
Chemistry for Changing Times
14th Edition
ISBN: 9780134212777
Author: John W. Hill; Terry W. McCreary
Publisher: Pearson Education (US)
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Question
Chapter 2, Problem 32P
Interpretation Introduction
Interpretation:
When elements react, their combination of atoms should be determined by Dalton's atomic theory.
Concept introduction:
Dalton’s atomic theory postulates that elements are formed of very small particles called atoms which are identical for an element in case of mass, size and other properties. It also states that atoms can neither be destroyed nor created.
Correct answer:
The answer is (a), a simple whole number ratio that is unique for each set of elements.
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2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Interpreting NMR spectra is a skill that often requires some
amount of practice, which, in turn, necessitates access to a
collection of NMR spectra. Beyond Labz Organic Synthesis and
Organic Qualitative Analysis have spectral libraries containing
over 700 1H NMR spectra. In this assignment, you will take
advantage of this by first predicting the NMR spectra for two
closely related compounds and then checking your predictions
by looking up the actual spectra in the spectra library. After
completing this assignment, you may wish to select other
compounds for additional practice.
1. Write the IUPAC names for the following two structures:
Question 2
Question 3
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
11:14
...
worksheets.beyondlabz.com
3. To check your predictions, click this link for Interpreting
NMR Spectra 1. You will see a list of all the
-
compounds in the spectra library in alphabetical order by
IUPAC name. Hovering over a name in the list will show
the structure on the chalkboard. The four buttons on the
top of the Spectra tab in the tray are used to select the
different spectroscopic techniques for the selected
compound. Make sure the NMR button has been selected.
4. Scroll through the list of names to find the names for the
two compounds you have been given and click on the
name to display the NMR spectrum for each. In the NMR
tables below, list the chemical shift, the splitting, and
the number of hydrogens associated with each peak for
each compound. Compare your answers to your
predictions.
**Not all slots must be filled**
Peak
Chemical Shift (d)
Multiplicity
1
2
3
4
5
Chapter 2 Solutions
Chemistry for Changing Times
Ch. 2 - Prob. 1RQCh. 2 - Prob. 2RQCh. 2 - Prob. 3RQCh. 2 - Prob. 4RQCh. 2 - Cavendish found that water was composed of two...Ch. 2 - Prob. 6RQCh. 2 - Fructose (fruit sugar) is always composed of 40,0%...Ch. 2 - Outline the main points of Dalton's atomic theory,...Ch. 2 - Prob. 9RQCh. 2 - Prob. 10RQ
Ch. 2 - In the figure. the blue spheres represent...Ch. 2 - 12. a. How is Avogadro’s number linked with the...Ch. 2 - Prob. 13RQCh. 2 - Prob. 14RQCh. 2 - Prob. 15PCh. 2 - 16. An iron nail dissolves in a solution of...Ch. 2 - If you place a 400 g effervescent antacid pill...Ch. 2 - Prob. 18PCh. 2 - 19, Acetylene, used for welding, contains 24.02 g...Ch. 2 - 20. Nitrous oxide (N2O, "laughing gas") contains...Ch. 2 - Prob. 21PCh. 2 - Prob. 22PCh. 2 - Prob. 23PCh. 2 - Prob. 24PCh. 2 - When 18.029 of water is decomposed by...Ch. 2 - Prob. 26PCh. 2 - Prob. 27PCh. 2 - Prob. 28PCh. 2 - Prob. 29PCh. 2 - Prob. 30PCh. 2 - 31. Use Dalton's atomic theory to explain what is...Ch. 2 - Prob. 32PCh. 2 - Hydrogen and oxygen combine in a mass ratio of...Ch. 2 - Prob. 34PCh. 2 - Prob. 35PCh. 2 - A compound containing only oxygen and rubidium has...Ch. 2 - 37. A sample of an oxide of tin with the formula...Ch. 2 - 38. Consider three oxides of nitrogen, X, Y, and...Ch. 2 - Prob. 39PCh. 2 - Prob. 40PCh. 2 - Prob. 41PCh. 2 - Prob. 42PCh. 2 - Prob. 43PCh. 2 - Prob. 44PCh. 2 - A blue solid called azulene is thought to be a...Ch. 2 - Prob. 46PCh. 2 - Prob. 47APCh. 2 - Prob. 48APCh. 2 - Prob. 49APCh. 2 - Prob. 50APCh. 2 - 51. See Table 2.1 . Another compound of nitrogen...Ch. 2 - Prob. 52APCh. 2 - Prob. 53APCh. 2 - Prob. 54APCh. 2 - Prob. 55APCh. 2 - Prob. 56APCh. 2 - Prob. 57APCh. 2 - Prob. 58APCh. 2 - Prob. 2.1CTECh. 2 - When water is electrolyzed, from each one molecule...Ch. 2 - A health-food store has a large display of...Ch. 2 - Prob. 2.4CTECh. 2 - Prob. 2.5CTECh. 2 - Prob. 2.6CTECh. 2 - Prob. 1CGPCh. 2 - Prob. 2CGPCh. 2 - Prob. 3CGPCh. 2 - Prob. 4CGPCh. 2 - Prob. 5CGPCh. 2 - Materials Needed: Alka-Seltzer tablets (8) 1/4 cup...Ch. 2 - Materials Needed: Alka-Seltzer tablets (8) 1/4 cup...Ch. 2 - Prob. 3CHQ
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