions necessary for a nuclear chain...Ch. 20 - Describe the components of a nuclear reactor.Ch. 20 - In usual practice, both a moderator and control...Ch. 20 - Describe how the potential energy of uranium is...Ch. 20 - The mass of a hydrogen atom (11H) is 1.007825 arm;...Ch. 20 - How can a radioactive nuclide be used to show that...Ch. 20 - Technetium-99m has a half-life of 6.01 hours. If a...Ch. 20 - Iodine that enters the body is stored in the...Ch. 20 - If a hospital were storing radioisotopes, what is...Ch. 20 - Based on what is known about Radon-222’s primary...Ch. 20 - Given specimens uranium-232 (t1/2=68.9y) and...Ch. 20 - A scientist is studying a 2.234 g sample of...Ch. 20 - Given specimens neon-24 (t1/2=3.38min) and...
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