Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
15th Edition
ISBN: 9781269935678
Author: Nivaldo J. Tro
Publisher: Pearson Education
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Chapter 20, Problem 117E
The molar mass of a metal (M) is 50.9 g/mol; it forms a chloride of unknown composition.
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You have now performed a liquid-liquid extraction protocol in Experiment 4. In doing so, you
manipulated and exploited the acid-base chemistry of one or more of the compounds in your
mixture to facilitate their separation into different phases. The key to understanding how liquid-
liquid extractions work is by knowing which layer a compound is in, and in what protonation state.
The following liquid-liquid extraction is different from the one you performed in Experiment
4, but it uses the same type of logic. Your task is to show how to separate apart Compound
A and Compound B.
. Complete the following flowchart of a liquid-liquid extraction. Handwritten work is
encouraged.
•
Draw by hand (neatly) only the appropriate organic compound(s) in the boxes.
.
Specify the reagent(s)/chemicals (name is fine) and concentration as required in Boxes 4
and 5.
•
Box 7a requires the solvent (name is fine).
•
Box 7b requires one inorganic compound.
• You can neatly complete this assignment by hand and…
b) Elucidate compound D w) mt at 170 nd shows c-1 stretch at 550cm;'
The compound has the ff electronic transitions: 0%o* and no a*
1H NMR Spectrum
(CDCl3, 400 MHz)
3.5
3.0
2.5
2.0
1.5
1.0
0.5 ppm
13C{H} NMR Spectrum
(CDCl3, 100 MHz)
Solvent
80
70
60
50
40
30
20
10
0 ppm
ppm
¹H-13C me-HSQC Spectrum
ppm
(CDCl3, 400 MHz)
5
¹H-¹H COSY Spectrum
(CDCl3, 400 MHz)
0.5
10
3.5
3.0
2.5
2.0
1.5 1.0
10
15
20
20
25
30
30
-35
-1.0
1.5
-2.0
-2.5
3.0
-3.5
0.5
ppm
3.5
3.0
2.5
2.0
1.5
1.0
0.5
ppm
Show work with explanation. don't give Ai generated solution
Chapter 20 Solutions
Chemistry: Structure and Properties Custom Edition for Rutgers University General Chemistry
Ch. 20 - Balance the redox reaction equation (occurring in...Ch. 20 - Prob. 2SAQCh. 20 - Prob. 3SAQCh. 20 - Refer to Table 19.1 to determine which statement...Ch. 20 - Prob. 5SAQCh. 20 - The Zn/Zn2+ electrode has a standard electrode...Ch. 20 - Refer to Table 19.1 to calculate G for the...Ch. 20 - A redox reaction has an Ecell=0.56V . What can you...Ch. 20 - Prob. 9SAQCh. 20 - Prob. 10SAQ
Ch. 20 - Prob. 11SAQCh. 20 - Prob. 12SAQCh. 20 - Which reaction occurs at the cathode of an...Ch. 20 - Copper is plated onto the cathode of an...Ch. 20 - Prob. 15SAQCh. 20 - Prob. 1ECh. 20 - Explain the difference between a voltaic (or...Ch. 20 - Prob. 3ECh. 20 - Prob. 4ECh. 20 - Prob. 5ECh. 20 - Prob. 6ECh. 20 - What is the definition of the standard cell...Ch. 20 - Describe the basic features of a cell diagram (or...Ch. 20 - Why do some electrochemical cells employ inert...Ch. 20 - Describe the standard hydrogen electrode (SHE) and...Ch. 20 - How is the cell potential of an electrochemical...Ch. 20 - Prob. 12ECh. 20 - Prob. 13ECh. 20 - How can Table 19.1be used to predict whether or...Ch. 20 - Explain why Ecell , Grxn , and K are all...Ch. 20 - Does a redox reaction with a small equilibrium...Ch. 20 - How does Ecell depend on the concentrations of the...Ch. 20 - Prob. 18ECh. 20 - What is a concentration electrochemical cell?Ch. 20 - What are the anode and cathode reactions in a...Ch. 20 - What are the anode and cathode reactions in a...Ch. 20 - Prob. 22ECh. 20 - What is a fuel cell? What is the most common type...Ch. 20 - The anode of an electrolytic cell must be...Ch. 20 - What species is oxidized, and what species is...Ch. 20 - If an electrolytic cell contains a mixture of...Ch. 20 - Why does the electrolysis of an aqueous sodium...Ch. 20 - What is overvoltage in an electrochemical cell?...Ch. 20 - How is the amount of current flowing through an...Ch. 20 - Prob. 30ECh. 20 - Prob. 31ECh. 20 - Prob. 32ECh. 20 - Balance each redox reaction occurring in acidic...Ch. 20 - Prob. 34ECh. 20 - Balance each redox reaction occurring in acidic...Ch. 20 - Prob. 36ECh. 20 - Prob. 37ECh. 20 - Balance each redox reaction occurring in basic...Ch. 20 - Prob. 39ECh. 20 - Prob. 40ECh. 20 - Calculate the standard cell potential for each of...Ch. 20 - Prob. 42ECh. 20 - Consider the voltaic cell: Determine the direction...Ch. 20 - Prob. 44ECh. 20 - Use line notation to represent each...Ch. 20 - Use line notation to represent each...Ch. 20 - a sketch of the voltaic cell represented by the...Ch. 20 - Prob. 48ECh. 20 - Determine