Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
6th Edition
ISBN: 9781305717367
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 2, Problem 2CLE
Write a brief description of the relationships among each of the following groups of terms or phrases. Answers to the Concept-Linking Exercises are given at the end of the chapter.
Homogeneous, heterogeneous, pure substance, mixture
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Draw the stepwise mechanism for the reactions
Part I.
a)
Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone
b) Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone
(3,3-dimethyl-2-butanone) and 2, 3-dimethyl - 1,3-butadiene. Give reasonable mechanism
the formation of
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3. The explosive decomposition of 2 mole of TNT (2,4,6-trinitrotoluene) is shown below:
Assume the C(s) is soot-basically atomic carbon (although it isn't actually atomic carbon in real life).
2
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NO2
3N2 (g)+7CO (g) + 5H₂O (g) + 7C (s)
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a. Use bond dissociation energies to calculate how much AU is for this reaction in kJ/mol.
Chapter 2 Solutions
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
Ch. 2 - Consider the photograph and illustrations of table...Ch. 2 - In the left box, draw a particulate-level...Ch. 2 - Classify the following changes as chemical C or...Ch. 2 - Specific gravity is a physical property. Beakers...Ch. 2 - Classify the following as homogenous or...Ch. 2 - Table salt from the beaker on the left in the...Ch. 2 - Which of the following are compounds, and which...Ch. 2 - Prob. 2.8TCCh. 2 - Identify the net electrical force-attraction,...Ch. 2 - aIs the process of boiling water exothermic or...
Ch. 2 - In everyday language, the term conserve usually...Ch. 2 - Write a brief description of the relationships...Ch. 2 - Write a brief description of the relationships...Ch. 2 - Prob. 3CLECh. 2 - Write a brief description of the relationships...Ch. 2 - Prob. 5CLECh. 2 - Prob. 6CLECh. 2 - Prob. 1ECh. 2 - Classify each of the following as macroscopic,...Ch. 2 - Suggest a reason for studying matter at the...Ch. 2 - How does a chemist think about particles that are...Ch. 2 - Using spheres to represent individual atoms,...Ch. 2 - Describe a piece of ice at the particulate level....Ch. 2 - 7.The word pour is commonly used in reference to...Ch. 2 - Prob. 8ECh. 2 - Which of the three states of matter is most easily...Ch. 2 - Compare the volumes occupied by the same sample of...Ch. 2 - Classify each of the following properties as...Ch. 2 - Classify the italicized property as chemical or...Ch. 2 - Which among the following are physical changes? a...Ch. 2 - Classify each of the following changes as chemical...Ch. 2 - Is the change illustrated below a physical change...Ch. 2 - Is the change in the illustration below a physical...Ch. 2 - Diamonds and graphite are two forms of carbon....Ch. 2 - Aspirin is a pure substance. If you had the choice...Ch. 2 - The substance in the glass below is from a kitchen...Ch. 2 - Are the contents of the bottle in the picture...Ch. 2 - Which of the following particulate illustrations...Ch. 2 - Which of the following particulate illustrations...Ch. 2 - Which of the following are pure substances and...Ch. 2 - Which of the substances below are pure and which...Ch. 2 - Apart from food, list five things in your home...Ch. 2 - Can the terms homogeneous and heterogeneous be...Ch. 2 - Which items in the following list are...Ch. 2 - Classify each of the following mixtures as either...Ch. 2 - Some ice cubes are homogeneous and some are...Ch. 2 - The freshly polished brass cylinder in the picture...Ch. 2 - Draw a particulate-level sketch of a heterogeneous...Ch. 2 - Draw a particulate-level sketch of a homogeneous...Ch. 2 - Suppose someone emptied ball bearings into a...Ch. 2 - Suggest at least two ways to separate ball...Ch. 2 - Prob. 35ECh. 