Chemistry (7th Edition)
7th Edition
ISBN: 9780321943170
Author: John E. McMurry, Robert C. Fay, Jill Kirsten Robinson
Publisher: PEARSON
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Chapter 2, Problem 2.74SP
In methane, one part hydrogen combine with three parts carbon by mass. If a sample of a compound containing only carbon and hydrogen contains 32.0 g of carbon and 8.0 g of hydrogen, could the sample be methane? If the sample is not methane, show that the law of multiple proportions is followed for methane and this other substance
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ
Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions
about this system:
rise
Under these conditions, will the pressure of NOCI tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO?
In other words, if you said the pressure of NOCI will tend to rise, can that
be changed to a tendency to fall by adding NO? Similarly, if you said the
pressure of NOCI will tend to fall, can that be changed to a tendency to
rise by adding NO?
yes
no
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO needed to reverse it.
Round your answer to 2 significant digits.
atm
☑
18
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HCN is a weak acid.
acids:
0.29 mol of NaOH is added
to 1.0 L of a 1.2M HCN
solution.
bases:
☑
other:
0.09 mol of HCl is added to
acids:
1.0 L of a solution that is
bases:
0.3M in both HCN and
KCN.
other:
0,0,...
?
00.
18
Ar
日
Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
acids:
0.2 mol of KOH is added to
1.0 L of a 0.5 M HF
solution.
bases:
Х
other: ☐
acids:
0.10 mol of HI is added to
1.0 L of a solution that is
1.4M in both HF and NaF.
bases:
other: ☐
0,0,...
ด
?
18
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Chapter 2 Solutions
Chemistry (7th Edition)
Ch. 2 - Conceptual PRACTICE 2.1 An element is a shiny,...Ch. 2 - Prob. 2.2ACh. 2 - PRACTICE 2.3Compounds A and B are colorless gases...Ch. 2 - APPLY 2.4If the chemical formula of compound A in...Ch. 2 - PRACTICE 2.5The gold foil that Rutherford used in...Ch. 2 - Prob. 2.6ACh. 2 - PRACTICE 2.7The isotope 3475Se is used medically...Ch. 2 - APPLY 2.8Element X is toxic to humans in high...Ch. 2 - PRACTICE 2.9Copper metal has two naturally occur-...Ch. 2 - Prob. 2.10A
Ch. 2 - Prob. 2.11PCh. 2 - APPLY 2.12If 2.26 1022 atoms Of element Y have a...Ch. 2 - Prob. 2.13PCh. 2 - Prob. 2.14ACh. 2 - Prob. 2.15PCh. 2 - Prob. 2.16ACh. 2 - Prob. 2.17PCh. 2 - Prob. 2.18ACh. 2 - Prob. 2.19PCh. 2 - Prob. 2.20ACh. 2 - Prob. 2.21PCh. 2 - Prob. 2.22ACh. 2 - Prob. 2.23PCh. 2 - Prob. 2.24ACh. 2 - Prob. 2.25PCh. 2 - Prob. 2.26PCh. 2 - Prob. 2.27PCh. 2 - Prob. 2.28PCh. 2 - Prob. 2.29PCh. 2 - Prob. 2.30PCh. 2 - Prob. 2.31CPCh. 2 - Prob. 2.32CPCh. 2 - Prob. 2.33CPCh. 2 - Prob. 2.34CPCh. 2 - Prob. 2.35CPCh. 2 - Prob. 2.36CPCh. 2 - Prob. 2.37CPCh. 2 - Prob. 2.38CPCh. 2 - Prob. 2.39CPCh. 2 - Prob. 2.40CPCh. 2 - Prob. 2.41CPCh. 2 - Prob. 2.42CPCh. 2 - Prob. 2.43CPCh. 2 - Prob. 2.44SPCh. 2 - Prob. 2.45SPCh. 2 - Prob. 2.46SPCh. 2 - Prob. 2.47SPCh. 2 - Prob. 2.48SPCh. 2 - Prob. 2.49SPCh. 2 - Prob. 2.50SPCh. 2 - Prob. 2.51SPCh. 2 - Prob. 2.52SPCh. 2 - Prob. 2.53SPCh. 2 - Prob. 2.54SPCh. 2 - Prob. 2.55SPCh. 2 - Where in the periodic table are the metallic...Ch. 2 - Prob. 2.57SPCh. 2 - Prob. 