General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Textbook Question
Chapter 2, Problem 2.25CP
Where on the periodic table do elements that meet the following descriptions appear?
- (a) Elements with electrons whose largest principal quantum number is n = 4
- (b) Elements with the valence-shell ground-state electron configuration ns2 np3
- (c) Elements that have only one unpaired p electron
- (d) The d-block elements
- (e) The p-block elements
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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an
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Predicted 1H NMR Spectrum
4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1
f1 (ppm)
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100
f1 (ppm)
30
220 210 200 190 180
170
160 150 140 130 120
110
90
80
70
-26
60
50
40
46
30
20
115
10
1.0 0.9 0.8
0
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Chapter 2 Solutions
General Chemistry: Atoms First
Ch. 2.1 - What is the frequency of a gamma ray with = 3.56 ...Ch. 2.1 - What is the wavelength in meters of an FM radio...Ch. 2.1 - Two electromagnetic waves are represented below....Ch. 2.2 - The Balmer equation can be extended beyond the...Ch. 2.2 - What is the longest-wavelength line in nanometers...Ch. 2.2 - What is the shortest-wavelength line in nanometers...Ch. 2.3 - What is the energy in kilojoules per mole of...Ch. 2.3 - The biological effects of a given dose of radiant...Ch. 2.3 - The work function of zinc metal is 350 kJ/mol....Ch. 2.3 - What is the work function of nickel metal if light...
Ch. 2.4 - What is the de Broglie wavelength in meters of a...Ch. 2.6 - Extend Table 2.2 to show allowed combinations of...Ch. 2.6 - Give orbital notations for electrons in orbitals...Ch. 2.6 - Give the allowed combinations of three quantum...Ch. 2.7 - Prob. 2.15PCh. 2.7 - Give a possible combination of n and l quantum...Ch. 2.9 - Calculate in kilojoules per mole the energy...Ch. 2.12 - Look at the electron configurations in Figure...Ch. 2.13 - Give expected ground-state electron configurations...Ch. 2.13 - Take a guess. What do you think is a likely...Ch. 2.13 - Identify the atom with the following ground-state...Ch. 2.14 - Which atom in each of the following pairs would...Ch. 2.14 - Prob. 2.23PCh. 2 - Where on the blank outline of the periodic table...Ch. 2 - Where on the periodic table do elements that meet...Ch. 2 - One of the elements shown on the following...Ch. 2 - Two electromagnetic waves are represented below....Ch. 2 - Prob. 2.28CPCh. 2 - The following orbital-filling diagram represents...Ch. 2 - Prob. 2.30CPCh. 2 - Identify each of the following orbitals, and give...Ch. 2 - Which has the higher frequency, red light or...Ch. 2 - Prob. 2.33SPCh. 2 - The Hubble Space Telescope detects radiant energy...Ch. 2 - Prob. 2.35SPCh. 2 - What is the wavelength in meters of ultraviolet...Ch. 2 - Prob. 2.37SPCh. 2 - Calculate the energies of the following waves in...Ch. 2 - The MRI (magnetic resonance imaging) body scanners...Ch. 2 - A certain cellular telephone transmits at a...Ch. 2 - Prob. 2.41SPCh. 2 - What is the wavelength in meters of photons with...Ch. 2 - What is the energy of each of the following...Ch. 2 - The data encoded on CDs, DVDs, and Blu-ray discs...Ch. 2 - The semimetal germanium is used as a component in...Ch. 