2 - You receive a mixture of table salt and sand and...Ch. 2 - Classify the following as compounds or elements: a...Ch. 2 - Classify each of the following pure substances as...Ch. 2 - Which of the following are elements, and which are...Ch. 2 - Classify each of the following pure substances as...Ch. 2 - Classify each substance in the illustrations below...Ch. 2 - Does each of the particulate-level models below...Ch. 2 - a Which of the following substances would you...Ch. 2 - a Which of the following substances would you...Ch. 2 - Metal A dissolves in nitric acid solution. You can...Ch. 2 - A white, crystalline material that looks like...Ch. 2 - Questions 47 and 48: Samples of matter may be...Ch. 2 - Questions 47 and 48: Samples of matter may be...Ch. 2 - What is the main difference between electrostatic...Ch. 2 - Identify the net electrostatic force attraction,...Ch. 2 - Identify the reactants and products in the...Ch. 2 - In the following equation for a chemical reaction,...Ch. 2 - In the equation Ni+Cu(NO3)2Ni(NO3)2+Cu, which of...Ch. 2 - Write the formulas of the elements that are...Ch. 2 - Prob. 55ECh. 2 - Classify each of the following changes as...Ch. 2 - As a child plays on a swing, at what point in her...Ch. 2 - A bicycle accelerates from 5 miles per hour to 15...Ch. 2 - After solid limestone is heated, the rock that...Ch. 2 - Before electronic flashes were commonly used in...Ch. 2 - The photograph below shows a beaker of water and a...Ch. 2 - Prob. 62ECh. 2 - Prob. 63ECh. 2 - Prob. 64ECh. 2 - Distinguish precisely and in scientific terms the...Ch. 2 - Prob. 66ECh. 2 - A natural-food store advertises that no chemicals...Ch. 2 - Prob. 68ECh. 2 - Name some pure substances you have used today.Ch. 2 - How many homogeneous substances can you reach...Ch. 2 - Which of the following can be pure substances:...Ch. 2 - Can you have a mixture of two elements as well as...Ch. 2 - Can you have more than one compound made of the...Ch. 2 - Rainwater comes from the oceans. Is rainwater more...Ch. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Consider the sample of matter in the illustration...Ch. 2 - A particulate-level illustration of the reaction...Ch. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Particles in the illustration below undergo a...Ch. 2 - Prob. 84E
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- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: Pinacol (2,3-dimethyl, 1-3-butanediol) on treatment w/ acid gives a mixture of pina colone and (3,3-dimethyl-2-butanone) 2,3-dimethyl-1,3-butadiene. Give reasonable mechanism the formation of the products Forarrow_forwardShow the mechanism for these reactionsarrow_forwardDraw the stepwise mechanismarrow_forward
- Draw a structural formula of the principal product formed when benzonitrile is treated with each reagent. (a) H₂O (one equivalent), H₂SO₄, heat (b) H₂O (excess), H₂SO₄, heat (c) NaOH, H₂O, heat (d) LiAlH4, then H₂Oarrow_forwardDraw the stepwise mechanism for the reactionsarrow_forwardDraw stepwise mechanismarrow_forward
- Part I. Draw reaction mechanism for the transformations of benzophenone to benzopinacol to benzopinaco lone and answer the ff: a) Give the major reason for the exposure of benzophenone al isopropyl alcohol (w/acid) to direct sunlight of pina colone Mechanism For b) Pinacol (2,3-dimethy 1, 1-3-butanediol) on treatment w/ acid gives a mixture (3,3-dimethyl-2-butanone) and 2, 3-dimethyl-1,3-butadiene. Give reasonable the formation of the productsarrow_forwardwhat are the Iupac names for each structurearrow_forwardWhat are the IUPAC Names of all the compounds in the picture?arrow_forward
- 1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)arrow_forward19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+arrow_forwardLi+ is a hard acid. With this in mind, which if the following compounds should be most soluble in water? Group of answer choices LiBr LiI LiF LiClarrow_forward
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