Chemical Principles
Chemical Principles
8th Edition
ISBN: 9781337247269
Author: Steven S. Zumdahl; Donald J. DeCoste
Publisher: Cengage Learning US
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Chapter 20, Problem 11E

(a)

Interpretation Introduction

Interpretation:

The equation for the decay of A95241m by alpha production needs to be determined.

Concept Introduction:

Radioactive decay of unstable nuclei leads to formation of smaller nuclei that are stable and during this course alpha, beta and gamma radiations are emitted. When alpha particles are released, the new nuclei will display a decrease of 4 units in mass number and decrease of 2 units in atomic number.

(a)

Expert Solution
Check Mark

Answer to Problem 11E

The equation for the decay of A95241m by alpha production is A95241mN93237p+H24e .

Explanation of Solution

The decay of A95241m with production of alpha particle is depicted by equation as A95241m?+H24e .

While computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 241 =? + 4

x = 237

Atomic number: 95 =? + 2

y= 93

Hence unknown element is x93237 . Looking through the periodic table, it is found that element with mass number 237 and atomic number 93 is Np. Hence, the element is N93237p . The release of alpha particle during decay results in mass number showing a decrease of 4 units and atomic number showing decrease of 2 units.

Hence, the decay of the decay of A95241m by alpha production is A95241mN93237p+H24e .

(b)

Interpretation Introduction

Interpretation:

The balanced equation for the complete decay of A95241m needs to be determined, wherein the, a, β a, a, β a, a, a, β a and β are emitted successively.

Concept Introduction:

Alpha decay involves the release of alpha particle, namely, H24e with a new nucleus which will have mass number reduced by 4 units and atomic number reduced by 2 units.

Beta decay involves the release of beta particle, namely, e10 with a new nucleus which will have same mass number but atomic number decreased by 1 unit.

(b)

Expert Solution
Check Mark

Answer to Problem 11E

The final product obtained complete decay of A95241m is B83209i .

Explanation of Solution

The complete decay of A95241m in which a, a,β, a, a,β, a ,a, a,β, a and β are emitted successively show that 8 a and 4 β are involved.

In other words, it indicates that 8 x H24e and 4 xe10 which implies that there should be

Mass number = 8 x 4 + 0 = 32 units

Atomic number = 16 + (-4) = 12 units

While computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 241 = 0 + 32

x = 209

Atomic number: 95 =? + 12

y= 83

Hence unknown element is x83209 . Looking through the periodic table, it is found that element with mass number 209 and atomic number 83 is Bi. Hence, the element is B83209i .

The decay of A95241m with successive emission of 8 a and 4 β gives the final product as B83209i .

(c)

Interpretation Introduction

Interpretation:

The intermediate products formed by complete decay of A95241m needs to be determined in which a, a, β a, a, β a, a, a, β a and β are emitted successively.

Concept Introduction:

There is a release of alpha particle in alpha decay wherein the emitted is H24e along with a new nucleus that will have a reduction of mass number by 4 units and atomic number by 2 units.

In Beta decay, there is of a beta particle which is e10 along with a new nucleus that displays the same mass number with reduction in atomic number by 1 unit.

(c)

Expert Solution
Check Mark

Answer to Problem 11E

The various intermediates formed by complete decay of A95241m are depicted N93237p , P91233a , U92233 , T90229h , R88225a , A89225c , F87221 , A85217t , B83213i , P84213o , P82209b , B83209i .

Explanation of Solution

-The alpha decay of A95241m is depicted as A95241m?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 241 =? + 4

x = 237

Atomic number: 95 =? + 2

y= 93

Hence unknown element is x93237 . Looking through the periodic table, it is found that element with mass number 237 and atomic number 93 is Np. Hence, the element is N93237p .

The alpha decay of A95241m is depicted as A95241mN93237p+H24e

-The alpha decay of N93237p is depicted as N93237p?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 237 =? + 4

x = 230

Atomic number: 93 =? + 2

y= 91

Hence unknown element is x91233 . Looking through the periodic table, it is found that element with mass number 233 and atomic number 91 is Pa. Hence, the element is P91233a .

