Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined Concept introduction: Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

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Answer 1

Question

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

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Give the structure(s) of the product(s) the reaction below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise I'm struggling to see how this reaction will go! I am wondering if it will cycle on itself but I'm not sure how I drew out a decagon but I'm a bit lost

Give the structure(s) of the product(s) for the reactions below, and be sure to indicate any relative stereochemistry (you can assume that each of the Diels-Alder reactions will proceed with endo selectivity). Draw out relevant enantiomer(s) if they are expected to form. If no reaction is expected to occur under the indicated conditions, then write "no reaction" or NR, and explain why you would expect nothing to occur. If more than one product is formed, please indicate which one will be the major product or if they will be formed in equal amounts. In all cases, equimolar amounts of both components/reagents are present unless indicated otherwise .

Answer 2

Question

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

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Answer 3

Question

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

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Answer 4

Question

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

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Answer 5

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

Answer 6

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

Answer 7

Chapter 2, Problem 1Q

Interpretation Introduction

Interpretation:

Among low flammability, low toxicity, high boiling point and water solubility the one that attributes of more benign solvent should be determined

Concept introduction:

Solvents play an essential role in chemical processes not only to put reactants in contact with dissolution but also sometimes cause hazardous explosions. The chemical reactions or processes can be improved done by the replacement of the hazardous solvent with a benign solvent.Benign solvents are safer solvents and less hazardous for the environment.

Answer 8

Expert Solution & Answer

Answer to Problem 1Q

Low toxicity and low flammability are the attributes of the benign solvent.

Answer 9

Expert Solution & Answer

Answer 10

Expert Solution & Answer

Answer 11

Explanation of Solution

The characteristics of the benign solvent are as follows:

A solvent that has a low flash point should not be used for chemical reactions because the solvents with a low flash point or high-flammability are prone to ignition at normal conditions. Therefore, the flammability of the solvent should be high.

The high toxicity of the solvent can cause many health problems and may lead to unconsciousness. Therefore, the solvent should be of low toxicity.

The high boiling point cannot be considered as the characteristic property because some best benign solvent has a moderate boiling point.

Water solubility cannot be considered as the characteristic property of the benign solvent as it varies.

Answer 12

Ch. 2 - Prob. 1Q Ch. 2 - Prob. 2Q Ch. 2 - Prob. 3Q Ch. 2 - Prob. 4Q Ch. 2 - Prob. 5Q Ch. 2 - Prob. 6Q

Answer to Problem 1Q

Explanation of Solution

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Chapter 2 Solutions