Chemical Principles
8th Edition
ISBN: 9781305581982
Author: Steven S. Zumdahl, Donald J. DeCoste
Publisher: Cengage Learning
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Chapter 2, Problem 33E
What is the distinction between
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Chapter 2 Solutions
Chemical Principles
Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of...Ch. 2 - These questions concern the work of J. J. Thomson:...Ch. 2 - Heat is applied to an ice cube in a closed...Ch. 2 - You have a chemical in a sealed glass container...Ch. 2 - Prob. 7DQCh. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9DQCh. 2 - How does Dalton’s atomic theory account for each...
Ch. 2 - What refinements had to be made in Dalton’s...Ch. 2 - Which (if any) of the following can be determined...Ch. 2 - The average mass of a carbon atom is 12.011....Ch. 2 - Which of the following explain how an ion is...Ch. 2 - Prob. 15DQCh. 2 - Prob. 16DQCh. 2 - Why is calcium dichloride not the correct...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Prob. 19ECh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - Prob. 22ECh. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 80.0-g samples of two different compounds...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - Prob. 27ECh. 2 - Prob. 28ECh. 2 - A chemist in a galaxy far, far away performed the...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - Consider Ernest Rutherford’s a-particle...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Prob. 34ECh. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - Consider the elements of the carbon family: C, Si,...Ch. 2 - Prob. 37ECh. 2 - The number of protons in an atom determines the...Ch. 2 - For lighter, stable isotopes, the ratio of the...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 41ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Prob. 43ECh. 2 - Prob. 44ECh. 2 - Prob. 45ECh. 2 - Prob. 46ECh. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 48ECh. 2 - The compounds AlCl3,CrCl3,andICl3 have similar...Ch. 2 - Each of the following compounds has three...Ch. 2 - Prob. 51ECh. 2 - Prob. 52ECh. 2 - Prob. 53ECh. 2 - Prob. 54ECh. 2 - Prob. 55ECh. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Prob. 58ECh. 2 - Prob. 59ECh. 2 - Prob. 60ECh. 2 - Prob. 61ECh. 2 - Prob. 62AECh. 2 - Prob. 63AECh. 2 - What discoveries were made by J. J. Thomson,...Ch. 2 - Prob. 65AECh. 2 - Prob. 66AECh. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - In a reaction, 34.0 g of chromium(III) oxide...Ch. 2 - Prob. 69AECh. 2 - Prob. 70AECh. 2 - Prob. 71AECh. 2 - Prob. 72AECh. 2 - Prob. 73AECh. 2 - Prob. 74AECh. 2 - Prob. 75AECh. 2 - Prob. 76AECh. 2 - Prob. 77AECh. 2 - Prob. 78AECh. 2 - Prob. 79AECh. 2 - Identify each of the following elements. a. a...Ch. 2 - A certain element has only two naturally occurring...Ch. 2 - Prob. 82AECh. 2 - Which of the following is(are) correct? a. 40Ca2+...Ch. 2 - Prob. 84AECh. 2 - Prob. 85AECh. 2 - Complete the following table to predict whether...Ch. 2 - Which of the following statements is(are) correct?...Ch. 2 - Prob. 88CPCh. 2 - Each of the statements below is true, but Dalton...Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Two elements, R and Q, combine to form two...Ch. 2 - A single molecule has a mass of 7.3110223g ....Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - You have gone back in time and are working with...
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- Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0arrow_forwardConsider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2arrow_forwardNonearrow_forward
- Nonearrow_forwardn Feb 3 A T + 4. (2 pts) Draw the structure of the major component of the Limonene isolated. Explain how you confirmed the structure. 5. (2 pts) Draw the fragment corresponding to the base peak in the Mass spectrum of Limonene. 6. (1 pts) Predict the 1H NMR spectral data of R-Limonene. Proton NMR: 5.3 pon multiplet (H Ringarrow_forwardPart VI. Ca H 10 O is the molecular formula of compound Tom and gives the in the table below. Give a possible structure for compound Tom. 13C Signals summarized C1 C2 C3 C4 C5 C6 C7 13C shift (ppm) 23.5 27.0 33.0 35.8 127 162 205 DEPT-90 + DEPT-135 + +arrow_forward
- 2. Using the following data to calculate the value of AvapH o of water at 298K. AvapH o of water at 373K is 40.7 kJ/mol; molar heat capacity of liquid water at constant pressure is 75.2J mol-1 K-1 and molar heat capacity of water vapor at constant pressure is 33.6 J mol-1 K-1.arrow_forwardPart VII. Below are the 'HNMR 13 3 C-NMR, COSY 2D- NMR, and HSQC 20-NMR (Similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H13 O. Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum ли 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 1.0 0.9 0.8 f1 (ppm)arrow_forward3. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-pentene. expanded structure: Condensed structure: Skeletal formula: 4. Draw the expanded structural formula, the condensed structural formula, and the skeletal structural formula for 2-methyl-3-heptene. expanded structure: Condensed structure: Skeletal formula: following structurearrow_forward
- Part IV. Propose a plausible Structure w/ the following descriptions: a) A 5-carbon hydrocarbon w/ a single peak in its proton decoupled the DEPT-135 Spectrum shows a negative peak C-NMR spectrum where b) what cyclohexane dione isomer gives the largest no. Of 13C NMR signals? c) C5H120 (5-carbon alcohol) w/ most deshielded carbon absent in any of its DEPT Spectivaarrow_forward13C NMR is good for: a) determining the molecular weight of the compound b) identifying certain functional groups. c) determining the carbon skeleton, for example methyl vs ethyl vs propyl groups d) determining how many different kinds of carbon are in the moleculearrow_forward6 D 2. (1 pt) Limonene can be isolated by performing steam distillation of orange peel. Could you have performed this experiment using hexane instead of water? Explain. 3. (2 pts) Using GCMS results, analyze and discuss the purity of the Limonene obtained from the steam distillation of orange peel.arrow_forward
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