The alpha decay of N93237p is depicted as N93237pP91233a+H24e

-The beta decay of P91233a is P91233a?+e10

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 233 =? + 0

x = 233

Atomic number: 91 =? + (-1)

y= 92

\Hence unknown element is x92233 . Looking through the periodic table, it is found that element with mass number 233 and atomic number 92 is U. Hence, the element is U92233 .

The beta decay of P91233a is depicted as P91233aU92233+e10

-The alpha decay of U92233 is depicted as U92233?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 233 =? + 4

x = 229

Atomic number: 92 =? + 2

y= 90

Hence unknown element is x90229 . Looking through the periodic table, it is found that element with mass number 229 and atomic number 90 is Th. Hence, the element is T90229h .

The alpha decay of U92233 is depicted as U92233T90229h+H24e

-The alpha decay of T90229h is depicted as T90229h?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 229 =? + 4

x = 225

Atomic number: 90 =? + 2

y= 88

Hence unknown element is x88225 . Looking through the periodic table, it is found that element with mass number 225 and atomic number 88 is Ra. Hence, the element is R88225a .

The alpha decay of T90229h is depicted as T90229hR88225a+H24e

-The beta decay of R88225a is R88225a?+e10

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 225 =? + 0

x = 225

Atomic number: 88 =? + (-1)

y= 89

Hence unknown element is x89225 . Looking through the periodic table, it is found that element with mass number 225 and atomic number 89 is Ac. Hence, the element is A89225c .

The beta decay of R88225a is depicted as R88225aA89225c+e10

-The alpha decay of A89225c is depicted as A89225c?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 225 =? + 4

x = 221

Atomic number: 89 =? + 2

y= 87

Hence unknown element is x87221 . Looking through the periodic table, it is found that element with mass number 221 and atomic number 87 is Fr. Hence, the element is F87221r .

The alpha decay of A89225c is depicted as A89225cF87221r+H24e

-The alpha decay of F87221r is depicted as F87221r?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 221 =? + 4

x = 217

Atomic number: 87 =? + 2

y= 85

Hence unknown element is x85217 . Looking through the periodic table, it is found that element with mass number 217 and atomic number 85 is at. Hence, the element is A85217t

The alpha decay of F87221r is depicted as F87221rA85217t+H24e

-The alpha decay of A85217t is depicted as A85217t?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 217 =? + 4

x = 213

Atomic number: 85 =? + 2

y= 83

Hence unknown element is x83213 . Looking through the periodic table, it is found that element with mass number 213 and atomic number 83 is Bi. Hence, the element is B83213i .

The alpha decay of A85217t is depicted as A85217tB83213i+H24e

-The beta decay of B83213i is B83213i?+e10

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 213 =? + 0

x = 213

Atomic number: 83 =? + (-1)

y= 84

Hence unknown element is x84213 . Looking through the periodic table, it is found that element with mass number 213 and atomic number 84 is Po. Hence, the element is P84213o .

The beta decay of B83213i is depicted as B83213iP84213o+e10

-The alpha decay of P84213o is depicted as P84213o?+H24e

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 213 =? + 4

x = 209

Atomic number: 84 =? + 2

y= 82

Hence unknown element is x82209 . Looking through the periodic table, it is found that element with mass number 209 and atomic number 82 is Pb. Hence, the element is P82209b .

The alpha decay of P84213o is depicted as P84213oP82209b+H24e

-The beta decay of P82209b is P82209b?+e10

Computing the mass numbers and atomic mass for unknown element, it is found that

Mass number: 209 =? + 0

x = 209

Atomic number: 82 =? + (-1)

y= 83

Hence unknown element is x83209 . Looking through the periodic table, it is found that element with mass number 209 and atomic number 83 is Bi. Hence, the element is B83209i .

The beta decay of P82209b is depicted as P82209bB83209i+e10 .

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Chapter 20 Solutions

Chemical Principles

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