Resonance structure of anion 2 and cation 3 of the given compound has to be drawn. Concept Introduction: Curved arrows are necessary in drawing the resonance structure. Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going. The two rules in drawing the resonance structure is, Breaking of single bond is not allowed. Never exceed an octet for second row elements. When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

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Answer 1

Question

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

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Answer 2

Question

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

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Answer 3

Question

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

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Answer 4

Question

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

Expert Solution & Answer

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Answer 5

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

Answer 6

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

Answer 7

Chapter 2, Problem 83CP

(a)

Interpretation Introduction

Interpretation:

Resonance structure of anion 2 and cation 3 of the given compound has to be drawn.

Concept Introduction:

Curved arrows are necessary in drawing the resonance structure.

Curved arrows has a head indicating that the electrons are coming and tail indicating that the electrons are going.

The two rules in drawing the resonance structure is,

Breaking of single bond is not allowed.

Never exceed an octet for second row elements.

When a single Lewis structure does not represent a structure adequately, the true structure is the intermediate between the two or more structure referred to as resonance structure.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

Answer 9

(b)

Interpretation Introduction

Interpretation:

Reason for why C-C bond length in compound 1 varies greatly but bond length in ions of 2 and 3 are similar has to be explained.

Concept Introduction:

Bond length: Bond distance or bond length is the average distance between nuclei of two bonded atoms in a molecule. It is a transferable property of a bond between atoms of fixed types

Single bond (1.54 A0) are longer than double bond (1.34 A0) and triple bond(1.20 A0)

Answer 10

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Reason for why the intermolecular hydrogen bonding in structure 3 diminishes in comparison to the structure 1 has to be explained.

Concept Introduction:

Hydrogen bonding is a type of dipole-dipole interaction of molecules when the hydrogen is bonded to strong electronegative atom (F, O, N, etc) in the molecules.

Intramolecular hydrogen bonding is the hydrogen bonding with a molecule.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 2.1 - Prob. 1LTS Ch. 2.1 - Prob. 1PTS Ch. 2.1 - Prob. 2ATS Ch. 2.2 - Prob. 2LTS Ch. 2.2 - Prob. 3PTS Ch. 2.2 - Prob. 4ATS Ch. 2.2 - Prob. 3LTS Ch. 2.2 - Prob. 5PTS Ch. 2.2 - Certain compounds that are alternatives to fossil...Ch. 2.3 - Prob. 7CC

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