Fundamentals of Physics, Volume 1, Chapter 1-20
10th Edition
ISBN: 9781118233764
Author: David Halliday
Publisher: WILEY
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Chapter 19, Problem 97P
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The ratio
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4. This problem explores "effusion", the process by which gas in a container leaks out of a small hole.
(a) Consider a wall of a container full of an ideal gas. Find an expression for vrms (the root-mean-squared
speed of the gas molecules in the direction perpendicular to the wall) in terms of the gas temperature
(T) and the molecular mass of the gas (m).
(b) Consider a small portion (with area A) of the wall. Each molecule colliding with this portion of the
wall exerts the following pressure on it:
- m Δυ,
ΑΔt
where v, is the molecule's speed in the direction perpendicular to the wall. We assume an elastic
collision, so over the course of the collision we have Avx = -2vx.
An interesting quantity is N, the number of molecules colliding with this portion of the wall in (very
short) time interval At. We can estimate that the gas pressure P, which is the total pressure exerted by
N molecular collisions with the wall, is N times the average pressure exerted by a single molecule:
2Nm
P = N…
The average kinetic energy of the molecules in a gas sample depends only on the temperature, ?. However, given the same kinetic energies, a lighter molecule will move faster than a heavier molecule, as shown in the equation for rms speed.
where ?=8.314 J/(mol⋅K) and ℳ is molar mass in kilograms per mole. Note that a joule is the same as a kilogram‑meter squared per second squared (kg·m2/s2).
What is the rms speed of Cl2 molecules at 401 K?
What is the rms speed of He atoms at 401401 K?
A container with volume 1.64 L is initially evacuated. Then it is filled with 0.226 g of N2. Assume that the pressure of the gas is low enough for the gas to obey the ideal-gas law to a high degree of accuracy. If the root-mean-square speed of the gas molecules is 182 m/s, what is the pressure of the gas?
Chapter 19 Solutions
Fundamentals of Physics, Volume 1, Chapter 1-20
Ch. 19 - For four situations for an ideal gas, the table...Ch. 19 - In the p-V diagram of Fig. 19-17, the gas does 5 J...Ch. 19 - For a temperature increase of T1, a certain amount...Ch. 19 - The dot in Fig, 19-18a represents the initial...Ch. 19 - A certain amount of energy is to be transferred as...Ch. 19 - The dot in Fig. 19-18b represents the initial...Ch. 19 - a Rank the four paths of Fig. 19-16 according to...Ch. 19 - The dot in Fig. 19-18c represents the initial...Ch. 19 - Prob. 9QCh. 19 - Does the temperature of an ideal gas increase,...
Ch. 19 - Prob. 1PCh. 19 - Gold has a molar mass of 197 g/mol. a How many...Ch. 19 - SSM Oxygen gas having a volume of 1000 cm3 at...Ch. 19 - A quantity of ideal gas at: 10.0C and 100 kPa...Ch. 19 - The best laboratory vacuum has a pressure of about...Ch. 19 - Water bottle in a hot car. In the American...Ch. 19 - Suppose 1.80 mol of an ideal gas is taken from a...Ch. 19 - Compute a the number of moles and b the number of...Ch. 19 - An automobile tire has a volume of 1.64 102 m3...Ch. 19 - A container encloses 2 mol of an ideal gas that...Ch. 19 - SSM ILW WWW Air that initially occupies 0.140 m3...Ch. 19 - GO Submarine rescue. When the U.S. submarine...Ch. 19 - Prob. 13PCh. 19 - In the temperature range 310 K to 330 K, the...Ch. 19 - Suppose 0.825 mol of an ideal gas undergoes an...Ch. 19 - An air bubble of volume 20 cm3 is at the bottom of...Ch. 19 - GO Container A in Fig. 19-22 holds an ideal gas at...Ch. 19 - The temperature and pressure in the Suns...Ch. 19 - a Compute the rms speed of a nitrogen molecule at...Ch. 19 - Calculate the rms speed of helium atoms at 1000 K....Ch. 19 - SSM The lowest possible temperature in outer space...Ch. 19 - Find the rms speed of argon atoms at 313 K. See...Ch. 19 - A beam of hydrogen molecules H2 is directed toward...Ch. 19 - At 273 K and 1.00 102 atm, the density of a gas...Ch. