Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
8th Edition
ISBN: 9780134421377
Author: Charles H Corwin
Publisher: PEARSON
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Chapter 2, Problem 9ST
Interpretation Introduction
Interpretation:
The temperature on Celsius scale is to be predicted.
Concept introduction:
Temperature can be measured in Kelvin scale, Celsius scale and Fahrenheit scale. Celsius is the commonly used measurement unit for temperature. Kelvin is the SI unit of temperature. The absolute zero on the Kelvin scale is the temperature at which all the thermal motion ceases.
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Draw the anti-Markovnikov product of the hydration of this alkene.
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Explanation
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AG/F-2° V
3. Before proceeding with this problem you may want to glance at p. 466 of your textbook
where various oxo-phosphorus derivatives and their oxidation states are summarized.
Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14:
-0.93
+0.38
-0.50
-0.51 -0.06
H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3
Acidic solution
Basic solution
-0.28
-0.50
3--1.12
-1.57
-2.05 -0.89
PO HPO H₂PO₂ →P → PH3
-1.73
a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the
formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both
processes; comment.
(3 points)
0.5
PH
P
0.0
-0.5
-1.0-
-1.5-
-2.0
H.PO,
-2.3+
-3 -2
-1
1
2
3
2
H,PO,
b) Frost diagram for phosphorus under acidic
conditions is shown. Identify possible
disproportionation and comproportionation processes;
write out chemical equations describing them. (2 points)
H,PO
4
S
Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the
metal:
a) Tris(acetylacetonato)iron(III)
b) Hexabromoplatinate(2-)
c) Potassium diamminetetrabromocobaltate(III)
(6 points)
Chapter 2 Solutions
Introductory Chemistry: Concepts and Critical Thinking (8th Edition)
Ch. 2 - Prob. 2.1CECh. 2 - Prob. 2.2CECh. 2 - Prob. 2.3CECh. 2 - Prob. 2.4CECh. 2 - Prob. 2.5CECh. 2 - Prob. 2.6CECh. 2 - Prob. 2.7CECh. 2 - Prob. 2.8CECh. 2 - Prob. 2.9CECh. 2 - Prob. 2.10CE
Ch. 2 - Prob. 2.11CECh. 2 - Prob. 2.12CECh. 2 - Prob. 2.13CECh. 2 - Prob. 2.14CECh. 2 - Prob. 2.15CECh. 2 - Prob. 2.16CECh. 2 - Prob. 2.17CECh. 2 - Prob. 2.18CECh. 2 - Prob. 1KTCh. 2 - Prob. 2KTCh. 2 - Prob. 3KTCh. 2 - Prob. 4KTCh. 2 - Prob. 5KTCh. 2 - Prob. 6KTCh. 2 - Prob. 7KTCh. 2 - Prob. 8KTCh. 2 - Prob. 9KTCh. 2 - Prob. 10KTCh. 2 - Prob. 11KTCh. 2 - Prob. 12KTCh. 2 - Prob. 13KTCh. 2 - Prob. 14KTCh. 2 - Prob. 15KTCh. 2 - Prob. 16KTCh. 2 - Prob. 17KTCh. 2 - Prob. 18KTCh. 2 - Prob. 19KTCh. 2 - Prob. 20KTCh. 2 - Prob. 21KTCh. 2 - Prob. 22KTCh. 2 - Prob. 23KTCh. 2 - Prob. 24KTCh. 2 - Prob. 25KTCh. 2 - Prob. 1ECh. 2 - Prob. 2ECh. 2 - Prob. 3ECh. 2 - Prob. 4ECh. 2 - Prob. 5ECh. 2 - Prob. 6ECh. 2 - Prob. 7ECh. 2 - Prob. 8ECh. 2 - Prob. 9ECh. 2 - Prob. 10ECh. 2 - Prob. 11ECh. 2 - Prob. 12ECh. 2 - Prob. 13ECh. 2 - Prob. 14ECh. 2 - Prob. 15ECh. 2 - Prob. 16ECh. 2 - Prob. 17ECh. 2 - Prob. 18ECh. 2 - Prob. 19ECh. 2 - Prob. 20ECh. 2 - Prob. 21ECh. 2 - Prob. 22ECh. 2 - Prob. 23ECh. 2 - Prob. 24ECh. 2 - Prob. 25ECh. 2 - Prob. 26ECh. 2 - Prob. 27ECh. 2 - Prob. 28ECh. 2 - Prob. 29ECh. 2 - Prob. 30ECh. 2 - Prob. 31ECh. 2 - Prob. 32ECh. 2 - Prob. 33ECh. 2 - Prob. 34ECh. 2 - Prob. 35ECh. 2 - Prob. 36ECh. 2 - Prob. 37ECh. 2 - Prob. 38ECh. 2 - Prob. 39ECh. 2 - Prob. 40ECh. 2 - Prob. 41ECh. 2 - Prob. 42ECh. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Prob. 47ECh. 2 - Prob. 48ECh. 2 - Prob. 49ECh. 2 - Prob. 50ECh. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62ECh. 2 - Prob. 63ECh. 2 - Prob. 64ECh. 2 - Prob. 65ECh. 2 - Prob. 66ECh. 2 - Prob. 67ECh. 2 - Prob. 68ECh. 2 - Prob. 69ECh. 2 - Prob. 70ECh. 2 - Prob. 71ECh. 2 - Prob. 72ECh. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Prob. 84ECh. 2 - Prob. 85ECh. 2 - Prob. 86ECh. 2 - Prob. 87ECh. 2 - Prob. 88ECh. 2 - Prob. 89ECh. 2 - Prob. 90ECh. 2 - Prob. 91ECh. 2 - Prob. 92ECh. 2 - Prob. 93ECh. 2 - Prob. 94ECh. 2 - Prob. 95ECh. 2 - Prob. 96ECh. 2 - Prob. 1STCh. 2 - Prob. 2STCh. 2 - Prob. 3STCh. 2 - Prob. 4STCh. 2 - Prob. 5STCh. 2 - Prob. 6STCh. 2 - Prob. 7STCh. 2 - Prob. 8STCh. 2 - Prob. 9STCh. 2 - Prob. 10STCh. 2 - Prob. 11STCh. 2 - Prob. 12STCh. 2 - Prob. 13STCh. 2 - Prob. 14ST
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