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(a)
Interpretation:
The isomeric structures of octane having five carbons in their principal chains are to be drawn. The naming for all the structures is to be stated.
Concept introduction:
The naming of the chemical compound is done using the parameters given by IUPAC. IUPAC stands for International Union of Pure and Applied Chemistry. This system of nomenclature is accepted worldwide. The IUPAC system provides the set of rules in order to do the naming of the chemical compounds.
Isomers are the chemical compounds which have same chemical formula but different arrangement of molecules.
Answer to Problem 2.26AP
The isomeric structures of octane having five carbons in their principal chains along with their names are drawn below as,
Explanation of Solution
The structure of octane can be drawn as shown in figure 1.
Figure 1
The isomers of the octane having five carbons in their principal chains can be drawn by rearranging the carbon atoms.
The first isomer is shown in figure 2 as,
Figure 2
For the naming of the compound, the longest carbon chain is selected first. In the given compound the longest carbon chain has
The second isomer is shown in figure 3 as,
Figure 3
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The third isomer is shown in figure 4 as,
Figure 4
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The fourth isomer is shown in figure 5 as,
Figure 5
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The fifth isomer is shown in figure 6 as,
Figure 6
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The sixth isomer is shown in figure 7 as,
Figure 7
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The isomeric structures of octane having five carbons in their principal chains along with their names are shown in figure 2 to 7.
(b)
Interpretation:
The isomeric structures of octane having six carbons in their principal chains are to be drawn. The naming for all the structures is to be stated.
Concept introduction:
The naming of the chemical compound is done using the parameters given by IUPAC. IUPAC stands for International Union of Pure and Applied Chemistry. This system of nomenclature is accepted worldwide. The IUPAC system provides the set of rules in order to do the naming of the chemical compounds.
Isomers are the chemical compounds which have same chemical formula but different arrangement of molecules.
Answer to Problem 2.26AP
The isomeric structures of octane having six carbons in their principal chains along with their names are drawn below as,
Explanation of Solution
The isomers of the octane having six carbons in their principal chains can be drawn by rearranging the carbon atoms.
The first isomer is shown in figure 8 as,
Figure 8
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The second isomer is shown in figure 9 as,
Figure 9
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The third isomer is shown in figure 10 as,
Figure 10
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The fourth isomer is shown in figure 11 as,
Figure 11
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The fifth isomer is shown in figure 12 as,
Figure 12
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest carbon chain has
The sixth isomer is shown in figure 13 as,
Figure 13
For the naming of the compound the longest carbon chain is selected first. In the given compound the longest chain carbon has
The isomeric structures of octane having six carbons in their principal chains along with their names are shown in figure 8 to 13.
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Chapter 2 Solutions
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Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning