Chemistry & Chemical Reactivity
9th Edition
ISBN: 9781133949640
Author: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 75PS
Sulfur trioxide, SO3, is made industrially in enormous quantities by combining oxygen and sulfur dioxide SO2. What amount (moles) of SO3 is represented by 1.00 kg of sulfur trioxide? How many molecules? How many sulfur atoms? How many oxygen atoms?
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5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 2 Solutions
Chemistry & Chemical Reactivity
Ch. 2.2 - 1. What is the mass of an iron atom with 30...Ch. 2.2 - 1. The mass of an atom of manganese is 54.9380 u....Ch. 2.2 - An atom contains 12 neutrons and has a mass number...Ch. 2.3 - 1. Silver has two isotopes, one with 60 neutrons...Ch. 2.3 - 2. A naturally occurring sample of argon contains...Ch. 2.4 - Verify that the atomic weight of chlorine is...Ch. 2.4 - Neon has three stable isotopes, one with a small...Ch. 2.4 - 1. Which is the more abundant isotope of copper,...Ch. 2.4 - 2. Which of the following is closest to the...Ch. 2.4 - Prob. 3RC
Ch. 2.5 - Prob. 1QCh. 2.5 - Prob. 2QCh. 2.5 - Which of the following elements is a metalloid?...Ch. 2.5 - Prob. 2RCCh. 2.5 - Prob. 3RCCh. 2.5 - Prob. 4RCCh. 2.6 - Prob. 1RCCh. 2.7 - Give the number and identity of the constituent...Ch. 2.7 - (a) Write the formulas of all neutral ionic...Ch. 2.7 - Prob. 1RCCh. 2.7 - Prob. 2RCCh. 2.7 - Prob. 3RCCh. 2.7 - The formula of barium acetate is (a) Ba(CH3CO2)2...Ch. 2.7 - 5. The name of the compound with the formula V2O3...Ch. 2.7 - Which should have the higher melting point, MgO or...Ch. 2.8 - Prob. 1RCCh. 2.8 - Prob. 2RCCh. 2.8 - Prob. 3RCCh. 2.8 - Prob. 4RCCh. 2.9 - The density of gold, Au, is 19.32 g/cm3. What is...Ch. 2.9 - If you have 454 g of citric acid (H3C6H5O7), what...Ch. 2.9 - Prob. 1RCCh. 2.9 - Which of the following contains the largest number...Ch. 2.9 - Which of the following has the largest mass? (a)...Ch. 2.9 - Prob. 4RCCh. 2.9 - Prob. 5RCCh. 2.10 - 1. Express the composition of ammonium carbonate,...Ch. 2.10 - 1. What is the empirical formula of naphthalene,...Ch. 2.10 - Gallium oxide, GaxOy forms when gallium is combine...Ch. 2.10 - Hydrated nickel(II) chloride is a beautiful green,...Ch. 2.10 - Prob. 1QCh. 2.10 - Salvarsan was long thought to be a single...Ch. 2.10 - To determine the density of atmospheric nitrogen....Ch. 2.10 - The density of a mixture of gases may be...Ch. 2.10 - Atmospheric argon is a mixture of three stable...Ch. 2.10 - Given that the density of argon is 1.78 g/L under...Ch. 2.10 - 1. Which of the following hydrocarbons has the...Ch. 2.10 - 2. An organic compound has an empirical formula...Ch. 2.10 - Eugenol is the major component in oil of cloves....Ch. 2.10 - 4. Epsom salt is MgSO4 · 7H2O. When heated to 70...Ch. 2 - Prob. 1PSCh. 2 - Define mass number. What is the difference between...Ch. 2 - An atom has a very small nucleus surrounded by an...Ch. 2 - A gold atom has a radius of 145 pm. If you could...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Give the complete symbol(ZAX), including atomic...Ch. 2 - Prob. 7PSCh. 2 - Atomic structure. (a) The synthetic radioactive...Ch. 2 - Prob. 9PSCh. 2 - In 1886 Eugene Goldstein observed positively...Ch. 2 - Marie Curie was born in Poland but studied and...Ch. 2 - Prob. 12PSCh. 2 - The mass of an 16 O atom is 15.995 u. What is its...Ch. 2 - What is the mass of one 16O atom, in grams? (The...Ch. 2 - Cobalt has three radioactive isotopes used in...Ch. 2 - Naturally occurring silver exists as two isotopes...Ch. 2 - Name and describe the composition of the three...Ch. 2 - Which of the following are isotopes of element X,...Ch. 2 - Thallium has two stable isotopes, 203TIand 205Tl....Ch. 2 - Strontium has four stable isotopes. 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(a)...Ch. 2 - Cacodyl, a compound containing arsenic, was...Ch. 2 - The action of bacteria on meat and fish produces a...Ch. 2 - In the laboratory you combine 0.125 g of nickel...Ch. 2 - A compound called MMT was once used to boost the...Ch. 2 - Elemental phosphorus is made by heating calcium...Ch. 2 - Chromium is obtained by heating chromium(III)...Ch. 2 - Stibnite, Sb2S3, is a dark gray mineral from which...Ch. 2 - Direct reaction of iodine (I2) and chlorine (Cl2)...Ch. 2 - In a reaction, 2.04 g of vanadium combined with...Ch. 2 - Iron pyrite, often called fools gold, has the...Ch. 2 - Which of the following statements about 57.1 g of...Ch. 2 - The formula of barium molybdate is BaMoO4. Which...Ch. 2 - A metal M forms a compound with the formula MCl4....Ch. 2 - Pepto-Bismol, which can help provide relief for an...Ch. 2 - The weight percent of oxygen in an oxide that has...Ch. 2 - The mass of 2.50 mol of a compound with the...Ch. 2 - The elements A and Z combine to produce two...Ch. 2 - Polystyrene can be prepared by heating styrene...Ch. 2 - A sample of hemoglobin is found to be 0.335% iron....Ch. 2 - Consider an atom of 64Zn. (a) Calculate the...Ch. 2 - Estimating the radius of a lead atom. (a) You are...Ch. 2 - A piece of nickel foil, 0.550 mm thick and 1.25 cm...Ch. 2 - Uranium is used as a fuel, primarily in the form...Ch. 2 - In an experiment, you need 0.125 mol of sodium...Ch. 2 - Mass spectrometric analysis showed that there are...Ch. 2 - The mass spectrum of CH3Cl is illustrated here....Ch. 2 - Prob. 156GQCh. 2 - If Epsom salt, MgSO4 x H2O, is heated to 250 C,...Ch. 2 - The alum used in cooking is potassium aluminum...Ch. 2 - Tin metal (Sn) and purple iodine (I2) combine to...Ch. 2 - When analyzed, an unknown compound gave these...Ch. 2 - Two general chemistry students working together in...Ch. 2 - To find the empirical formula of tin oxide, you...Ch. 2 - Prob. 163SCQCh. 2 - Prob. 164SCQCh. 2 - The photo here depicts what happens when a coil of...Ch. 2 - A jar contains some number of jelly beans. To find...
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