Connect One Semester Access Card for General, Organic, & Biological Chemistry
4th Edition
ISBN: 9781260194654
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 19, Problem 86P
Interpretation Introduction
Interpretation:
The importance of cholesterol, HDLs and LDLs in the laboratory blood report needs to be explained.
Concept Introduction:
Steroids are types of lipids, which consist of three 6-membered rings and one 5-membered ring. These all rings together called as steroid nucleus. Other polar and non-polar groups are bonded with these rings and are responsible for different physical and chemical properties of steroids. Cholesterol is one of the examples of steroid with four steroid nuclei.
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A solution contains 0.097 M Ce3+, 1.55x10-3 M Ce4+, 1.55x10-3 M Mn2+, 0.097 M MnO4-, and 1.00 M HClO4 (F= 9.649 x 104 C/mol).
a) Write a balanced net reaction that can occur between species in this solution.
b) Calculate deltaG0 and K for the reaction.
c) Calculate E and deltaG for the conditions given.
Ce4+ + e- = Ce3+ E0= 1.70 V
MnO4- + 8H+ + 5e- = Mn2+ + 4H2O E0= 1.507 V
1. Provide a step-by-step mechanism for formation of ALL STEREOISOMERS in
the following reaction.
Na HCO3 (Sodium bicarbonate, baking soda) is not soluble in CH2Cl2. The powder is
a weak base used to neutralize strong acid (pKa < 0) produced by the reaction.
Redraw the product to show the configuration(s) that form at C-2 and C-4.
Br2
OH
CH2Cl2
Na* HCO3
Br
HO
OH
+ Na Br +
2. Specify the solvent and reagent(s) required to carry out each of the following FGI. If
two reagent sets must be used for the FGI, specify the solvent and reagent(s) for each
reagent set. If a reaction cannot be carried out with reagents (sets)
class, write NP (not possible) in the solvent box for reagent set #1.
Use the letter abbreviation for each solvent; use a number abbreviation for reagent(s).
Solvents: CH2Cl2 (A);
H₂O (B);
Reagents:
HBr (1);
R₂BH (6);
H2SO4 (2);
CH3OH (C);
Br₂ (3);
CH3CO₂H (D)
NaHCO3 (4);
Hg(OAc)2 (5);
H₂O2/HO (7);
NaBH4 (8)
Reagent Set #1
Reagent Set #2
FGI
+ enant
OH
Solvent Reagent(s) Solvent Reagent(s)
Chapter 19 Solutions
Connect One Semester Access Card for General, Organic, & Biological Chemistry
Ch. 19.1 - Prob. 19.1PPCh. 19.1 - Prob. 19.1PCh. 19.2 - (a) Draw a skeletal structure for each fatty acid....Ch. 19.2 - Prob. 19.2PCh. 19.2 - Prob. 19.3PCh. 19.3 - Prob. 19.3PPCh. 19.3 - One component of jojoba oil is a wax formed from...Ch. 19.3 - Explain why beeswax is insoluble in water,...Ch. 19.3 - Prob. 19.6PCh. 19.4 - Prob. 19.4PP
Ch. 19.4 - Prob. 19.7PCh. 19.4 - Prob. 19.8PCh. 19.5 - Prob. 19.5PPCh. 19.5 - Review Section 5.2 on balancing chemical...Ch. 19.5 - Prob. 19.10PCh. 19.6 - Prob. 19.6PPCh. 19.6 - Identify the components of each lipid and classify...Ch. 19.7 - Prob. 19.12PCh. 19.7 - Prob. 19.13PCh. 19.7 - Prob. 19.14PCh. 19.8 - (a) Label the rings of the steroid nucleus in...Ch. 19.8 - Prob. 19.16PCh. 19.8 - Prob. 19.17PCh. 19.9 - Prob. 19.18PCh. 19.9 - Prob. 19.19PCh. 19.10 - Prob. 19.20PCh. 19.11 - Prob. 19.21PCh. 19.11 - Prob. 19.22PCh. 19 - Prob. 23PCh. 19 - Prob. 24PCh. 19 - Prob. 25PCh. 19 - Prob. 26PCh. 19 - Prob. 27PCh. 19 - Prob. 28PCh. 19 - Rank the fatty acids in order of increasing...Ch. 19 - Prob. 30PCh. 19 - Prob. 31PCh. 19 - Prob. 32PCh. 19 - Prob. 33PCh. 19 - Prob. 34PCh. 19 - Draw the structure of a wax formed from palmitic...Ch. 19 - Draw the structure of a wax formed from a...Ch. 19 - What hydrolysis products are formed when each wax...Ch. 19 - What hydrolysis products are formed when each wax...Ch. 19 - Prob. 39PCh. 19 - Prob. 40PCh. 19 - Draw a triacylglycerol that fits each description:...Ch. 19 - Draw a triacylglycerol that fits each description:...Ch. 19 - Draw the structure of a triacylglycerol that...Ch. 19 - Draw the structure of a triacylglycerol that...Ch. 19 - Consider the following four types of compounds:...Ch. 19 - How do fats and oils compare with respect to each...Ch. 19 - For the food product shown in the accompanying...Ch. 19 - For the food product shown in the accompanying...Ch. 19 - Answer the following questions about the given...Ch. 19 - Answer the following questions about the given...Ch. 19 - Draw the products formed when each triacylglycerol...Ch. 19 - Draw the products formed when each triacylglycerol...Ch. 19 - Which of the following are phospholipids: (a)...Ch. 19 - Prob. 54PCh. 19 - Prob. 55PCh. 19 - Prob. 56PCh. 19 - wIn transporting molecules or ions across a cell...Ch. 19 - Prob. 58PCh. 19 - Draw the structure of the anabolic steroid...Ch. 19 - Draw the structure of the anabolic steroid...Ch. 19 - Why must cholesterol be transported through the...Ch. 19 - Describe the role of HDLs and LDL5 in cholesterol...Ch. 19 - Prob. 63PCh. 19 - Prob. 64PCh. 19 - (a) Draw the structure of an estrogen and an...Ch. 19 - (a) Draw the structure of an androgen and a...Ch. 19 - What are the similarities and differences between...Ch. 19 - Why aren’t prostaglandins classified as hormones?Ch. 19 - What two structural features characterize all...Ch. 19 - List three biological functions of prostaglandins...Ch. 19 - Explain why aspirin and celecoxib differ in how...Ch. 19 - How does zileuton treat the cause of asthma, not...Ch. 19 - Answer each question with regard to vitamins A and...Ch. 19 - Answer each question in Problem 19.73 for vitamins...Ch. 19 - Give an example of each type of lipid. a. a...Ch. 19 - Give an example of each type of lipid. a. a...Ch. 19 - Consider each of the following components: [1]...Ch. 19 - Consider each of the following components: [1]...Ch. 19 - Block diagrams representing the general structures...Ch. 19 - For each block diagram in Problem 19.79, label the...Ch. 19 - Prob. 81PCh. 19 - Prob. 82PCh. 19 - Prob. 83PCh. 19 - Prob. 84PCh. 19 - Prob. 85PCh. 19 - Prob. 86PCh. 19 - Can an individual survive on a completely fat-free...Ch. 19 - Prob. 88PCh. 19 - Prob. 89PCh. 19 - Prob. 90PCh. 19 - Prob. 91PCh. 19 - Prob. 92PCh. 19 - Prob. 93CPCh. 19 - Prob. 94CP
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