(a)
Interpretation:
The formulas for ammonium and ammonia are to be determined.
Concept introduction:
Covalent bonds are formed by the sharing of electrons between two or more atoms. In covalent bonding, there is a mutual attraction between two nuclei and the two electrons that reside between them. The elements that engage in covalent bond formation are present at the rightmost corner of the periodic table. These elements are non-metals. The interaction between two non-metal elements leads to the formation of a covalent bond.
(b)
Interpretation:
The formulas for magnesium sulfide, magnesium sulfite, and magnesium sulfate are to be determined.
Concept introduction:
The general rules for naming ionic compounds are as follows:
1) In ionic compounds, the cations are named before the anions.
2) In binary ionic compounds, the name of the cation is the same as the name of the metal. The name of the anion includes the root name of the non-metal and a suffix
3) In polyatomic ions in which a non-metal is bonded to one or more oxygen atoms. In two oxoanions in the family, the ion with fewer oxygen atoms has the non-metal root name and a suffix
(c)
Interpretation:
The formulas for hydrochloric acid, chloric acid, and chlorous acid are to be determined.
Concept introduction:
The general formula for naming binary acids is,
The general rules for naming the members of a family with four oxoanions are as follows:
1) The anion with the most number of oxygen atoms has the refix
2) The anion with one fewer oxygen atom has the non-metal root and the suffix
3) The anion with two fewer oxygen atoms has the non-metal root and the suffix
4) The anion with three fewer oxygen atoms has the prefix
(d)
Interpretation:
The formulas for cuprous bromide and cupric bromide are to be determined.
Concept introduction:
The general rules for naming ionic compounds with different charges on the same metal are:
1) The root name of the metal is followed by the suffix
2)The root name of the metal is followed by the suffix
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Chapter 2 Solutions
CHEMISTRY:MOLECULAR...V.2 W/ACCESS
- Nonearrow_forward4. Draw and label all possible isomers for [M(py)3(DMSO)2(CI)] (py = pyridine, DMSO dimethylsulfoxide).arrow_forwardThe emission data in cps displayed in Table 1 is reported to two decimal places by the chemist. However, the instrument output is shown in Table 2. Table 2. Iron emission from ICP-AES Sample Blank Standard Emission, cps 579.503252562 9308340.13122 Unknown Sample 343.232365741 Did the chemist make the correct choice in how they choose to display the data up in Table 1? Choose the best explanation from the choices below. No. Since the instrument calculates 12 digits for all values, they should all be kept and not truncated. Doing so would eliminate significant information. No. Since the instrument calculates 5 decimal places for the standard, all of the values should be limited to the same number. The other decimal places are not significant for the blank and unknown sample. Yes. The way Saman made the standards was limited by the 250-mL volumetric flask. This glassware can report values to 2 decimal places, and this establishes our number of significant figures. Yes. Instrumental data…arrow_forward
- 7. Draw a curved arrow mechanism for the following reaction. HO cat. HCI OH in dioxane with 4A molecular sievesarrow_forwardTry: Convert the given 3D perspective structure to Newman projection about C2 - C3 bond (C2 carbon in the front). Also, show Newman projection of other possible staggered conformers and circle the most stable conformation. Use the template shown. F H3C Br Harrow_forwardNonearrow_forward
- 16. Consider the probability distribution p(x) = ax", 0 ≤ x ≤ 1 for a positive integer n. A. Derive an expression for the constant a, to normalize p(x). B. Compute the average (x) as a function of n. C. Compute σ2 = (x²) - (x)², the variance of x, as a function of n.arrow_forward451. Use the diffusion model from lecture that showed the likelihood of mixing occurring in a lattice model with eight lattice sites: Case Left Right A B C Permeable Barrier → and show that with 2V lattice sites on each side of the permeable barrier and a total of 2V white particles and 2V black particles, that perfect de-mixing (all one color on each side of the barrier) becomes increasingly unlikely as V increases.arrow_forward46. Consider an ideal gas that occupies 2.50 dm³ at a pressure of 3.00 bar. If the gas is compressed isothermally at a constant external pressure so that the final volume is 0.500 dm³, calculate the smallest value Rest can have. Calculate the work involved using this value of Rext.arrow_forward
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