The following scheme outlines the mechanism for the LiAlH 4 reduction of the acid chloride equation 20-19 . The appropriate curved arrows are to be supplied. The name of the elementary step is to be written underneath each reaction arrow, and the tetrahedral intermediate is to be identified. Concept introduction: In general, LiAlH 4 can be used to convert a ketone to a secondary alcohol and an aldehyde to a primary alcohol. The hydride ion from LiAlH 4 is an excellent nucleophile. The hydride nucleophile can react with acid derivatives in nucleophilic addition-elimination reaction. Here the carbonyl group is converted into primary alcohol.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.11YT

Interpretation Introduction

Interpretation:

The following scheme outlines the mechanism for the LiAlH4 reduction of the acid chloride equation 20-19. The appropriate curved arrows are to be supplied. The name of the elementary step is to be written underneath each reaction arrow, and the tetrahedral intermediate is to be identified.

Concept introduction:

In general, LiAlH4 can be used to convert a ketone to a secondary alcohol and an aldehyde to a primary alcohol. The hydride ion from LiAlH4 is an excellent nucleophile. The hydride nucleophile can react with acid derivatives in nucleophilic addition-elimination reaction. Here the carbonyl group is converted into primary alcohol.

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Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.11YT

Interpretation Introduction

Interpretation:

The following scheme outlines the mechanism for the LiAlH4 reduction of the acid chloride equation 20-19. The appropriate curved arrows are to be supplied. The name of the elementary step is to be written underneath each reaction arrow, and the tetrahedral intermediate is to be identified.

Concept introduction:

In general, LiAlH4 can be used to convert a ketone to a secondary alcohol and an aldehyde to a primary alcohol. The hydride ion from LiAlH4 is an excellent nucleophile. The hydride nucleophile can react with acid derivatives in nucleophilic addition-elimination reaction. Here the carbonyl group is converted into primary alcohol.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.11YT

Interpretation Introduction

Interpretation:

The following scheme outlines the mechanism for the LiAlH4 reduction of the acid chloride equation 20-19. The appropriate curved arrows are to be supplied. The name of the elementary step is to be written underneath each reaction arrow, and the tetrahedral intermediate is to be identified.

Concept introduction:

In general, LiAlH4 can be used to convert a ketone to a secondary alcohol and an aldehyde to a primary alcohol. The hydride ion from LiAlH4 is an excellent nucleophile. The hydride nucleophile can react with acid derivatives in nucleophilic addition-elimination reaction. Here the carbonyl group is converted into primary alcohol.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 20, Problem 20.11YT

Interpretation Introduction