Chemistry: The Molecular Science
5th Edition
ISBN: 9781285199047
Author: John W. Moore, Conrad L. Stanitski
Publisher: Cengage Learning
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Question
Chapter 19, Problem 86QRT
Interpretation Introduction
Interpretation:
Molecular formula of sulfur in vapor has to be determined.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 19 Solutions
Chemistry: The Molecular Science
Ch. 19.1 - Prob. 19.1ECh. 19.1 - Prob. 19.2ECh. 19.2 - Prob. 19.3CECh. 19.2 - Prob. 19.4CECh. 19.3 - Prob. 19.5ECh. 19.4 - Prob. 19.1PSPCh. 19.4 - Prob. 19.6ECh. 19.4 - Prob. 19.7ECh. 19.4 - Prob. 19.2PSPCh. 19.5 - Prob. 19.8CE
Ch. 19.5 - Prob. 19.9ECh. 19.5 - Prob. 19.3PSPCh. 19.5 - Use the terms oxidation, reduction, oxidizing...Ch. 19.5 - Prob. 19.11ECh. 19.6 - Prob. 19.13ECh. 19.6 - Prob. 19.14ECh. 19.6 - Prob. 19.15CECh. 19.6 - Prob. 19.16CECh. 19.6 - Prob. 19.4PSPCh. 19.6 - Prob. 19.5PSPCh. 19.6 - Prob. 19.17ECh. 19.6 - Prob. 19.6PSPCh. 19.6 - Prob. 19.7PSPCh. 19.6 - Prob. 19.8PSPCh. 19 - Prob. 1QRTCh. 19 - Prob. 2QRTCh. 19 - Prob. 3QRTCh. 19 - Prob. 4QRTCh. 19 - Prob. 5QRTCh. 19 - Prob. 6QRTCh. 19 - Prob. 7QRTCh. 19 - Prob. 8QRTCh. 19 - Prob. 9QRTCh. 19 - Prob. 10QRTCh. 19 - Prob. 11QRTCh. 19 - Prob. 12QRTCh. 19 - Prob. 13QRTCh. 19 - Prob. 14QRTCh. 19 - Prob. 15QRTCh. 19 - Prob. 16QRTCh. 19 - Prob. 17QRTCh. 19 - Prob. 18QRTCh. 19 - Prob. 19QRTCh. 19 - Prob. 20QRTCh. 19 - Prob. 21QRTCh. 19 - Prob. 22QRTCh. 19 - Prob. 23QRTCh. 19 - Prob. 24QRTCh. 19 - Prob. 25QRTCh. 19 - Prob. 26QRTCh. 19 - Identify the substance or substances produced by...Ch. 19 - Prob. 28QRTCh. 19 - Prob. 29QRTCh. 19 - Prob. 30QRTCh. 19 - Prob. 31QRTCh. 19 - Prob. 32QRTCh. 19 - Prob. 33QRTCh. 19 - Prob. 34QRTCh. 19 - Prob. 35QRTCh. 19 - Prob. 36QRTCh. 19 - Prob. 37QRTCh. 19 - Prob. 38QRTCh. 19 - Prob. 39QRTCh. 19 - Prob. 40QRTCh. 19 - Prob. 41QRTCh. 19 - Prob. 42QRTCh. 19 - A human body contains approximately 5 L of blood....Ch. 19 - Prob. 44QRTCh. 19 - Prob. 45QRTCh. 19 - Prob. 46QRTCh. 19 - Prob. 47QRTCh. 19 - Prob. 48QRTCh. 19 - Prob. 49QRTCh. 19 - Prob. 50QRTCh. 19 - Prob. 51QRTCh. 19 - Prob. 52QRTCh. 19 - Prob. 53QRTCh. 19 - Prob. 54QRTCh. 19 - Prob. 55QRTCh. 19 - Prob. 56QRTCh. 19 - Prob. 57QRTCh. 19 - Prob. 58QRTCh. 19 - Prob. 59QRTCh. 19 - Prob. 60QRTCh. 19 - Prob. 61QRTCh. 19 - Prob. 62QRTCh. 19 - Prob. 63QRTCh. 19 - Prob. 64QRTCh. 19 - Prob. 65QRTCh. 19 - Prob. 66QRTCh. 19 - Prob. 67QRTCh. 19 - Prob. 68QRTCh. 19 - Prob. 69QRTCh. 19 - Prob. 70QRTCh. 19 - Prob. 71QRTCh. 19 - Prob. 72QRTCh. 19 - Prob. 73QRTCh. 19 - Prob. 74QRTCh. 19 - Use the phase diagram for sulfur for Question 75....Ch. 19 - Prob. 76QRTCh. 19 - Prob. 77QRTCh. 19 - Prob. 78QRTCh. 19 - Prob. 79QRTCh. 19 - Prob. 80QRTCh. 19 - A natural brine found in Arkansas has a bromide...Ch. 19 - Prob. 82QRTCh. 19 - Prob. 83QRTCh. 19 - Prob. 84QRTCh. 19 - At 20. C the vapor pressure of white phosphorus is...Ch. 19 - Prob. 86QRTCh. 19 - Assume that the radius of Earth is 6400 km, the...Ch. 19 - Prob. 88QRTCh. 19 - Prob. 89QRTCh. 19 - Prob. 90QRTCh. 19 - Prob. 91QRTCh. 19 - Prob. 92QRTCh. 19 - Prob. 93QRTCh. 19 - Prob. 94QRTCh. 19 - Prob. 95QRTCh. 19 - Use a Born-Haber cycle (Sec. 5-13) to calculate...Ch. 19 - Prob. 97QRTCh. 19 - Elemental analysis of a borane indicates this...Ch. 19 - Prob. 99QRTCh. 19 - Prob. 100QRT
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