whether or not each redox reaction...Ch. 20 - Prob. 50ECh. 20 - Which metal could you use to reduce Mn2+ ions but...Ch. 20 - Prob. 52ECh. 20 - Prob. 53ECh. 20 - Prob. 54ECh. 20 - Prob. 55ECh. 20 - Prob. 56ECh. 20 - Calculate Ecell for each balanced redox reaction...Ch. 20 - Prob. 58ECh. 20 - Prob. 59ECh. 20 - Which metal is the best reducing agent? Mn Al Ni...Ch. 20 - Use tabulated electrode potentials to calculate...Ch. 20 - Use tabulated electrode potentials to calculate...Ch. 20 - Prob. 63ECh. 20 - Calculate the equilibrium constant for each of the...Ch. 20 - Calculate the equilibrium constant for the...Ch. 20 - Prob. 66ECh. 20 - Calculate Grxn and Ecell for a redox reaction with...Ch. 20 - Prob. 68ECh. 20 - Prob. 69ECh. 20 - Prob. 70ECh. 20 - Prob. 71ECh. 20 - Prob. 72ECh. 20 - Prob. 73ECh. 20 - Prob. 74ECh. 20 - Prob. 75ECh. 20 - Consider the concentration cell: Label the anode...Ch. 20 - Prob. 77ECh. 20 - Prob. 78ECh. 20 - Prob. 79ECh. 20 - Prob. 80ECh. 20 - Refer to the tabulated values of Gf in Appendix...Ch. 20 - Refer to the tabulated values of Gf in Appendix...Ch. 20 - Prob. 83ECh. 20 - Prob. 84ECh. 20 - Prob. 85ECh. 20 - Prob. 86ECh. 20 - Prob. 87ECh. 20 - Which products are obtained in the electrolysis of...Ch. 20 - Write equations for the half-reactions that occur...Ch. 20 - Which products are obtained in the electrolysis of...Ch. 20 - Prob. 91ECh. 20 - Write equations for the half-reactions that occur...Ch. 20 - Prob. 93ECh. 20 - Prob. 94ECh. 20 - Prob. 95ECh. 20 - Silver can be electroplated at the cathode of an...Ch. 20 - A major source of sodium metal is the electrolysis...Ch. 20 - Prob. 98ECh. 20 - Prob. 99ECh. 20 - Prob. 100ECh. 20 - Consider the molecular view of an AL strip and...Ch. 20 - Consider the molecular view of an electrochemical...Ch. 20 - Prob. 103ECh. 20 - Prob. 104ECh. 20 - The cell potential of this electrochemical cell...Ch. 20 - Prob. 106ECh. 20 - Prob. 107ECh. 20 - What voltage can theoretically be achieved in a...Ch. 20 - A battery relies on the oxidation of magnesium and...Ch. 20 - A rechargeable battery is constructed based on a...Ch. 20 - If a water electrolysis cell operates at a current...Ch. 20 - Prob. 112ECh. 20 - Prob. 113ECh. 20 - Prob. 114ECh. 20 - Calculate Grxn and K for each reaction. The...Ch. 20 - Calculate Grxn and K for each reaction. The...Ch. 20 - The molar mass of a metal (M) is 50.9 g/mol; it...Ch. 20 - A metal forms the fluoride MF3. Electrolysis of...Ch. 20 - A sample of impure tin of mass 0.535 g is...Ch. 20 - Prob. 120ECh. 20 - Prob. 121ECh. 20 - A 215 mL sample of a 0.500 M NaCl solution with an...Ch. 20 - Prob. 123ECh. 20 - Prob. 124ECh. 20 - Prob. 125ECh. 20 - Prob. 126ECh. 20 - Prob. 127ECh. 20 - Prob. 128ECh. 20 - Prob. 129ECh. 20 - Three electrolytic cells are connected in a...Ch. 20 - Prob. 131ECh. 20 - Prob. 132ECh. 20 - Prob. 133ECh. 20 - Prob. 134ECh. 20 - Prob. 135E
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- Redraw the flowchartarrow_forwardredraw the flowchart with boxes and molecules written in themarrow_forwardPart I. a) Elucidate the structure of compound A using the following information. • mass spectrum: m+ = 102, m/2=57 312=29 • IR spectrum: 1002.5 % TRANSMITTANCE Ngg 50 40 30 20 90 80 70 60 MICRONS 5 8 9 10 12 13 14 15 16 19 1740 cm M 10 0 4000 3600 3200 2800 2400 2000 1800 1600 13 • CNMR 'H -NMR Peak 8 ppm (H) Integration multiplicity a 1.5 (3H) triplet b 1.3 1.5 (3H) triplet C 2.3 1 (2H) quartet d 4.1 1 (2H) quartet & ppm (c) 10 15 28 60 177 (C=0) b) Elucidate the structure of compound B using the following information 13C/DEPT NMR 150.9 MHz IIL 1400 WAVENUMBERS (CM-1) DEPT-90 DEPT-135 85 80 75 70 65 60 55 50 45 40 35 30 25 20 ppm 1200 1000 800 600 400arrow_forward
- • Part II. a) Elucidate The structure of compound c w/ molecular formula C10 11202 and the following data below: • IR spectra % TRANSMITTANCE 1002.5 90 80 70 60 50 40 30 20 10 0 4000 3600 3200 2800 2400 2000 1800 1600 • Information from 'HAMR MICRONS 8 9 10 11 14 15 16 19 25 1400 WAVENUMBERS (CM-1) 1200 1000 800 600 400 peak 8 ppm Integration multiplicity a 2.1 1.5 (3H) Singlet b 3.6 1 (2H) singlet с 3.8 1.5 (3H) Singlet d 6.8 1(2H) doublet 7.1 1(2H) doublet Information from 13C-nmR Normal carbon 29ppm Dept 135 Dept -90 + NO peak NO peak 50 ppm 55 ppm + NO peak 114 ppm t 126 ppm No peak NO peak 130 ppm t + 159 ppm No peak NO peak 207 ppm по реак NO peakarrow_forwardCould you redraw these and also explain how to solve them for me pleasarrow_forwardNonearrow_forward
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