Chemistry Principles And Practice
3rd Edition
ISBN: 9781305295803
Author: David Reger; Scott Ball; Daniel Goode
Publisher: Cengage Learning
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Chapter 20, Problem 20.25QE
Interpretation Introduction
Interpretation:
The oxides of the metals, the non-metals, and the metalloids has to be classified as acidic, basic, or amphoteric.
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Identifying electron-donating and
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
NH2
○ donating
NO2
Explanation
Check
withdrawing
no inductive effects
Resonance Effects
Overall Electron-Density
○ donating
O withdrawing
O no resonance effects
O donating
O withdrawing
O donating
withdrawing
O no inductive effects
Ono resonance effects
O electron-rich
electron-deficient
O similar to benzene
O electron-rich
O electron-deficient
O similar to benzene
olo
18
Ar
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Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
Х
(Choose one)
OH
(Choose one)
OCH3
(Choose one)
OH
(Choose one)
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Assign R or S to all the chiral centers in each compound drawn below
porat
bg
9
Br
Br
Chapter 20 Solutions
Chemistry Principles And Practice
Ch. 20 - Prob. 20.1QECh. 20 - Prob. 20.2QECh. 20 - Prob. 20.3QECh. 20 - Prob. 20.4QECh. 20 - Prob. 20.5QECh. 20 - Prob. 20.6QECh. 20 - Prob. 20.7QECh. 20 - Prob. 20.8QECh. 20 - Prob. 20.9QECh. 20 - Prob. 20.10QE
Ch. 20 - Prob. 20.11QECh. 20 - Prob. 20.12QECh. 20 - Prob. 20.13QECh. 20 - Prob. 20.14QECh. 20 - Prob. 20.15QECh. 20 - Prob. 20.16QECh. 20 - Prob. 20.17QECh. 20 - Prob. 20.18QECh. 20 - Prob. 20.19QECh. 20 - Prob. 20.20QECh. 20 - Prob. 20.21QECh. 20 - Prob. 20.23QECh. 20 - Prob. 20.24QECh. 20 - Prob. 20.25QECh. 20 - Prob. 20.26QECh. 20 - Prob. 20.27QECh. 20 - Prob. 20.28QECh. 20 - Prob. 20.30QECh. 20 - Prob. 20.31QECh. 20 - Prob. 20.32QECh. 20 - Prob. 20.33QECh. 20 - Prob. 20.34QECh. 20 - Prob. 20.35QECh. 20 - Prob. 20.36QECh. 20 - Prob. 20.37QECh. 20 - Prob. 20.38QECh. 20 - Prob. 20.39QECh. 20 - Prob. 20.40QECh. 20 - Prob. 20.41QECh. 20 - Prob. 20.42QECh. 20 - Prob. 20.43QECh. 20 - Prob. 20.44QECh. 20 - Prob. 20.46QECh. 20 - Prob. 20.47QECh. 20 - Prob. 20.49QECh. 20 - Prob. 20.50QECh. 20 - Prob. 20.51QECh. 20 - Prob. 20.52QECh. 20 - Prob. 20.53QECh. 20 - Prob. 20.54QECh. 20 - Prob. 20.55QECh. 20 - Prob. 20.56QECh. 20 - Prob. 20.57QECh. 20 - Prob. 20.58QECh. 20 - Prob. 20.59QECh. 20 - Prob. 20.60QECh. 20 - Prob. 20.61QECh. 20 - Prob. 20.62QECh. 20 - Prob. 20.63QECh. 20 - Prob. 20.64QECh. 20 - Prob. 20.65QECh. 20 - Prob. 20.66QECh. 20 - Prob. 20.67QECh. 20 - Prob. 20.68QECh. 20 - Prob. 20.69QECh. 20 - Prob. 20.70QECh. 20 - Prob. 20.71QECh. 20 - Prob. 20.72QECh. 20 - Prob. 20.73QECh. 20 - Prob. 20.74QECh. 20 - Prob. 20.75QECh. 20 - Prob. 20.76QECh. 20 - Prob. 20.77QECh. 20 - Prob. 20.78QECh. 20 - Prob. 20.79QECh. 20 - Prob. 20.80QECh. 20 - Prob. 20.82QECh. 20 - Prob. 20.83QECh. 20 - Prob. 20.84QE
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- (c) (4pts) Mechanism: heat (E1) CH3OH + 1.5pts each _E1 _ (1pt) Br CH3OH (d) (4pts) Mechanism: SN1 (1pt) (e) (3pts) 1111 I H 10 Ill!! H LDA THF (solvent) Mechanism: E2 (1pt) NC (f) Bri!!!!! CH3 NaCN (3pts) acetone Mechanism: SN2 (1pt) (SN1) -OCH3 OCH3 1.5pts each 2pts for either product 1pt if incorrect stereochemistry H Br (g) “,、 (3pts) H CH3OH +21 Mechanism: SN2 (1pt) H CH3 2pts 1pt if incorrect stereochemistry H 2pts 1pt if incorrect stereochemistryarrow_forwardA mixture of butyl acrylate and 4'-chloropropiophenone has been taken for proton NMR analysis. Based on this proton NMR, determine the relative percentage of each compound in the mixturearrow_forwardQ5: Label each chiral carbon in the following molecules as R or S. Make sure the stereocenter to which each of your R/S assignments belong is perfectly clear to the grader. (8pts) R OCH 3 CI H S 2pts for each R/S HO R H !!! I OH CI HN CI R Harrow_forward
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