EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
EBK GENERAL CHEMISTRY: THE ESSENTIAL CO
7th Edition
ISBN: 8220106637203
Author: Chang
Publisher: YUZU
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Chapter 20, Problem 20.13QP
  1. a)
Interpretation Introduction

Interpretation: The oxidation number of the metal ion for the given coordination compound to be predicted.

Concept Introduction:

Lewis acid: The species which accepts the lone pair of electrons.

Lewis base: The species which donates lone pair of electrons.

Donor atom: The neutral molecule or the negatively charged species which donates pair of electrons is known as Donor atom.

Coordinate covalent bonds: A covalent bond in which the Ligand donates both electrons to the metal ion to construct a bonding interaction known as coordinate covalent bond.

To Identify: The oxidation number of the metal ion for the given coordination compound to be predicted.

  1. b)
Interpretation Introduction

Interpretation: The oxidation number of the metal ion for the given coordination compound to be predicted.

Concept Introduction:

Lewis acid: The species which accepts the lone pair of electrons.

Lewis base: The species which donates lone pair of electrons.

Donor atom: The neutral molecule or the negatively charged species which donates pair of electrons is known as Donor atom.

Coordinate covalent bonds: A covalent bond in which the Ligand donates both electrons to the metal ion to construct a bonding interaction known as coordinate covalent bond.

To Identify: The oxidation number of the metal ion for the given coordination compound to be predicted.

  1. c)
Interpretation Introduction

Interpretation: The oxidation number of the metal ion for the given coordination compound to be predicted.

Concept Introduction:

Lewis acid: The species which accepts the lone pair of electrons.

Lewis base: The species which donates lone pair of electrons.

Donor atom: The neutral molecule or the negatively charged species which donates pair of electrons is known as Donor atom.

Coordinate covalent bonds: A covalent bond in which the Ligand donates both electrons to the metal ion to construct a bonding interaction known as coordinate covalent bond.

To Identify: The oxidation number of the metal ion for the given coordination compound to be predicted.

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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention to your units. A. What is the partition function for this system? B. What are the populations of each level? Now instead, consider a system with energy levels of 0 J mol C. Now what is the partition function? D. And what are the populations of the two levels? E. Finally, repeat the second calculation at 500 K. and 500 J mol 1 at 300 K. F. What do you notice about the populations as you increase the temperature? At what temperature would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²

Chapter 20 Solutions

EBK GENERAL CHEMISTRY: THE ESSENTIAL CO

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