Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Question
Chapter 2, Problem 25EQ
Interpretation Introduction
Interpretation:
The resonance structure of the given molecule is to be determined
Concept Introduction:
When the electron distribution of a molecule can be depicted correctly in more than one way using different Lewis structures, the drawings are called resonance structures.
Resonance structures have no discrete existence of their own but, taken in combination, describe the true structure of the molecule.
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the
compound. Find the structure. Show complete solutions.
Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
Predicted 13C NMR Spectrum
100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
-10
Q: Arrange BCC and Fec
metals, in sequence from the
Fable (Dr. R's slides) and
Calculate Volume and Density.
Aa
BCC
V
52 5
SFCC
None
Chapter 2 Solutions
Pushing Electrons
Ch. 2 - One Lewis structure for the 2-butenyl cation is...Ch. 2 - Prob. 2EQCh. 2 - One structure for the conjugate acid of acetone...Ch. 2 - Similarly, a resonance structure for the conjugate...Ch. 2 - Prob. 5EQCh. 2 - Pairs of unshared electrons can be pushed. One...Ch. 2 - One structure for the acetoxonium ion is Clearly,...Ch. 2 - Prob. 8EQCh. 2 - There are no important resonance structures for...Ch. 2 - Prob. 10EQ
Ch. 2 - Prob. 11EQCh. 2 - Prob. 12EQCh. 2 - Prob. 13EQCh. 2 - Prob. 14EQCh. 2 - Prob. 15EQCh. 2 - Prob. 16EQCh. 2 - Prob. 17EQCh. 2 - The cyclohexane carboxylate anion has a Lewis...Ch. 2 - One Lewis structure for the enolate anion of...Ch. 2 - Prob. 20EQCh. 2 - Prob. 21EQCh. 2 - Prob. 22EQCh. 2 - Prob. 23EQCh. 2 - Prob. 24EQCh. 2 - Prob. 25EQCh. 2 - Prob. 26EQCh. 2 - Prob. 27EQCh. 2 - Prob. 28EQ
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