Pushing Electrons
4th Edition
ISBN: 9781133951889
Author: Weeks, Daniel P.
Publisher: Cengage Learning
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Chapter 2, Problem 13EQ
Interpretation Introduction
Interpretation:
The resonance structure of the given molecule is to be determined
Concept Introduction:
When the electron distribution of a molecule can be depicted correctly in more than one way using different Lewis structures, the drawings are called resonance structures.
Resonance structures have no discrete existence of their own but, taken in combination, describe the true structure of the molecule.
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1600
1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
The potential energy of the reactants is 600 kJ
Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
d. What is the overall amount of activation energy for the above chemical reaction?
e. Which reaction intermediate would be considered a catalyst (if any) and why?
f. If you were to add 2700kJ of energy to the reaction (e.g. 2700 kl of heat or electricity), would
you be able to make the reaction reverse itself (i.e. have…
draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 2 Solutions
Pushing Electrons
Ch. 2 - One Lewis structure for the 2-butenyl cation is...Ch. 2 - Prob. 2EQCh. 2 - One structure for the conjugate acid of acetone...Ch. 2 - Similarly, a resonance structure for the conjugate...Ch. 2 - Prob. 5EQCh. 2 - Pairs of unshared electrons can be pushed. One...Ch. 2 - One structure for the acetoxonium ion is Clearly,...Ch. 2 - Prob. 8EQCh. 2 - There are no important resonance structures for...Ch. 2 - Prob. 10EQ
Ch. 2 - Prob. 11EQCh. 2 - Prob. 12EQCh. 2 - Prob. 13EQCh. 2 - Prob. 14EQCh. 2 - Prob. 15EQCh. 2 - Prob. 16EQCh. 2 - Prob. 17EQCh. 2 - The cyclohexane carboxylate anion has a Lewis...Ch. 2 - One Lewis structure for the enolate anion of...Ch. 2 - Prob. 20EQCh. 2 - Prob. 21EQCh. 2 - Prob. 22EQCh. 2 - Prob. 23EQCh. 2 - Prob. 24EQCh. 2 - Prob. 25EQCh. 2 - Prob. 26EQCh. 2 - Prob. 27EQCh. 2 - Prob. 28EQ
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