2.58SPCh. 2 - Prob. 2.59SPCh. 2 - 2.60 List several general properties of the...Ch. 2 - Prob. 2.61SPCh. 2 - Prob. 2.62SPCh. 2 - Prob. 2.63SPCh. 2 - At room temperature, a certain element is found to...Ch. 2 - Prob. 2.65SPCh. 2 - At room temperature, a certain element is yellow...Ch. 2 - Prob. 2.67SPCh. 2 - Prob. 2.68SPCh. 2 - Prob. 2.69SPCh. 2 - How does Dalton’s atomic theory account for the...Ch. 2 - Prob. 2.71SPCh. 2 - A sample of mercury with a mass of 114.0 g was...Ch. 2 - Prob. 2.73SPCh. 2 - In methane, one part hydrogen combine with three...Ch. 2 - In borane, one part hydrogen combine with 3.6...Ch. 2 - Benzene, ethane, and ethylene are just three of a...Ch. 2 - Prob. 2.77SPCh. 2 - Prob. 2.78SPCh. 2 - 2.79 In addition to carbon monoxide (CO) and...Ch. 2 - Prob. 2.80SPCh. 2 - Prob. 2.81SPCh. 2 - Prob. 2.82SPCh. 2 - What affects the magnitude of the deflection of...Ch. 2 - Prob. 2.84SPCh. 2 - Prob. 2.85SPCh. 2 - Which of the following charges is NOT possible for...Ch. 2 - What discovery about atomic structure was made...Ch. 2 - Prior to Rutherford’s gold foil experiment, the...Ch. 2 - A period at the end of sentence written with a...Ch. 2 - A 1/4 inch thick lead sheet is used for protection...Ch. 2 - Prob. 2.91SPCh. 2 - What is the difference between an atom’s atomic...Ch. 2 - Prob. 2.93SPCh. 2 - Prob. 2.94SPCh. 2 - Prob. 2.95SPCh. 2 - Prob. 2.96SPCh. 2 - The radioactive isotope cesium-137 was produced in...Ch. 2 - Prob. 2.98SPCh. 2 - Prob. 2.99SPCh. 2 - How many protons, neutrons, and electrons are in...Ch. 2 - Prob. 2.101SPCh. 2 - Prob. 2.102SPCh. 2 - Prob. 2.103SPCh. 2 - Prob. 2.104SPCh. 2 - Prob. 2.105SPCh. 2 - Prob. 2.106SPCh. 2 - Prob. 2.107SPCh. 2 - Prob. 2.108SPCh. 2 - Naturally occurring silver consists of two...Ch. 2 - Prob. 2.110SPCh. 2 - Prob. 2.111SPCh. 2 - Prob. 2.112SPCh. 2 - Prob. 2.113SPCh. 2 - Prob. 2.114SPCh. 2 - Prob. 2.115SPCh. 2 - Prob. 2.116SPCh. 2 - Prob. 2.117SPCh. 2 - Prob. 2.118SPCh. 2 - Prob. 2.119SPCh. 2 - Prob. 2.120SPCh. 2 - Which of the following bonds are likely to be...Ch. 2 - The symbol CO stands for carbon monoxide, but the...Ch. 2 - Prob. 2.123SPCh. 2 - Prob. 2.124SPCh. 2 - Prob. 2.125SPCh. 2 - Prob. 2.126SPCh. 2 - Prob. 2.127SPCh. 2 - Prob. 2.128SPCh. 2 - Prob. 2.129SPCh. 2 - Prob. 2.130SPCh. 2 - Prob. 2.131SPCh. 2 - Give systematic names for the following binary...Ch. 2 - Give systematic names for the following binary...Ch. 2 - Prob. 2.134SPCh. 2 - Prob. 2.135SPCh. 2 - Prob. 2.136SPCh. 2 - Prob. 2.137SPCh. 2 - Give systematic names for the following compounds:...Ch. 2 - Name the following ions: (a) Ba2+ (b) Cs+ (c) V3+...Ch. 2 - Prob. 2.140SPCh. 2 - Prob. 2.141SPCh. 2 - Prob. 2.142SPCh. 2 - Prob. 2.143SPCh. 2 - Prob. 2.144SPCh. 2 - Prob. 2.145SPCh. 2 - Prob. 2.146SPCh. 2 - Prob. 2.147SPCh. 2 - Prob. 2.148SPCh. 2 - Prob. 2.149SPCh. 2 - Prob. 2.150SPCh. 2 - Prob. 2.151SPCh. 2 - Germanium has five naturally occurring isotopes:...Ch. 2 - Prob. 2.153CPCh. 2 - Ammonia (NH3) and hydrazine (N2H4) are both...Ch. 2 - Prob. 2.155CPCh. 2 - Prob. 2.156CPCh. 2 - Prob. 2.157CPCh. 2 - Prob. 2.158CPCh. 2 - What was the mass in atomic mass units of a 40Ca...Ch. 2 - Prob. 2.160CPCh. 2 - Prob. 2.161CPCh. 2 - Prob. 2.162CPCh. 2 - Prob. 2.163CP
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