Chemistry: Principles and Reactions
8th Edition
ISBN: 9781305079373
Author: William L. Masterton, Cecile N. Hurley
Publisher: Cengage Learning
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Chapter 2, Problem 30QAP
Chlorine has two isotopes, Cl-35 and Cl-37. Their abundances are 75.53% and 24.47%, respectively. Assume that the only hydrogen isotope present is H-1.
(a) How many different HCI molecules are possible?
(b) What is the sum of the mass numbers of the two atoms in each molecule?
(c) Sketch the mass spectrum for HCI if all the positive ions are obtained by removing a single electron from an HCI molecule.
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What spectral features allow you to differentiate the product from the starting material?
Use four separate paragraphs for each set of comparisons. You should have one paragraph each devoted to MS, HNMR, CNMR and IR.
2) For MS, the differing masses of molecular ions are a popular starting point. Including a unique fragmentation is important, too.
3) For HNMR, CNMR and IR state the peaks that are different and what makes them different (usually the presence or absence of certain groups). See if you can find two differences (in each set of IR, HNMR and CNMR spectra) due to the presence or absence of a functional group. Include peak locations. Alternatively, you can state a shift of a peak due to a change near a given functional group. Including peak locations for shifted peaks, as well as what these peaks are due to. Ideally, your focus should be on not just identifying the differences but explaining them in terms of functional group changes.
Chapter 2 Solutions
Chemistry: Principles and Reactions
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