EP INTRO.TO GENERAL,ORGANIC...-OWL ACCE
12th Edition
ISBN: 9781337915984
Author: Bettelheim
Publisher: Cengage Learning
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Textbook Question
Chapter 20, Problem 14P
21-8 Predict which acid in each pair has the higher melting point and explain why.
(a) Palmitic acid or stearic acid
(b) Arachidonic acid or arachidic acid
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Q1:
a) Arrange the compounds in order of decreasing pKa, highest first.
ОН
ΟΗ
ῸΗ
дон
ОН
ОН
CI
Br
(4 pts - 2 pts each part) A route that can be taken to prepare a
hydrophobic (water-repellent) aerogel is to start with
trichloromethylsilane, CH3SiCl3 as the silicon source.
a. What is the chemical reaction that this undergoes to form a
product with Si-OH groups? Write as complete of a chemical
equation as you can.
CI
CI-SI-CH3
CI
b. The formation of a byproduct is what drives this reaction - what is the byproduct (if you
didn't already answer it in part (a)) and how/why does it form?
b) Circle the substrate that would not efficiently generate a Grignard reagent upon reaction
with Mg in ether.
CI
Br
ד
c) Circle the Grignard reagents that contain incompatible functional groups.
MgBr
HO
MgBr
MgBr
MgBr
MgBr
HO
MgBr
Chapter 20 Solutions
EP INTRO.TO GENERAL,ORGANIC...-OWL ACCE
Ch. 20.2 - Prob. 20.1QCCh. 20.4 - Prob. 20.2QCCh. 20.5 - Prob. 20.3QCCh. 20.7 - Prob. 20.4QCCh. 20.8 - Prob. 20.5QCCh. 20.9 - Prob. 20.6QCCh. 20.10 - Prob. 20.7QCCh. 20.13 - Prob. 20.8QCCh. 20 - Prob. 1PCh. 20 - 21-2 Why are fats a good source of energy for...
Ch. 20 - 21-3 Proteins, nucleic acids, and carbohydrates...Ch. 20 - Prob. 4PCh. 20 - Prob. 5PCh. 20 - Draw the line-angle structure for the following:...Ch. 20 - Prob. 7PCh. 20 - What is the difference between the -system and...Ch. 20 - Prob. 9PCh. 20 - Prob. 10PCh. 20 - Prob. 11PCh. 20 - Prob. 12PCh. 20 - For the diglycerides in Problem 12 , predict which...Ch. 20 - 21-8 Predict which acid in each pair has the...Ch. 20 - Prob. 15PCh. 20 - Prob. 16PCh. 20 - Prob. 17PCh. 20 - Prob. 18PCh. 20 - 21-13 Rank the following in order of increasing...Ch. 20 - Prob. 20PCh. 20 - Prob. 21PCh. 20 - Prob. 22PCh. 20 - Prob. 23PCh. 20 - Prob. 24PCh. 20 - Prob. 25PCh. 20 - Prob. 26PCh. 20 - Prob. 27PCh. 20 - Prob. 28PCh. 20 - 21-29 Name all the groups of complex lipids that...Ch. 20 - Prob. 30PCh. 20 - Prob. 31PCh. 20 - Prob. 32PCh. 20 - Prob. 33PCh. 20 - Prob. 34PCh. 20 - Prob. 35PCh. 20 - Prob. 36PCh. 20 - Prob. 37PCh. 20 - Prob. 38PCh. 20 - 21-39 How does VLDL become LDL?Ch. 20 - Prob. 40PCh. 20 - Prob. 41PCh. 20 - Prob. 42PCh. 20 - Prob. 43PCh. 20 - 21-44 Describe the difference in structure between...Ch. 20 - Prob. 45PCh. 20 - Prob. 46PCh. 20 - Prob. 47PCh. 20 - 21-48 List all of the functional groups that make...Ch. 20 - 21-49 Explain how the constant elimination of bile...Ch. 20 - Prob. 50PCh. 20 - Prob. 51PCh. 20 - 21-52 What are the chemical and physiological...Ch. 20 - 21-53 How does aspirin, an anti-inflammatory drug,...Ch. 20 - Prob. 54PCh. 20 - Prob. 55PCh. 20 - For each of the processes below, tell whether it...Ch. 20 - Prob. 57PCh. 20 - Prob. 58PCh. 20 - Prob. 59PCh. 20 - Prob. 60PCh. 20 - Prob. 61PCh. 20 - Prob. 62PCh. 20 - Prob. 63PCh. 20 - Prob. 64PCh. 20 - Prob. 65PCh. 20 - Prob. 66PCh. 20 - Prob. 67PCh. 20 - Prob. 68PCh. 20 - Prob. 69PCh. 20 - 21-68 What is the role of taurine in lipid...Ch. 20 - Prob. 71PCh. 20 - 21-70 How many different triglycerides can you...Ch. 20 - Prob. 73PCh. 20 - Prob. 74PCh. 20 - Prob. 75PCh. 20 - Prob. 76PCh. 20 - Prob. 77PCh. 20 - 21-76 Which part of LDL interacts with the LDL...Ch. 20 - Prob. 79PCh. 20 - Prob. 80PCh. 20 - Prob. 81PCh. 20 - Prob. 82PCh. 20 - Prob. 83PCh. 20 - 21-82 Suggest a reason why the same protein system...Ch. 20 - Prob. 85PCh. 20 - Prob. 86PCh. 20 - 21-85 Which of the following statements is (are)...Ch. 20 - Prob. 88PCh. 20 - 21-87 Which statements are consistent with the...Ch. 20 - Prob. 90PCh. 20 - Prob. 91PCh. 20 - 21-90 To what extent do lipids and carbohydrates...Ch. 20 - Prob. 93PCh. 20 - Prob. 94PCh. 20 - Prob. 95PCh. 20 - Prob. 96PCh. 20 - Prob. 97PCh. 20 - Prob. 98PCh. 20 - Prob. 99PCh. 20 - Prob. 100PCh. 20 - Prob. 101PCh. 20 - 21-100 What are the functions of a cell membrane?...Ch. 20 - 21-101 Glycerophospholipids tend to have both a...Ch. 20 - Prob. 104P
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- Q2: Predict all organic product(s), including stereoisomers when applicable. PCC OH a) CH2Cl2 Page 2 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) .OH Na2Cr2O7, H+ OH PCC CH2Cl2 c) OHarrow_forwardd) Circle the substrates that will give an achiral product after a Grignard reaction with CH3MgBr. Harrow_forwardQ4: Predict the organic products for the following reactions. Then draw curved arrow electron- pushing mechanism for the reactions. a) NaBH4 EtOH Page 4 of 5 Chem 0310 Organic Chemistry 1 HW Problem Sets b) 요 1. Et₂O H MgBr 2. H+, H₂Oarrow_forward
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