Introduction to General, Organic and Biochemistry
12th Edition
ISBN: 9780357391594
Author: Frederick A. Bettelheim; William H. Brown; Mary K. Campbell
Publisher: Cengage Learning US
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Question
Chapter 2, Problem 99P
Interpretation Introduction
Interpretation: The percent abundance of
Concept Introduction:For element with 3 isotopes, the formula to calculate average atomic weight of an element is as follows:
Here. %A is percentage
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Write structural formulas for the major products by
doing addition reactions
1. You must add H2 as Pt is catalyst it does not take part in reactions
only speed up the process
H₂
CH2=CH-CH3
Pt
2. Add HCI break it into H and Cl
CH3
HCI
3. Add Br2 only CC14 is catalyst
CH3-CH=CH2
B12
CCl4
4. Add water to this and draw major product, H2SO4 is catalyst you have add
water H20 in both the reaction below
H₂SO4
CH3-CH=CH2
CH3
H2SO4/H₂O
CH3-C=CH2
reflux
?
Plan the synthesis of the following compound using the starting
material provided and any other reagents needed as long as
carbon based reagents have 3 carbons or less. Either the
retrosynthesis or the forward synthesis (mechanisms are not
required but will be graded if provided) will be accepted if all
necessary reagents and intermediates are shown (solvents and
temperature requirements are not needed unless specifically
involved in the reaction, i.e. DMSO in the Swern oxidation or
heat in the KMnO4 oxidation).
H
H
Hint These are benzene substitution reactions.
ALCI3 and UV light are catalyst no part in reactions and triangle A means
heating.
A. Add ethyl for Et in benzene ring alkylation reaction EtCl =
CH3CH2CL
1) EtC1 / AlCl3 / A
?
B: Add Br to benzene ring ( substitution)
2) Br₂ / uv light
?
C Add (CH3)2 CHCH2 in benzene ring ( substitution)
(CH3)2CHCH,C1 / AICI,
?
Chapter 2 Solutions
Introduction to General, Organic and Biochemistry
Ch. 2.2 - Problem 2-1 Write the formulas of compounds in...Ch. 2.4 - Problem 2-2 What is the mass number of an atom...Ch. 2.4 - Problem 2-3 Name the elements given in Problem...Ch. 2.4 - Problem 2-4 (a) What are the atomic numbers of...Ch. 2.4 - Prob. 2.5QCCh. 2.4 - Problem 2-6 The atomic weight of lithium is 6.941...Ch. 2.6 - Problem 2-7 Write the Lewis dot structure for the...Ch. 2 - Prob. 1PCh. 2 - 9 Answer true or false. (a) Matter is divided into...Ch. 2 - Prob. 3P
Ch. 2 - Prob. 4PCh. 2 - 2-12 The elements game, Part 1. Name and give the...Ch. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Prob. 8PCh. 2 - Prob. 9PCh. 2 - 2-17 How does Dalton’s atomic theory explain: (a)...Ch. 2 - Prob. 11PCh. 2 - Prob. 12PCh. 2 - 2-20 Calculate the percentage of hydrogen and...Ch. 2 - Prob. 14PCh. 2 - Prob. 15PCh. 2 - 2-23 It has been said, “The number of protons...Ch. 2 - Prob. 17PCh. 2 - Prob. 18PCh. 2 - 2-26 Given these mass numbers and number of...Ch. 2 - If each atom in Problem 19 acquired two more...Ch. 2 - Prob. 21PCh. 2 - 2-29 How many protons and how many neutrons does...Ch. 2 - Prob. 23PCh. 2 - 2-31 Tin-118 is one of the isotopes of tin. Name...Ch. 2 - Prob. 25PCh. 2 - Prob. 26PCh. 2 - 2-34 There are only two naturally occurring...Ch. 2 - 2-35 The two most abundant naturally occurring...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Prob. 32PCh. 2 - Prob. 33PCh. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - 2-43 Which group(s) of the Periodic Table...Ch. 2 - 2-44 Which period(s) in the Periodic Table...Ch. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - 2-47 Which element in each pair is more metallic?...Ch. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - 2-51 What is the correlation between the group...Ch. 2 - Prob. 45PCh. 2 - Prob. 46PCh. 2 - Prob. 47PCh. 2 - Prob. 48PCh. 2 - Prob. 49PCh. 2 - Prob. 50PCh. 2 - Prob. 51PCh. 2 - 2-59 You are presented with a Lewis dot structure...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Prob. 55PCh. 2 - Prob. 56PCh. 2 - 2-64 Consider the elements B, C, and N. Using only...Ch. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - 2-67 Account for the fact that the first...Ch. 2 - Prob. 61PCh. 2 - 2-69 (Chemical Connections 2A) Why does the body...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - 2-73 (Chemical Connections 2D) Copper is a soft...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - Prob. 72PCh. 2 - Prob. 73PCh. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - 2-83 The natural abundance of boron isotopes is as...Ch. 2 - Prob. 77PCh. 2 - 2-85 The mass of a proton is 1.67 × 10-24g. The...Ch. 2 - Prob. 79PCh. 2 - Prob. 80PCh. 2 - Prob. 81PCh. 2 - Prob. 82PCh. 2 - Prob. 83PCh. 2 - 2-91 These are the first two ionization energy for...Ch. 2 - Prob. 85PCh. 2 - Prob. 86PCh. 2 - 2-94 Using your knowledge of trends in element...Ch. 2 - Prob. 88PCh. 2 - Prob. 89PCh. 2 - 2-97 Explain why the Ca3+ ion is not found in...Ch. 2 - 2-98 Explain how the ionization energy of atoms...Ch. 2 - 2-99 A 7.12 g sample of magnesium is heated with...Ch. 2 - 2-100 A 0.100 g sample of magnesium, when combined...Ch. 2 - 2-101 Complete the following table: Symbol Atomic...Ch. 2 - 2-102 An element consists of 90.51% of an isotope...Ch. 2 - 2-103 The element silver has two naturally...Ch. 2 - 2-104 The average atomic weight of lithium is...Ch. 2 - Prob. 98PCh. 2 - Prob. 99PCh. 2 - Consider the Period 3 elements of the Periodic...Ch. 2 - Name the element that corresponds to each of the...
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