Chemistry: AP Edition - Package
9th Edition
ISBN: 9781285729473
Author: ZUMDAHL
Publisher: CENGAGE L
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Chapter 2, Problem 30Q
The vitamin niacin (nicotinic acid. C6H5NO2) can be isolated from a variety of natural sources such as liver, yeast, milk, and whole grain. It also can be synthesized from commercially available materials. From a nutritional point of view, which source of nicotinic acid is best for use in a multivitamin tablet? Why?
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6. Match each of the lettered items in the column on
the left with the most appropriate numbered
item(s) in the column on the right. Some of the
numbered items may be used more than once
and some not at all.
a.
Z = 37
1.
b.
Mn
2.
C.
Pr
element in period 5 and group
14
element in period 5 and group
15
d. S
e. [Rn] 7s¹
f.
d block
metal
3. highest metallic character of all
the elements
4. paramagnetic with 5 unpaired
electrons
5. 4f36s2
6. isoelectronic with Ca²+ cation
7.
an alkaline metal
8. an f-block element
Draw all formal charges on the structures below as is and draw 1 resonance structure that is more stable.
Part II. xiao isolated a compound TAD (Ca H 10 N₂) from tobacco and obtained its IR spectrum. Xiao proposed
a chemical structure shown below:
% Transmittance
4000
3500
3000
2500 2000
Wavenumber (cm-1)
1500
1000
(a) Explain why her proposed structure is inconsistent with the IR spectrum obtained
(b) TAD exists as a tautomer of the structure xiao proposed. Draw the structure
and explain why it is more compatible with the obtained spectrum.
(C) what is the possible source for the fairly intense signal at
1621cm1
Chapter 2 Solutions
Chemistry: AP Edition - Package
Ch. 2 - Use Daltons atomic theory to account for each of...Ch. 2 - What evidence led to the conclusion that cathode...Ch. 2 - What discoveries were made by J. J. Thomson, Henri...Ch. 2 - Consider Ernest Rutherfords -particle bombardment...Ch. 2 - Do the proton and the neutron have exactly the...Ch. 2 - What is the distinction between atomic number and...Ch. 2 - Distinguish between the terms family and period in...Ch. 2 - The compounds AlCl3, CrCl3, and ICl3 have similar...Ch. 2 - Prob. 9RQCh. 2 - How would you name HBrO4, KIO3, NaBrO2, and HIO?...
Ch. 2 - Which of the following is true about an individual...Ch. 2 - How would you go about finding the number of chalk...Ch. 2 - These questions concern the work of J. J. Thomson....Ch. 2 - Prob. 4ALQCh. 2 - You have a chemical in a sealed glass container...Ch. 2 - The formula of water is If-O. Which of the...Ch. 2 - You may have noticed that when water boils, you...Ch. 2 - One of the best indications of a useful theory is...Ch. 2 - Prob. 9ALQCh. 2 - Prob. 10ALQCh. 2 - Label each of the following as an atomic element,...Ch. 2 - Prob. 12ALQCh. 2 - Prob. 13ALQCh. 2 - Prob. 14ALQCh. 2 - Which of tire following explain how an ion is...Ch. 2 - What refinements had to be made in Daltons atomic...Ch. 2 - When hydrogen is burned in oxygen to form water,...Ch. 2 - The two most reactive families of elements are the...Ch. 2 - Explain the law of conservation of mass, the law...Ch. 2 - Section 2.3 describes the postulates of Daltons...Ch. 2 - The contributions of J. J. Thomson and Ernest...Ch. 2 - Prob. 22QCh. 2 - The number of protons in an atom determines the...Ch. 2 - If the volume of a proton were similar to the...Ch. 2 - Prob. 25QCh. 2 - List some characteristic properties that...Ch. 2 - Consider the elements of Group 4A (the carbon...Ch. 2 - Distinguish between the following terms. a....Ch. 2 - Label the type of bonding for each of the...Ch. 2 - The vitamin niacin (nicotinic acid. C6H5NO2) can...Ch. 2 - Prob. 31QCh. 2 - Prob. 32QCh. 2 - When mixtures of gaseous H2 and gaseous Cl2 react,...Ch. 2 - Observations of the reaction between nitrogen gas...Ch. 2 - A sample of chloroform is found to contain 12.0 g...Ch. 2 - A sample of H2SO4 contains 2.02 g of hydrogen,...Ch. 2 - Hydrazine, ammonia, and hydrogen azide all contain...Ch. 2 - Consider 100.0-g samples of two different...Ch. 2 - The three most stable oxides of carbon ire carbon...Ch. 2 - Two elements. R and Q, combine to form two binary...Ch. 2 - In Section 1.1 of the text, the concept of a...Ch. 2 - In a combustion reaction, 46.0 g of ethanol reacts...Ch. 2 - Early tables of atomic weights (masses) were...Ch. 2 - Indium oxide contains 4.784 g of indium for every...Ch. 2 - Prob. 45ECh. 2 - If you wanted to make an accurate scale model of...Ch. 2 - In an experiment it was found that the total...Ch. 2 - A chemist in a galaxy tar, far away performed the...Ch. 2 - What are the symbols of the following metals:...Ch. 2 - What are the symbols of the following nonmetals:...Ch. 2 - Give the names of the nonmetals that correspond to...Ch. 2 - a. Classify the following elements as metals or...Ch. 2 - a. List the noble gas elements. Which of the noble...Ch. 2 - For each of the following sets of elements, label...Ch. 2 - Prob. 56ECh. 2 - Prob. 57ECh. 2 - Write the atomic symbol (ZAX) for each of the...Ch. 2 - Write the symbol of each atom using the ZAX...Ch. 2 - For carbon-14 and carbon-12, how many protons and...Ch. 2 - How many protons and neutrons are in the nucleus...Ch. 2 - Prob. 62ECh. 2 - For each of the following ions, indicate the...Ch. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 65ECh. 2 - What is the symbol of an ion with 16 protons, 18...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Complete the following table: Symbol Number of...Ch. 2 - Would you expect each of the following atoms to...Ch. 2 - Prob. 70ECh. 2 - Name the compounds in parts ad and write the...Ch. 2 - Name the compounds in parts a-d and write the...Ch. 2 - Prob. 73ECh. 2 - Prob. 74ECh. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Prob. 77ECh. 2 - Prob. 78ECh. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Prob. 83ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 85ECh. 2 - Write the formula for each of the following...Ch. 2 - Prob. 87ECh. 2 - Each of the following compounds is incorrectly...Ch. 2 - Chlorine has two natural isotopes: 1737Cl and...Ch. 2 - What are the symbols for the following nonmetal...Ch. 2 - Four Fe2+ ions are key components of hemoglobin,...Ch. 2 - Which of the following statements is(are) true?...Ch. 2 - The isotope of an unknown element, X, has a mass...Ch. 2 - Prob. 94AECh. 2 - Prob. 95AECh. 2 - Identify each of the following elements: a. a...Ch. 2 - Prob. 97AECh. 2 - Prob. 98AECh. 2 - Prob. 99AECh. 2 - Prob. 100AECh. 2 - Prob. 101AECh. 2 - Prob. 102AECh. 2 - Complete the following table. Atom/Ion Protons...Ch. 2 - Which of the following is{are) correct? a. 40Ca2...Ch. 2 - Prob. 105CWPCh. 2 - Prob. 106CWPCh. 2 - Prob. 107CWPCh. 2 - Prob. 108CWPCh. 2 - Reaction of 2.0 L of hydrogen gas with 1.0 L of...Ch. 2 - A combustion reaction involves the reaction of a...Ch. 2 - A chemistry instructor makes the following claim:...Ch. 2 - The early alchemists used to do an experiment in...Ch. 2 - Consider the chemical reaction as depicted below....Ch. 2 - Each of the following statements is true, but...Ch. 2 - You have two distinct gaseous compounds made from...Ch. 2 - A single molecule has a mass of 7.31 1023 g....Ch. 2 - You take three compounds, each consisting of two...Ch. 2 - Prob. 119IPCh. 2 - Prob. 120IPCh. 2 - Using the information in Table 2.1, answer the...
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