Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
6th Edition
ISBN: 9781305717367
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 2, Problem 23E
Which of the following are pure substances and which are mixtures: (a) table salt; (b) tap water; (c) clean, dry air; (d) steam.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 2 Solutions
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
Ch. 2 - Consider the photograph and illustrations of table...Ch. 2 - In the left box, draw a particulate-level...Ch. 2 - Classify the following changes as chemical C or...Ch. 2 - Specific gravity is a physical property. Beakers...Ch. 2 - Classify the following as homogenous or...Ch. 2 - Table salt from the beaker on the left in the...Ch. 2 - Which of the following are compounds, and which...Ch. 2 - Prob. 2.8TCCh. 2 - Identify the net electrical force-attraction,...Ch. 2 - aIs the process of boiling water exothermic or...
Ch. 2 - In everyday language, the term conserve usually...Ch. 2 - Write a brief description of the relationships...Ch. 2 - Write a brief description of the relationships...Ch. 2 - Prob. 3CLECh. 2 - Write a brief description of the relationships...Ch. 2 - Prob. 5CLECh. 2 - Prob. 6CLECh. 2 - Prob. 1ECh. 2 - Classify each of the following as macroscopic,...Ch. 2 - Suggest a reason for studying matter at the...Ch. 2 - How does a chemist think about particles that are...Ch. 2 - Using spheres to represent individual atoms,...Ch. 2 - Describe a piece of ice at the particulate level....Ch. 2 - 7.The word pour is commonly used in reference to...Ch. 2 - Prob. 8ECh. 2 - Which of the three states of matter is most easily...Ch. 2 - Compare the volumes occupied by the same sample of...Ch. 2 - Classify each of the following properties as...Ch. 2 - Classify the italicized property as chemical or...Ch. 2 - Which among the following are physical changes? a...Ch. 2 - Classify each of the following changes as chemical...Ch. 2 - Is the change illustrated below a physical change...Ch. 2 - Is the change in the illustration below a physical...Ch. 2 - Diamonds and graphite are two forms of carbon....Ch. 2 - Aspirin is a pure substance. If you had the choice...Ch. 2 - The substance in the glass below is from a kitchen...Ch. 2 - Are the contents of the bottle in the picture...Ch. 2 - Which of the following particulate illustrations...Ch. 2 - Which of the following particulate illustrations...Ch. 2 - Which of the following are pure substances and...Ch. 2 - Which of the substances below are pure and which...Ch. 2 - Apart from food, list five things in your home...Ch. 2 - Can the terms homogeneous and heterogeneous be...Ch. 2 - Which items in the following list are...Ch. 2 - Classify each of the following mixtures as either...Ch. 2 - Some ice cubes are homogeneous and some are...Ch. 2 - The freshly polished brass cylinder in the picture...Ch. 2 - Draw a particulate-level sketch of a heterogeneous...Ch. 2 - Draw a particulate-level sketch of a homogeneous...Ch. 2 - Suppose someone emptied ball bearings into a...Ch. 2 - Suggest at least two ways to separate ball...Ch. 2 - Prob. 35ECh. 2 - You receive a mixture of table salt and sand and...Ch. 2 - Classify the following as compounds or elements: a...Ch. 2 - Classify each of the following pure substances as...Ch. 2 - Which of the following are elements, and which are...Ch. 2 - Classify each of the following pure substances as...Ch. 2 - Classify each substance in the illustrations below...Ch. 2 - Does each of the particulate-level models below...Ch. 2 - a Which of the following substances would you...Ch. 2 - a Which of the following substances would you...Ch. 2 - Metal A dissolves in nitric acid solution. You can...Ch. 2 - A white, crystalline material that looks like...Ch. 2 - Questions 47 and 48: Samples of matter may be...Ch. 2 - Questions 47 and 48: Samples of matter may be...Ch. 2 - What is the main difference between electrostatic...Ch. 2 - Identify the net electrostatic force attraction,...Ch. 2 - Identify the reactants and products in the...Ch. 2 - In the following equation for a chemical reaction,...Ch. 2 - In the equation Ni+Cu(NO3)2Ni(NO3)2+Cu, which of...Ch. 2 - Write the formulas of the elements that are...Ch. 2 - Prob. 55ECh. 2 - Classify each of the following changes as...Ch. 2 - As a child plays on a swing, at what point in her...Ch. 2 - A bicycle accelerates from 5 miles per hour to 15...Ch. 2 - After solid limestone is heated, the rock that...Ch. 2 - Before electronic flashes were commonly used in...Ch. 2 - The photograph below shows a beaker of water and a...Ch. 2 - Prob. 62ECh. 2 - Prob. 63ECh. 2 - Prob. 64ECh. 2 - Distinguish precisely and in scientific terms the...Ch. 2 - Prob. 66ECh. 2 - A natural-food store advertises that no chemicals...Ch. 2 - Prob. 68ECh. 2 - Name some pure substances you have used today.Ch. 2 - How many homogeneous substances can you reach...Ch. 2 - Which of the following can be pure substances:...Ch. 2 - Can you have a mixture of two elements as well as...Ch. 2 - Can you have more than one compound made of the...Ch. 2 - Rainwater comes from the oceans. Is rainwater more...Ch. 2 - Prob. 75ECh. 2 - Prob. 76ECh. 2 - Consider the sample of matter in the illustration...Ch. 2 - A particulate-level illustration of the reaction...Ch. 2 - Prob. 79ECh. 2 - Prob. 80ECh. 2 - Prob. 81ECh. 2 - Prob. 82ECh. 2 - Particles in the illustration below undergo a...Ch. 2 - Prob. 84E
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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