The structural formula for the products obtained when the tripeptide, Thr–Leu–Ile undergoes complete hydrolysis under acidic conditions has to be stated. Concept introduction: The complete hydrolysis of protein results into constituent amino acids. The component amino acids of the protein are obtained due to the breakdown of all the peptide bonds.

Question

Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

Answer 1

Question

Chapter 20, Problem 20.122EP

(a)

Interpretation Introduction

Interpretation: The structural formula for the products obtained when the tripeptide, Thr–Leu–Ile undergoes complete hydrolysis under acidic conditions has to be stated.

Concept introduction: The complete hydrolysis of protein results into constituent amino acids. The component amino acids of the protein are obtained due to the breakdown of all the peptide bonds.

(b)

Interpretation Introduction

Interpretation: The structural formula for the products obtained when the tripeptide, Thr–Leu–Ile undergoes complete hydrolysis under basic conditions.

Concept introduction: The complete hydrolysis of protein results into constituent amino acids. The component amino acids of the protein are obtained since, all of the peptide bonds break.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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