
Chemistry
4th Edition
ISBN: 9780078021527
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 2, Problem 85QP
Interpretation Introduction
Interpretation:
The molecular formula and name for the given molecular compounds are to be written.
Concept introduction:
A molecular model is a three-dimensional representation of molecules of a compound.
In a ball-and-stick-model, balls represent the atoms of an element and sticks represent the
The molecular formula signifies the exact number of atoms of each element which are present in the molecule of a particular compound.
The compoundsthat are formed by the sharing of two or more nonmetals are known as molecular compounds.
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(a
4 shows scanning electron microscope (SEM) images of extruded
actions of packing bed for two capillary columns of different diameters,
al 750 (bottom image) and b) 30-μm-i.d. Both columns are packed with the
same stationary phase, spherical particles with 1-um diameter.
A) When the columns were prepared, the figure shows that the column with
the larger diameter has more packing irregularities. Explain this observation.
B) Predict what affect this should have on band broadening and discuss your
prediction using the van Deemter terms.
C) Does this figure support your explanations in application question 33?
Explain why or why not and make any changes in your answers in light of
this figure.
Figure 4 SEM images of
sections of packed columns
for a) 750 and b) 30-um-i.d.
capillary columns.³
fcrip
= ↓ bandwidth Il temp
32. What impact (increase, decrease, or no change) does each of the following conditions have on the individual
components of the van Deemter equation and consequently, band broadening?
Increase temperature
Longer column
Using a gas mobile phase
instead of liquid
Smaller particle stationary phase
Multiple Paths
Diffusion
Mass Transfer
34. Figure 3 shows Van Deemter plots for a solute molecule using different column inner diameters (i.d.).
A) Predict whether decreasing the column inner diameters increase or decrease bandwidth.
B) Predict which van Deemter equation coefficient (A, B, or C) has the greatest effect on increasing or
decreasing bandwidth as a function of i.d. and justify your answer.
Figure 3 Van Deemter plots for hydroquinone using different column inner diameters (i.d. in μm). The data was
obtained from liquid chromatography experiments using fused-silica capillary columns packed with 1.0-μm particles.
35
20
H(um)
큰 20
15
90
0+
1500
100
75
550
01
02
594
05
μ(cm/sec)
30
15
10
Chapter 2 Solutions
Chemistry
Ch. 2.1 - Practice Problem ATTEMPT
In each case, calculate...Ch. 2.1 - Practice Problem BUILD
(a) Two of the simplest...Ch. 2.1 - Practice Problem CONCEPTUALIZE
Which of the...Ch. 2.1 - For the two compounds pictured, evaluate the...Ch. 2.1 - Prob. 2CPCh. 2.2 - Practice ProblemATTEMPT How many protons,...Ch. 2.2 - Practice ProblemBUILD Give the correct symbols to...Ch. 2.2 - Prob. 1PPCCh. 2.3 - 2.3.1 How many neutrons are there in an atom of
Ch. 2.3 - Prob. 2CP
Ch. 2.3 - Practice ProblemATTEMPT The atomic masses of the...Ch. 2.3 - Practice ProblemBUILD The average atomic mass of...Ch. 2.3 - Practice Problem CONCEPTUALIZE
The following...Ch. 2.4 - Which of the following series of elemental symbols...Ch. 2.4 - 2.4.2 Which of the following elements would you...Ch. 2.4 - Practice Problem ATTEMPT
Name the following ionic...Ch. 2.4 - Practice Problem BUILD
Name the following ionic...Ch. 2.4 - Practice ProblemCONCEPTUALIZE The diagram...Ch. 2.5 - Boron has two naturally occurring isotopes, which...Ch. 2.5 - 2.5.2 The two naturally occurring isotopes of...Ch. 2.5 - Practice Problem ATTEMPT
Deduce the formulas of...Ch. 2.5 - Practice ProblemBUILD Deduce the formulas of the...Ch. 2.5 - Practice Problem CONCEPTUALIZE
The diagram...Ch. 2.6 - Prob. 1PPACh. 2.6 - Practice ProblemBUILD Name the following species:...Ch. 2.6 - Prob. 1PPCCh. 2.6 - Prob. 1CPCh. 2.6 - Prob. 2CPCh. 2.6 - Prob. 3CPCh. 2.6 - 2.6.4 What is the formula of nickel(II) nitrate...Ch. 2.6 - Prob. 5CPCh. 2.6 - Prob. 6CPCh. 2.7 - Practice ProblemATTEMPT Chloroform was used as an...Ch. 2.7 - Practice ProblemBUILD Write the molecular formula...Ch. 2.7 - Prob. 1PPCCh. 2.7 - Prob. 1CPCh. 2.7 - 2.7.2 What is the name of the compound...Ch. 2.7 - What is the correct formula for the compound...Ch. 2.7 - 2.7.4 What is the empirical formula of the...Ch. 2.8 - Practice Problem ATTEMPT
