Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
expand_more
expand_more
format_list_bulleted
Videos
Question
Chapter 20, Problem 20.60QE
Interpretation Introduction
Interpretation:
The meaning of fixation of nitrogen with hydrogen has to be given.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Can you please explain why structure 3 is the correct answer? Please give a detailed explanation.
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
Chapter 20 Solutions
Chemistry Principles And Practice
Ch. 20 - Prob. 20.1QECh. 20 - Prob. 20.2QECh. 20 - Prob. 20.3QECh. 20 - Prob. 20.4QECh. 20 - Prob. 20.5QECh. 20 - Prob. 20.6QECh. 20 - Prob. 20.7QECh. 20 - Prob. 20.8QECh. 20 - Prob. 20.9QECh. 20 - Prob. 20.10QE
Ch. 20 - Prob. 20.11QECh. 20 - Prob. 20.12QECh. 20 - Prob. 20.13QECh. 20 - Prob. 20.14QECh. 20 - Prob. 20.15QECh. 20 - Prob. 20.16QECh. 20 - Prob. 20.17QECh. 20 - Prob. 20.18QECh. 20 - Prob. 20.19QECh. 20 - Prob. 20.20QECh. 20 - Prob. 20.21QECh. 20 - Prob. 20.23QECh. 20 - Prob. 20.24QECh. 20 - Prob. 20.25QECh. 20 - Prob. 20.26QECh. 20 - Prob. 20.27QECh. 20 - Prob. 20.28QECh. 20 - Prob. 20.30QECh. 20 - Prob. 20.31QECh. 20 - Prob. 20.32QECh. 20 - Prob. 20.33QECh. 20 - Prob. 20.34QECh. 20 - Prob. 20.35QECh. 20 - Prob. 20.36QECh. 20 - Prob. 20.37QECh. 20 - Prob. 20.38QECh. 20 - Prob. 20.39QECh. 20 - Prob. 20.40QECh. 20 - Prob. 20.41QECh. 20 - Prob. 20.42QECh. 20 - Prob. 20.43QECh. 20 - Prob. 20.44QECh. 20 - Prob. 20.46QECh. 20 - Prob. 20.47QECh. 20 - Prob. 20.49QECh. 20 - Prob. 20.50QECh. 20 - Prob. 20.51QECh. 20 - Prob. 20.52QECh. 20 - Prob. 20.53QECh. 20 - Prob. 20.54QECh. 20 - Prob. 20.55QECh. 20 - Prob. 20.56QECh. 20 - Prob. 20.57QECh. 20 - Prob. 20.58QECh. 20 - Prob. 20.59QECh. 20 - Prob. 20.60QECh. 20 - Prob. 20.61QECh. 20 - Prob. 20.62QECh. 20 - Prob. 20.63QECh. 20 - Prob. 20.64QECh. 20 - Prob. 20.65QECh. 20 - Prob. 20.66QECh. 20 - Prob. 20.67QECh. 20 - Prob. 20.68QECh. 20 - Prob. 20.69QECh. 20 - Prob. 20.70QECh. 20 - Prob. 20.71QECh. 20 - Prob. 20.72QECh. 20 - Prob. 20.73QECh. 20 - Prob. 20.74QECh. 20 - Prob. 20.75QECh. 20 - Prob. 20.76QECh. 20 - Prob. 20.77QECh. 20 - Prob. 20.78QECh. 20 - Prob. 20.79QECh. 20 - Prob. 20.80QECh. 20 - Prob. 20.82QECh. 20 - Prob. 20.83QECh. 20 - Prob. 20.84QE
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- 1600° 1538°C 1493°C In the diagram, the letter L indicates that it is a liquid. Indicate its components in the upper region where only L is indicated. The iron-iron carbide phase diagram. Temperature (°C) 1400 8 1394°C y+L 1200 2.14 y, Austenite 10000 912°C 800a 0.76 0.022 600 400 (Fe) a, Ferrite Composition (at% C) 15 1147°C a + Fe3C 2 3 Composition (wt% C) L 2500 4.30 2000 y + Fe3C 727°C 1500 Cementite (Fe3C) 1000 4 5 6 6.70 Temperature (°F)arrow_forwardNonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forward
- The iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forwardPart V. Choose which isomer would give the 1H-NMR spectrum below. Justify your reasoning by assigning important signals to the Corresponding protons of the correct molecule. A D on of of of H H 88 2 90 7.8 7.6 7.4 80 5 6 [ppm] 7.2 6.8 6.6 6.4 ō [ppm]arrow_forwardShow work with explanation. don't give Ai generated solutionarrow_forward
- Q7. a. Draw the line-bond structure of the major product for the following reaction, if a reaction occurs, assume monohalogenation. b. Calculate the product ratios using the following information (hint: use the number of hydrogens in each category present to calculate the ratios). Chlorination: 1° Reactivity=1 2° Reactivity=4 Heat + Cl2 3° Reactivity=5arrow_forwardPlease correct answer and don't use hand rating and don't use Ai solutionarrow_forwardQ10: Alkane halogenation a. Give the name and structures of the five isomeric hexanes. Page 4 of 5 Chem 0310 Organic Chemistry 1 Recitations b. For each isomer, give all the free radical monochlorination and monobromination products that are structurally isomeric.arrow_forward
- Q9. The insecticide DDT (in the box below) is useful in controlling mosquito populations and has low toxicity to humans, but is dangerous to birds and fish. Hoping to alleviate the dangers, little Johnny Whizbang, an aspiring chemist, proposes a new version of DDT ("Bromo-DDT") and shows his synthesis to his boss. Will Johnny Whizbang's synthesis work? Or will he be fired? Assume there is an excess of bromine and polybrominated products can be separated. Explain why. CH3 Br2, light CBR3 ok-ok Br Br Br Br CI "Bromo-DDT" CCl 3 DDT (dichlorodiphenyltrichloroethane) CIarrow_forwardDifferentiate the terms Monotectic, Eutectic, Eutectoid, Peritectic, Peritectoid.arrow_forwardQ5. Predict the organic product(s) for the following transformations. If no reaction will take place (or the reaction is not synthetically useful), write "N.R.". Determine what type of transition state is present for each reaction (think Hammond Postulate). I Br₂ CH3 F2, light CH3 Heat CH3 F₂ Heat Br2, light 12, light CH3 Cl2, lightarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStax
Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry & Chemical Reactivity
Chemistry
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
DISTINCTION BETWEEN ADSORPTION AND ABSORPTION; Author: 7activestudio;https://www.youtube.com/watch?v=vbWRuSk-BhE;License: Standard YouTube License, CC-BY
Difference Between Absorption and Adsorption - Surface Chemistry - Chemistry Class 11; Author: Ekeeda;https://www.youtube.com/watch?v=e7Ql2ZElgc0;License: Standard Youtube License