EBK PHYSICAL CHEMISTRY
EBK PHYSICAL CHEMISTRY
3rd Edition
ISBN: 9780100664814
Author: Reid
Publisher: YUZU
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Chapter 2, Problem 2.31NP
Interpretation Introduction

Interpretation: The increase in temperature needs to be determined after 2.5 hours if an adult is in a thermally insulating barrier and the heat evolved by metabolism is absorbed by the body. The heat capacity of body is 4.18 J/g K and heat produced by the metabolism is 9.4 kJ/ kg hr .

Concept Introduction: The change in temperature can be takes place using the following relation:

  ΔT=qCP

Here, q is amount of heat involved in the process and CP is heat capacity at constant pressure.

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30. We will derive the forms of the molecular partition functions for atoms and molecules shortly in class, but the partition function that describes the translational and rotational motion of a homonuclear diatomic molecule is given by Itrans (V,T) = = 2πmkBT h² V grot (T) 4π²IKBT h² Where h is Planck's constant and I is molecular moment of inertia. The overall partition function is qmolec Qtrans qrot. Find the energy, enthalpy, entropy, and Helmholtz free energy for the translational and rotational modes of 1 mole of oxygen molecules and 1 mole of iodine molecules at 50 K and at 300 K and with a volume of 1 m³. Here is some useful data: Moment of inertia: I2 I 7.46 x 10- 45 kg m² 2 O2 I 1.91 x 101 -46 kg m²
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Draw the principal organic product of the following reaction.
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