Name the following...Ch. 2.8 - Practice ProblemBUILD Name the following binary...Ch. 2.8 - Practice Problem CONCEPTUALIZE
Name the binary...Ch. 2.9 - Practice ProblemATTEMPT Give the molecular formula...Ch. 2.9 - Practice ProblemBUILD Give the molecular formula...Ch. 2.9 - Prob. 1PPCCh. 2.10 - Practice ProblemATTEMPT Determine the formula of...Ch. 2.10 - Practice ProblemBUILD Determine the formula of...Ch. 2.10 - Practice ProblemCONCEPTUALIZE Referring to the...Ch. 2.11 - Practice Problem ATTEMPT
Write empirical formulas...Ch. 2.11 - Practice ProblemBUILD For which of the following...Ch. 2.11 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 2 - Prob. 1KSPCh. 2 - Prob. 2KSPCh. 2 - Prob. 3KSPCh. 2 - What is the correct formula for phosphorus...Ch. 2 - What are the hypotheses on which Dalton's atomic...Ch. 2 - State the laws of definite proportions and...Ch. 2 - Prob. 3QPCh. 2 - Prob. 4QPCh. 2 - 2.5 Sulfur reacts with fluorine to produce three...Ch. 2 - 2.6 Both and contain only iron and oxygen. The...Ch. 2 - For the two compounds pictured, evaluate the...Ch. 2 - 2.8 For the two compounds pictured, evaluate the...Ch. 2 - Prob. 9QPCh. 2 - Prob. 10QPCh. 2 - Prob. 11QPCh. 2 - Describe the contributions of the following...Ch. 2 - 2.13 Describe the experimental basis for believing...Ch. 2 - The diameter of a neutral helium atom is about 1 ×...Ch. 2 - Prob. 15QPCh. 2 - Prob. 16QPCh. 2 - Prob. 17QPCh. 2 - Prob. 18QPCh. 2 - Prob. 19QPCh. 2 - 2.20 What is the mass number of an iron atom that...Ch. 2 - Prob. 21QPCh. 2 - 2.22 For each of the following species, determine...Ch. 2 - 2.23 Indicate the number of protons, neutrons, and...Ch. 2 - Prob. 24QPCh. 2 - Prob. 25QPCh. 2 - 2.26 Determine the mass number of (a) a boron atom...Ch. 2 - Prob. 27QPCh. 2 - Prob. 28QPCh. 2 - What is the periodic table, and what is its...Ch. 2 - 2.30 State two differences between a metal and a...Ch. 2 - Prob. 31QPCh. 2 - Give two examples of each of the following: (a)...Ch. 2 - Prob. 33QPCh. 2 - Prob. 34QPCh. 2 - Prob. 35QPCh. 2 - Prob. 36QPCh. 2 - Prob. 37QPCh. 2 - Prob. 38QPCh. 2 - Prob. 39QPCh. 2 - Prob. 40QPCh. 2 - Prob. 41QPCh. 2 - Prob. 42QPCh. 2 - Prob. 43QPCh. 2 - Prob. 44QPCh. 2 - The atomic masses of 204 Pb ( 1 .4 percent ) . 206...Ch. 2 - Prob. 46QPCh. 2 - Prob. 47QPCh. 2 - 2.48 What is the mass in grams of 13.2 amu?
Ch. 2 - Prob. 49QPCh. 2 - Prob. 50QPCh. 2 - Prob. 51QPCh. 2 - Prob. 52QPCh. 2 - Prob. 53QPCh. 2 - Prob. 54QPCh. 2 - Prob. 55QPCh. 2 - Prob. 56QPCh. 2 - Prob. 57QPCh. 2 - Prob. 58QPCh. 2 - Prob. 59QPCh. 2 - Prob. 60QPCh. 2 - 2.61 Name the following compounds:
Ch. 2 - Prob. 62QPCh. 2 - Prob. 63QPCh. 2 - Prob. 64QPCh. 2 - Prob. 65QPCh. 2 - Prob. 66QPCh. 2 - Prob. 67QPCh. 2 - Prob. 68QPCh. 2 - Prob. 69QPCh. 2 - Prob. 70QPCh. 2 - Prob. 71QPCh. 2 - Prob. 72QPCh. 2 - Prob. 73QPCh. 2 - Prob. 74QPCh. 2 - Prob. 75QPCh. 2 - Prob. 76QPCh. 2 - Prob. 77QPCh. 2 - Prob. 78QPCh. 2 - Prob. 79QPCh. 2 - Prob. 80QPCh. 2 - Prob. 81QPCh. 2 - Prob. 82QPCh. 2 - Prob. 83QPCh. 2 - Prob. 84QPCh. 2 - Prob. 85QPCh. 2 - Prob. 86QPCh. 2 - Prob. 87APCh. 2 - Prob. 88APCh. 2 - Prob. 89APCh. 2 - One isotope of a metallic element has mass number...Ch. 2 - Prob. 91APCh. 2 - Prob. 92APCh. 2 - 2.93 What is wrong with or ambiguous about the...Ch. 2 - Prob. 94APCh. 2 - Prob. 95APCh. 2 - Prob. 96APCh. 2 - Prob. 97APCh. 2 - Prob. 98APCh. 2 - Prob. 99APCh. 2 - Prob. 100APCh. 2 - Prob. 101APCh. 2 - Prob. 102APCh. 2 - Prob. 103APCh. 2 - Determine the molecular and empirical formulas of...Ch. 2 - Prob. 105APCh. 2 - Prob. 106APCh. 2 - The Group 1B metals . Cu, Ag, and Au, are called...Ch. 2 - Prob. 108APCh. 2 - Prob. 109APCh. 2 - Prob. 110APCh. 2 - Two elements form a compound that can be...Ch. 2 - Which of the diagrams can be used to illustrate...Ch. 2 - Prob. 113APCh. 2 - Prob. 114APCh. 2 - Prob. 115APCh. 2 - 2.116 Show the locations of (a) alkali metals, (b)...Ch. 2 - Prob. 117APCh. 2 - Prob. 118APCh. 2 - Prob. 119APCh. 2 - 2.120 (a) Describe Rutherford’s experiment and how...Ch. 2 - Prob. 121APCh. 2 - Prob. 122APCh. 2 - Prob. 123APCh. 2 - A cube made of platinum (Pt) has an edge length of...Ch. 2 - Prob. 125APCh. 2 - Prob. 126APCh. 2 - Prob. 1SEPPCh. 2 - Prob. 2SEPPCh. 2 - Prob. 3SEPPCh. 2 - Prob. 4SEPP
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