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Water standing in the open at 32.0C evaporates...Ch. 19 - At what frequency would the wavelength of sound in...Ch. 19 - SSM The atmospheric density at an altitude of 2500...Ch. 19 - Prob. 30PCh. 19 - In a certain particle accelerator, protons travel...Ch. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Prob. 35PCh. 19 - The most probable speed of the molecules in a gas...Ch. 19 - Prob. 37PCh. 19 - Figure 19-24 gives the probability distribution...Ch. 19 - At what temperature does the rms speed of a...Ch. 19 - Two containers are at the same temperature. The...Ch. 19 - Prob. 41PCh. 19 - What is the internal energy of 1.0 mol of an ideal...Ch. 19 - Prob. 43PCh. 19 - GO One mole of ail ideal diatomic gas goes from a...Ch. 19 - ILW The mass of a gas molecule can be computed...Ch. 19 - Under constant pressure, the temperature of 2.00...Ch. 19 - The temperature of 2.00 mol of an ideal monatomic...Ch. 19 - GO When 20.9 J was added as heat to a particular...Ch. 19 - SSM A container holds a mixture of three...Ch. 19 - We give 70 J as heat to a diatomic gas, which then...Ch. 19 - Prob. 51PCh. 19 - GO Suppose 12.0 g of oxygen O2 gas is heated at...Ch. 19 - SSM WWW Suppose 4.00 mol of an ideal diatomic gas...Ch. 19 - We know that for an adiabatic process pV = a...Ch. 19 - A certain gas occupies a volume of 4.3 L at a...Ch. 19 - Suppose 1.00 L of a gas with = 1.30, initially at...Ch. 19 - The volume of an ideal gas is adiabatically...Ch. 19 - GO Opening champagne. In a bottle of champagne,...Ch. 19 - GO Figure 19-26 shows two paths that may be taken...Ch. 19 - GO Adiabatic wind. The normal airflow over the...Ch. 19 - GO A gas is to be expanded from initial state i to...Ch. 19 - GO An ideal diatomic gas, with rotation but no...Ch. 19 - Figure 19-27 shows a cycle undergone by 1.00 mol...Ch. 19 - Calculate the work done by an external agent...Ch. 19 - An ideal gas undergoes an adiabatic compression...Ch. 19 - Prob. 66PCh. 19 - An ideal monatomic gas initially has a temperature...Ch. 19 - Prob. 68PCh. 19 - SSM The envelope and basket of a hot-air balloon...Ch. 19 - An ideal gas, at initial temperature T1 and...Ch. 19 - Prob. 71PCh. 19 - At what temperature do atoms of helium gas have...Ch. 19 - Prob. 73PCh. 19 - Prob. 74PCh. 19 - The temperature of 3.00 mol of a gas with CV =...Ch. 19 - During a compression at a constant pressure of 250...Ch. 19 - SSM Figure 19-28 shows a hypothetical speed...Ch. 19 - Prob. 78PCh. 19 - SSM An ideal gas undergoes isothermal compression...Ch. 19 - Oxygen O2 gas at 273 K and 1.0 atm is confined to...Ch. 19 - An ideal pas is taken through a complete cycle in...Ch. 19 - Prob. 82PCh. 19 - SSM A sample of ideal gas expands from an initial...Ch. 19 - An ideal gas with 3.00 mol is initially in state 1...Ch. 19 - A steel lank contains 300 g of ammonia gas NH3 at...Ch. 19 - In an industrial process the volume of 25.0 mol of...Ch. 19 - Figure 19-29 shows a cycle consisting of five...Ch. 19 - An ideal gas initially at 300 K is compressed at a...Ch. 19 - A pipe of length L = 25.0 m that is open at one...Ch. 19 - In a motorcycle engine, a piston is forced down...Ch. 19 - For adiabatic processes in an ideal gas, show that...Ch. 19 - Air at 0.000C and 1.00 atm pressure has a density...Ch. 19 - Prob. 93PCh. 19 - Prob. 94PCh. 19 - Prob. 95PCh. 19 - For air near 0C, by how much does the speed of...Ch. 19 - Prob. 97P
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