Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 2, Problem 65AE
Interpretation Introduction
Interpretation:The depicted
Concept introduction: Any chemical reaction involves transformation of its reactants to finally generate products. The reactants react in their elemental forms which can be atomic or molecular. The generated compounds consist of number of same molecules which are composed of atoms of distinct elements.
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1. Predict the organic product(s) of the following reactions. Assume excess of reagents unless
otherwise noted.
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b)
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2) H3O+
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1) EtMgBr
2) H3O+
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There are 48 pairs of students in the following table. Each pair has quantitatively determined the mass of taurine in a 250 mL can of the popular energy drink marketed as “Munster” using High Performance Liquid Chromatography (HPLC). The class results are presented below:
QUESTION: Summarise and report these results including an indication of measurement uncertainty.
In both calculation samples calculate if an outlier is present, max value, number of samples, mean, standard deviation, g (suspect), g (critical) and t (critical).
Mass of Taurine (mg)
Mass of Taurine (mg)
(Table continued)
152.01
152.23
151.87
151.45
154.11
152.64
152.98
153.24
152.88
151.45
153.49
152.48
150.68
152.33
151.52
153.63
152.48
151.68
153.17
153.40
153.77
153.67
152.34
153.16
152.57
153.02
152.86
151.50
151.23
152.57
152.72
151.54
146.47
152.38
152.44
152.54
152.53
152.54
151.32…
Indicate the rate expressions for reactions that have order 0, 1, and 2.
Chapter 2 Solutions
Chemical Principles
Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of...Ch. 2 - These questions concern the work of J. J. Thomson:...Ch. 2 - Heat is applied to an ice cube in a closed...Ch. 2 - You have a chemical in a sealed glass container...Ch. 2 - Prob. 7DQCh. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9DQCh. 2 - How does Dalton’s atomic theory account for each...
Ch. 2 - What refinements had to be made in Dalton’s...Ch. 2 - Which (if any) of the following can be determined...Ch. 2 - The average mass of a carbon atom is 12.011....Ch. 2 - Which of the following explain how an ion is...Ch. 2 - Prob. 15DQCh. 2 - Prob. 16DQCh. 2 - Why is calcium dichloride not the correct...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Prob. 19ECh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - Prob. 22ECh. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 80.0-g samples of two different compounds...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - Prob. 27ECh. 2 - Prob. 28ECh. 2 - A chemist in a galaxy far, far away performed the...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - Consider Ernest Rutherford’s a-particle...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Prob. 34ECh. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - Consider the elements of the carbon family: C, Si,...Ch. 2 - Prob. 37ECh. 2 - The number of protons in an atom determines the...Ch. 2 - For lighter, stable isotopes, the ratio of the...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 41ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 48ECh. 2 - The compounds AlCl3,CrCl3,andICl3 have similar...Ch. 2 - Each of the following compounds has three...Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62AECh. 2 - Prob. 63AECh. 2 - What discoveries were made by J. J. Thomson,...Ch. 2 - Prob. 65AECh. 2 - Prob. 66AECh. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 2 - Prob. 69AECh. 2 - Prob. 70AECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Identify each of the following elements. a. a...Ch. 2 - A certain element has only two naturally occurring...Ch. 2 - Prob. 82AECh. 2 - Which of the following is(are) correct? a. 40Ca2+...Ch. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Complete the following table to predict whether...Ch. 2 - Which of the following statements is(are) correct?...Ch. 2 - Prob. 88CPCh. 2 - Each of the statements below is true, but Dalton...Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Two elements, R and Q, combine to form two...Ch. 2 - A single molecule has a mass of 7.3110223g ....Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - You have gone back in time and are working with...
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- PROBLEMS Q1) Label the following salts as either acidic, basic, or neutral a) Fe(NOx) c) AlBr b) NH.CH COO d) HCOON (1/2 mark each) e) Fes f) NaBr Q2) What is the pH of a 0.0750 M solution of sulphuric acid?arrow_forward8. Draw all the resonance forms for each of the fling molecules or ions, and indicate the major contributor in each case, or if they are equivalent (45) (2) -PH2 سمة مدarrow_forwardA J то گای ه +0 Also calculate the amount of starting materials chlorobenzaldehyde and p-chloroacetophenone required to prepare 400 mg of the given chalcone product 1, 3-bis(4-chlorophenyl)prop-2-en-1-one molar mass ok 1,3-bis(4-Chlorophenyl) prop-2-en-1-one = 277.1591m01 number of moles= 0.400/277.15 = 0.00144 moles 2 x 0.00 144=0.00288 moves arams of acetophenone = 0.00144 X 120.16 = 0.1739 0.1739x2=0.3469 grams of benzaldehyde = 0.00144X106.12=0.1539 0.1539x2 = 0.3069 Starting materials: 0.3469 Ox acetophenone, 0.3069 of benzaldehyde 3arrow_forward
- 1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.arrow_forward3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗarrow_forward2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br Oarrow_forward
- 4. For the reactions below, draw the expected product. Be sure to indicate relevant stereochemistry or formal charges in the product structure. a) CI, H e b) H lux ligh Br 'Harrow_forwardArrange the solutions in order of increasing acidity. (Note that K (HF) = 6.8 x 10 and K (NH3) = 1.8 × 10-5) Rank solutions from least acidity to greatest acidity. To rank items as equivalent, overlap them. ▸ View Available Hint(s) Least acidity NH&F NaBr NaOH NH,Br NaCIO Reset Greatest acidityarrow_forward1. Consider the following molecular-level diagrams of a titration. O-HA molecule -Aion °° о ° (a) о (b) (c) (d) a. Which diagram best illustrates the microscopic representation for the EQUIVALENCE POINT in a titration of a weak acid (HA) with sodium. hydroxide? (e)arrow_forward
- Answers to the remaining 6 questions will be hand-drawn on paper and submitted as a single file upload below: Review of this week's reaction: H₂NCN (cyanamide) + CH3NHCH2COOH (sarcosine) + NaCl, NH4OH, H₂O ---> H₂NC(=NH)N(CH3)CH2COOH (creatine) Q7. Draw by hand the reaction of creatine synthesis listed above using line structures without showing the Cs and some of the Hs, but include the lone pairs of electrons wherever they apply. (4 pts) Q8. Considering the Zwitterion form of an amino acid, draw the Zwitterion form of Creatine. (2 pts) Q9. Explain with drawing why the C-N bond shown in creatine structure below can or cannot rotate. (3 pts) NH2(C=NH)-N(CH)CH2COOH This bond Q10. Draw two tautomers of creatine using line structures. (Note: this question is valid because problem Q9 is valid). (4 pts) Q11. Mechanism. After seeing and understanding the mechanism of creatine synthesis, students should be ready to understand the first half of one of the Grignard reactions presented in a past…arrow_forwardPropose a synthesis pathway for the following transformations. b) c) d)arrow_forwardThe rate coefficient of the gas-phase reaction 2 NO2 + O3 → N2O5 + O2 is 2.0x104 mol–1 dm3 s–1 at 300 K. Indicate whether the order of the reaction is 0, 1, or 2.arrow_forward
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