The formulas for the ionic compounds formed between the pair of given elements are to be written. Concept Introduction: An ionic compound consists of ions that have electrostatic interaction between them which is termed as ionic bonding. The element symbols and subscripts in an ionic compound are represented by a chemical formula. While writing the chemical formula for an ionic compound, the symbol of the metal is written first, which is followed by the symbol of the non-metal. Formal charge equation can be given as: Formal charge = number of valence electrons − 1 / 2 number of shared electrons − number of unshared electrons or F = Z − ( 1 / 2 ) S − U where F is the formal charge, Z is the group number of the element, S equals the number of shared electrons, and U is the number of unshared electrons. The arithmetic sum of all the formal charges in a molecule or ion will equal the overall charge on the molecule or ion.
The formulas for the ionic compounds formed between the pair of given elements are to be written. Concept Introduction: An ionic compound consists of ions that have electrostatic interaction between them which is termed as ionic bonding. The element symbols and subscripts in an ionic compound are represented by a chemical formula. While writing the chemical formula for an ionic compound, the symbol of the metal is written first, which is followed by the symbol of the non-metal. Formal charge equation can be given as: Formal charge = number of valence electrons − 1 / 2 number of shared electrons − number of unshared electrons or F = Z − ( 1 / 2 ) S − U where F is the formal charge, Z is the group number of the element, S equals the number of shared electrons, and U is the number of unshared electrons. The arithmetic sum of all the formal charges in a molecule or ion will equal the overall charge on the molecule or ion.
Solution Summary: The author explains that the formulas for ionic compounds formed between the pair of given elements are to be written.
The formulas for the ionic compounds formed between the pair of given elements are to be written.
Concept Introduction:
An ionic compound consists of ions that have electrostatic interaction between them which is termed as ionic bonding.
The element symbols and subscripts in an ionic compound are represented by a chemical formula.
While writing the chemical formula for an ionic compound, the symbol of the metal is written first, which is followed by the symbol of the non-metal.
Formal charge equation can be given as:
Formal charge = number of valence electrons −1/2 number of shared electrons−number of unshared electrons or
F=Z−(1/2)S− U
where F is the formal charge, Z is the group number of the element, S equals the number of shared electrons, and U is the number of unshared electrons.
The arithmetic sum of all the formal charges in a molecule or ion will equal the overall charge on the molecule or ion.
21.38 Arrange the molecules in each set in order of increasing acidity (from least acidic to
most acidic).
OH
OH
SH
NH2
8
NH3
OH
(b)
OH
OH
OH
(c)
& & &
CH3
NO2
21.39 Explain the trends in the acidity of phenol and the monofluoro derivatives of phenol.
OH
OH
OH
OH
PK 10.0
PK 8.81
PK 9.28
PK 9.81
identify which spectrum is for acetaminophen and which is for phenacetin
The Concept of Aromaticity
21.15 State the number of 2p orbital electrons in each molecule or ion.
(a)
(b)
(e)
(f)
(c)
(d)
(h)
(i)
DA
(k)
21.16 Which of the molecules and ions given in Problem 21.15 are aromatic according to the
Hückel criteria? Which, if planar, would be antiaromatic?
21.17 Which of the following structures are considered aromatic according to the Hückel
criteria?
---0-0
(a)
(b)
(c)
(d)
(e)
(h)
H
-H
.8.0-
21.18 Which of the molecules and ions from Problem 21.17 have electrons donated by a
heteroatom?
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell
Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; Darrell