2 - Prob. 2.46SPCh. 2 - According to the values cited in Problem 2.46, the...Ch. 2 - The work function of silver metal is 436 kJ/mol....Ch. 2 - What is the work function of gold metal in kJ/mol...Ch. 2 - Protons and electrons can be given very high...Ch. 2 - If a proton (mass = 1.673 1024 g) is accelerated...Ch. 2 - What is the de Broglie wavelength in meters of a...Ch. 2 - What is the de Broglie wavelength in meters of a...Ch. 2 - At what speed in meters per second must a 145 g...Ch. 2 - What velocity would an electron (mass = 9.11 1031...Ch. 2 - Use the Heisenberg uncertainty principle to...Ch. 2 - The mass of a helium-4 atom is 4.0026 u, and its...Ch. 2 - What are the four quantum numbers, and what does...Ch. 2 - What is the Heisenberg uncertainty principle, and...Ch. 2 - Why do we have to use an arbitrary value such as...Ch. 2 - How many nodal surfaces does a 4s orbital have?...Ch. 2 - Prob. 2.62SPCh. 2 - How does electron shielding in multielectron atoms...Ch. 2 - Give the allowable combinations of quantum numbers...Ch. 2 - Give the orbital designations of electrons with...Ch. 2 - Tell which of the following combinations of...Ch. 2 - Which of the following combinations of quantum...Ch. 2 - What is the maximum number of electrons in an atom...Ch. 2 - What is the maximum number of electrons in an atom...Ch. 2 - The wavelength of light at which the Balmer series...Ch. 2 - One series of lines of the hydrogen spectrum is...Ch. 2 - Prob. 2.72SPCh. 2 - Excited rubidium atoms emit red light with = 795...Ch. 2 - Why does the number of elements in successive...Ch. 2 - Prob. 2.75SPCh. 2 - Prob. 2.76SPCh. 2 - Prob. 2.77SPCh. 2 - According to the aufbau principle, which orbital...Ch. 2 - Prob. 2.79SPCh. 2 - Prob. 2.80SPCh. 2 - Give the expected ground-state electron...Ch. 2 - Prob. 2.82SPCh. 2 - Draw orbital-filling diagrams for atoms with the...Ch. 2 - Prob. 2.84SPCh. 2 - Prob. 2.85SPCh. 2 - Prob. 2.86SPCh. 2 - Prob. 2.87SPCh. 2 - Prob. 2.88SPCh. 2 - Prob. 2.89SPCh. 2 - Prob. 2.90SPCh. 2 - Prob. 2.91SPCh. 2 - Prob. 2.92SPCh. 2 - Which atom in each of the following pairs has a...Ch. 2 - Prob. 2.94SPCh. 2 - Prob. 2.95SPCh. 2 - What is the expected ground-state electron...Ch. 2 - Prob. 2.97SPCh. 2 - Orbital energies in single-electron atoms or ions,...Ch. 2 - Prob. 2.99CHPCh. 2 - Prob. 2.100CHPCh. 2 - Prob. 2.101CHPCh. 2 - Prob. 2.102CHPCh. 2 - What is the wavelength in meters of photons with...Ch. 2 - Prob. 2.104CHPCh. 2 - The second in the SI system is defined as the...Ch. 2 - Prob. 2.106CHPCh. 2 - Prob. 2.107CHPCh. 2 - Cesium metal is often used in photoelectric...Ch. 2 - Prob. 2.109CHPCh. 2 - Prob. 2.110CHPCh. 2 - Prob. 2.111CHPCh. 2 - Youre probably familiar with using Scotch Tape for...Ch. 2 - Hard wintergreen-flavored candies are...Ch. 2 - Prob. 2.114CHPCh. 2 - Prob. 2.115CHPCh. 2 - Prob. 2.116CHPCh. 2 - Prob. 2.117CHPCh. 2 - Prob. 2.118CHPCh. 2 - X rays with a wavelength of 1.54 1010 m are...Ch. 2 - Prob. 2.120CHPCh. 2 - Assume that the rules for quantum numbers are...Ch. 2 - Given the subshells 1s, 2s, 2p, 3s, 3p, and 3d,...Ch. 2 - Prob. 2.123CHPCh. 2 - A minimum energy of 7.21 1019 J is required to...Ch. 2 - A photon produced by an X-ray machine has an...Ch. 2 - An energetically excited hydrogen atom has its...Ch. 2 - Prob. 2.127MP
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