Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
4th Edition
ISBN: 9781260269284
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 2, Problem 35P
Interpretation Introduction
Interpretation:
The element located in group 
which is not an alkali metal is to be identified.
Concept introduction:
The elements are placed in periodic table according to their
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32. Consider a two-state system in which the low energy level is 300 J mol 1 and the higher energy
level is 800 J mol 1, and the temperature is 300 K. Find the population of each level. Hint: Pay attention
to your units.
A. What is the partition function for this system?
B. What are the populations of each level?
Now instead, consider a system with energy levels of 0 J mol
C. Now what is the partition function?
D. And what are the populations of the two levels?
E. Finally, repeat the second calculation at 500 K.
and 500 J mol 1 at 300 K.
F. What do you notice about the populations as you increase the temperature? At what temperature
would you expect the states to have equal populations?
30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in
class, but the partition function that describes the translational and rotational motion of a homonuclear
diatomic molecule is given by
Itrans (V,T) =
=
2πmkBT
h²
V
grot (T)
4π²IKBT
h²
Where h is Planck's constant and I is molecular moment of inertia.
The overall partition function is qmolec Qtrans qrot.
Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational
modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a
volume of 1 m³. Here is some useful data:
Moment of inertia:
I2 I 7.46 x 10-
45
kg m²
2
O2 I 1.91 x 101
-46
kg m²
K
for each reaction step.
Be sure to account for all bond-breaking and bond-making
steps.
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Chapter 2 Solutions
Loose Leaf for General, Organic and Biological Chemistry with Connect 2 Year Access Card
Ch. 2.1 - Give the symbol for each element. a. calcium, a...Ch. 2.1 - Give the name corresponding to each element...Ch. 2.1 - Locate each element in the periodic table and...Ch. 2.1 - Prob. 2.4PCh. 2.1 - Identify the elements used ineach example of...Ch. 2.1 - Identify the elements in each chemical formula,...Ch. 2.1 - Prob. 2.6PCh. 2.1 - Prob. 2.2PPCh. 2.2 - Prob. 2.3PPCh. 2.2 - Prob. 2.4PP
Ch. 2.2 - For the given atom: (a) determine the number of...Ch. 2.2 - How many protons, neutrons, and electrons are...Ch. 2.2 - What is the mass number of an atom that contains...Ch. 2.3 - For each atom give the following information: [1]...Ch. 2.3 - Write an isotope symbol for the isotope of...Ch. 2.3 - Magnesium has three isotopes that contain 12, 13,...Ch. 2.3 - Prob. 2.9PPCh. 2.3 - Calculate the atomic weight of each element given...Ch. 2.4 - Prob. 2.9PCh. 2.4 - Label each macronutrient in Figure 2.2 in the...Ch. 2.4 - Identify the element fitting each description. an...Ch. 2.4 - Identify each highlighted element in the periodic...Ch. 2.5 - How many electrons are present in each shell,...Ch. 2.6 - What element has each electronic configuration? a....Ch. 2.6 - What element(s) in the first and second period fit...Ch. 2.6 - Draw an orbital diagram for each element; (a)...Ch. 2.6 - Give the electronic configuration for each element...Ch. 2.7 - Prob. 2.13PPCh. 2.7 - Determine the number of valence electrons and give...Ch. 2.7 - Give the electron-dot symbol for each element: (a)...Ch. 2.8 - Which element in each pair has the larger atomic...Ch. 2.8 - Prob. 2.16PCh. 2.8 - Prob. 2.17PPCh. 2.8 - (a) Which of the indicated atoms has the smaller...Ch. 2 - Identify the elements used in each example of...Ch. 2 - Write a chemical formula for each example of...Ch. 2 - Give the name of the elements in each group of...Ch. 2 - What element(s) are designated by each symbol or...Ch. 2 - Does each chemical formula represent an element or...Ch. 2 - Identify the elements in each chemical formula and...Ch. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - Give all of the terms that apply to each...Ch. 2 - Give all of the terms that apply to each...Ch. 2 - Give the following information about the atom...Ch. 2 - Give the following information about the atom...Ch. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - Prob. 31PCh. 2 - Consider the four atoms-L, M, N, and X- with the...Ch. 2 - Label each region on the periodic table. Noble...Ch. 2 - Identify each highlighted element in the periodic...Ch. 2 - Prob. 35PCh. 2 - Prob. 36PCh. 2 - Prob. 37PCh. 2 - Prob. 38PCh. 2 - Prob. 39PCh. 2 - Complete the followin table for the two most...Ch. 2 - How many protons, neutrons, and electrons are...Ch. 2 - Give the number of protons, neutrons, and...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Write the element symbol that fits each...Ch. 2 - Calculate the atomic weight of silver, which has...Ch. 2 - Calculate the atomic weight of antimony, which has...Ch. 2 - Prob. 47PCh. 2 - What is the maximum number of electrons that can...Ch. 2 - Prob. 49PCh. 2 - Use an orbital diagram to write the electronic...Ch. 2 - Prob. 51PCh. 2 - For each element in Problem 2.50: (a) Write out...Ch. 2 - Prob. 53PCh. 2 - Prob. 54PCh. 2 - Give the total number of electrons, the number of...Ch. 2 - Give the total number of electrons, the number of...Ch. 2 - Prob. 57PCh. 2 - Prob. 58PCh. 2 - Prob. 59PCh. 2 - Prob. 60PCh. 2 - Prob. 61PCh. 2 - Which of the following orbital diagrams are...Ch. 2 - Prob. 63PCh. 2 - Prob. 64PCh. 2 - Prob. 65PCh. 2 - Write an electron-dot symbol for each element: (a)...Ch. 2 - Prob. 67PCh. 2 - Prob. 68PCh. 2 - Prob. 69PCh. 2 - Prob. 70PCh. 2 - Prob. 71PCh. 2 - For each pair of elements in Problem 2.70, label...Ch. 2 - Rank the atoms in each group in order of...Ch. 2 - Prob. 74PCh. 2 - Prob. 75PCh. 2 - Prob. 76PCh. 2 - Prob. 77PCh. 2 - Prob. 78PCh. 2 - Prob. 79PCh. 2 - (a) What is the chemical formula for...Ch. 2 - Answer the following questions about the...Ch. 2 - Platinum is a precious metal used in a wide...Ch. 2 - Prob. 83PCh. 2 - Answer the following questions about the...Ch. 2 - Prob. 85CPCh. 2 - Prob. 86CP
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