The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions. Concept introduction: Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction. Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule. Oxidation Reaction : The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons. LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols. To identify : The synthetic route to accomplish the given transformation.

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Answer 1

Question

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

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Answer 2

Question

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

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Answer 3

Question

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

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Answer 4

Question

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

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Answer 5

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

Answer 6

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

Answer 7

Chapter 19, Problem 85IP

Interpretation Introduction

Interpretation:

The possible reaction and mechanism should be draw and identified for the given reaction proceeds under acidic conditions.

Concept introduction:

Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.

Acid Catalyzed Hydration Reaction: The reaction involves breaking of π-bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.

Oxidation Reaction: The oxidation-reduction reaction is a type of chemical reaction it is involves a transfer of electrons between two species. In other words oxidation reaction number of a molecule atom or ion changes by gaining or losing electrons.

LAH Reduction: The saturated/unsaturated aldehyde and ketones in the presence of sodium metal in LAH and carbonyl compound produced saturated alcohols. The keto group involves in the reduction process of LAH, this end up reducing to give the alcohols.

To identify: The synthetic route to accomplish the given transformation.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 19.2 - Prob. 1LTS Ch. 19.2 - Prob. 1PTS Ch. 19.2 - Prob. 2PTS Ch. 19.2 - APPLY the skill Compounds with two ketone groups...Ch. 19.2 - Prob. 4ATS Ch. 19.3 - Prob. 5CC Ch. 19.4 - Prob. 6CC Ch. 19.5 - Prob. 7CC Ch. 19.5 - Prob. 2LTS Ch. 19.5 - Prob. 8PTS

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Chapter 19 Solutions