Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Question
Chapter 20, Problem 20.21QE
Interpretation Introduction
Interpretation:
The mineral which is mined for the production of lead has to be given and also the purification method of lead from that mineral has to be described.
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1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 20 Solutions
Chemistry Principles And Practice
Ch. 20 - Prob. 20.1QECh. 20 - Prob. 20.2QECh. 20 - Prob. 20.3QECh. 20 - Prob. 20.4QECh. 20 - Prob. 20.5QECh. 20 - Prob. 20.6QECh. 20 - Prob. 20.7QECh. 20 - Prob. 20.8QECh. 20 - Prob. 20.9QECh. 20 - Prob. 20.10QE
Ch. 20 - Prob. 20.11QECh. 20 - Prob. 20.12QECh. 20 - Prob. 20.13QECh. 20 - Prob. 20.14QECh. 20 - Prob. 20.15QECh. 20 - Prob. 20.16QECh. 20 - Prob. 20.17QECh. 20 - Prob. 20.18QECh. 20 - Prob. 20.19QECh. 20 - Prob. 20.20QECh. 20 - Prob. 20.21QECh. 20 - Prob. 20.23QECh. 20 - Prob. 20.24QECh. 20 - Prob. 20.25QECh. 20 - Prob. 20.26QECh. 20 - Prob. 20.27QECh. 20 - Prob. 20.28QECh. 20 - Prob. 20.30QECh. 20 - Prob. 20.31QECh. 20 - Prob. 20.32QECh. 20 - Prob. 20.33QECh. 20 - Prob. 20.34QECh. 20 - Prob. 20.35QECh. 20 - Prob. 20.36QECh. 20 - Prob. 20.37QECh. 20 - Prob. 20.38QECh. 20 - Prob. 20.39QECh. 20 - Prob. 20.40QECh. 20 - Prob. 20.41QECh. 20 - Prob. 20.42QECh. 20 - Prob. 20.43QECh. 20 - Prob. 20.44QECh. 20 - Prob. 20.46QECh. 20 - Prob. 20.47QECh. 20 - Prob. 20.49QECh. 20 - Prob. 20.50QECh. 20 - Prob. 20.51QECh. 20 - Prob. 20.52QECh. 20 - Prob. 20.53QECh. 20 - Prob. 20.54QECh. 20 - Prob. 20.55QECh. 20 - Prob. 20.56QECh. 20 - Prob. 20.57QECh. 20 - Prob. 20.58QECh. 20 - Prob. 20.59QECh. 20 - Prob. 20.60QECh. 20 - Prob. 20.61QECh. 20 - Prob. 20.62QECh. 20 - Prob. 20.63QECh. 20 - Prob. 20.64QECh. 20 - Prob. 20.65QECh. 20 - Prob. 20.66QECh. 20 - Prob. 20.67QECh. 20 - Prob. 20.68QECh. 20 - Prob. 20.69QECh. 20 - Prob. 20.70QECh. 20 - Prob. 20.71QECh. 20 - Prob. 20.72QECh. 20 - Prob. 20.73QECh. 20 - Prob. 20.74QECh. 20 - Prob. 20.75QECh. 20 - Prob. 20.76QECh. 20 - Prob. 20.77QECh. 20 - Prob. 20.78QECh. 20 - Prob. 20.79QECh. 20 - Prob. 20.80QECh. 20 - Prob. 20.82QECh. 20 - Prob. 20.83QECh. 20 - Prob. 20.84QE
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